Electronic ink, electronic paper and display method of electronic paper
An electronic ink and electrophoretic display technology, applied in the field of electronic paper, can solve the problems of reducing the first resistance and increasing the second resistance, etc., to reduce resistance, solve the problem of poor ability to maintain static images, and fast dynamic image switching Effect
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Embodiment 1
[0057] Example 1 Preparation method of negative electrorheological fluid-polyamic acid salt / silicone oil system
[0058] 1. Synthesis of polyamic acid
[0059] Add 0.01mol each of pyromellitic dianhydride and ether diamine to a three-necked flask, add N, N-dimethylformamide to form a solution with a mass concentration of reactants of 15%, stir in an ice-water bath for about 10 hours, and then After stirring at room temperature for about 12 hours, a bright yellow transparent polyamic acid was obtained.
[0060] The polyamic acid that polymerizes is obtained with the Ca(OH) of 1L 0.02mol / L 2 The solution is processed to precipitate out of the solution to obtain polyamic acid calcium salt.
[0061] The mass fractions of several main elements in polyamic acid particles obtained by photoelectron spectroscopy analysis are: ω(C) is 66%; ω(O) is 25.7%; ω(N) is 8.3%. The average diameter of the particles was 6.71 μm.
[0062] figure 2 It is the infrared spectrogram of polyamic ac...
Embodiment 2
[0066] Example 2 Preparation method of negative electrorheological fluid-polyamic acid salt / silicone oil system
[0067] 1. Synthesis of polyamic acid
[0068] Add 0.003mol 4,4'-diaminodiphenylmethane monomer (MDA) to a dry four-neck flask equipped with a magnetic stirrer, a thermometer, and a nitrogen inlet tube, and then add the solvent dimethylformamide (DMF), fully After dissolving, slowly add a DMF solution containing 0.001mol 3,3',4,4'-benzophenonetetracarboxylic dianhydride (BTDA) and 0.002mol pyromellitic dianhydride (PMDA) dropwise with a syringe, drop within 1h Finished adding. During the reaction, N was continuously passed 2 , keep the reaction at 30°C, and keep the temperature constant. After 24 hours of reaction, pour the mixed solution into deionized water to precipitate the polymer, filter it with suction, wash it with deionized water first, then wash it with methanol several times, and put the obtained solid in Dry at room temperature in a vacuum drying oven...
Embodiment 3
[0074] Embodiment 3 electronic ink
[0075] The electronic ink of the present invention is made of a plurality of electronic ink microcapsules, and the electronic ink microcapsules contain a negative electrorheological fluid polyamic acid salt / silicone oil system as an electrophoretic display liquid; wherein, the polyamic acid salt accounts for a negative current The mass volume percentage of the changing solution is 50%.
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