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High mechanical strength ammonia storage mixture containing ceramic fiber and preparation method thereof

A technology of ceramic fiber and mechanical strength, which is applied in the field of hydrogen fuel cell system of new energy vehicles, can solve the problems that there are no clear claims and detailed items, and technical personnel cannot implement it, so as to achieve good physical adsorption and surface chemical activity, improve viscosity and Adsorption capacity, effect of structural stability

Active Publication Date: 2015-08-19
CHINA FIRST AUTOMOBILE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

This patent uses solid material for direct compression molding, uses binder, only declares that it may be silica fiber binder, and does not add the proportion, and other claims and examples only state that the solid material may include Composition of granular materials, porous materials, crystalline materials, amorphous materials or their combinations, without clear claim details, it is almost impossible for those skilled in the industry to implement

Method used

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  • High mechanical strength ammonia storage mixture containing ceramic fiber and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] The industrial anhydrous magnesium chloride salt powder of 69wt%, the ceramic fiber of 7wt%, the industrial clay of 7wt% and the industrial alcohol of 17wt% form a mixture, stir evenly by the mixer, stirring time is 1h, forms semi-dry mixed powder; The semi-dry mixed powder is added into an openable airtight container and subjected to mechanical vibration for 30 minutes to form a wet body sample, and then at 80°C with a vacuum of 10 -1 After drying for 2 hours under the condition of Kpa, an ammonia storage active mixture containing 8.4wt% ceramic fibers can be obtained.

[0016] Fill 10g of ammonia storage active mixture with ammonia in a naturally ventilated environment. Put the openable airtight container into a water tank with enough cooling water in advance, connect the ammonia steel cylinder, and pass through the pressure reducing valve and drying system , fill ammonia slowly within the pressure range of 1Mpa, and the ammonia filling time is 3h; after ammonia filli...

Embodiment 2

[0018] The industrial anhydrous magnesium chloride salt powder of 80wt%, the ceramic fiber of 4wt%, the industrial clay of 4wt% and the industrial alcohol of 12wt% form a mixture, stir evenly by the mixer, and stirring time is 5h, forms semi-dry mixed powder; The semi-dry mixed powder is added into an openable airtight container and mechanically shaken for 60 minutes to form a wet body sample, and then dried at 60°C for 3 hours under a vacuum of 1Kpa to obtain 4.5wt % Ammonia storage active mixture of ceramic fibers 。

[0019] Fill 10g of ammonia storage active mixture with ammonia in a naturally ventilated environment. Put the openable airtight container into a water tank with enough cooling water in advance, connect the ammonia steel cylinder, and pass through the pressure reducing valve and drying system , fill ammonia slowly within the pressure range of 0.3Mpa, and the ammonia filling time is 5h; after ammonia filling, the mass of the sample block is 19.9g, that is, 9.9g ...

Embodiment 3

[0021] The industrial anhydrous magnesium chloride salt powder of 75wt%, the ceramic fiber of 10wt%, the industrial clay of 4wt% and the industrial alcohol of 11wt% form a mixture, stir evenly by the mixer, stirring time is 10h, forms semi-dry mixed powder; The semi-dry mixed powder is added into an openable airtight container and subjected to mechanical vibration for 45 minutes to form a wet body sample, and then dried at 100°C for 3 hours to obtain a storage material containing 11.2wt% ceramic fibers. Ammonia Active Mixture 。

[0022] Fill 10g of ammonia storage active mixture with ammonia in a naturally ventilated environment. Put the openable airtight container into a water tank with enough cooling water in advance, connect the ammonia steel cylinder, and pass through the pressure reducing valve and drying system , fill ammonia slowly within the pressure range of 0.2Mpa, and the ammonia filling time is 8h; after ammonia filling, the mass of the sample block is 19.1g, that...

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Abstract

The invention relates to a high-mechanical strength stored ammonia mixture containing a ceramic fiber. The high-mechanical strength stored ammonia mixture contains anhydrous magnesium chloride, the ceramic fiber and industrial clay. The high-mechanical strength stored ammonia mixture is characterized in that the preparation method comprises the steps of: forming mixture by industrial anhydrous magnesium chloride powder, the ceramic fiber, the industrial clay and industrial alcohol; uniformly agitating the mixture by an agitator, forming semi-drying mixture powder; adding the semi-drying mixture powder to an open sealed container to mechanically oscillate, forming a wet sample block, and drying the sample block for 2-3 hours under the condition that the temperature is 60-80 DEG C and the vacuum degree is 1-10pa to 1Kpa. The prepared storage ammonia mixture has super-strong adsorptive capacity, stable structure and high mechanical strength; in a process of preparing the active stored ammonia mixture, proper industrial clay is also added. Clay mineral has plasticity after being humidified by water, and can deform and keep an original shape for a long time under smaller pressure; the specific surface area is large, and the particles have electronegativity, so the high-mechanical strength stored ammonia mixture has good physical adsorbability and surface chemical activity, and the viscosity and adsorbability of the mixture can be further improved.

Description

technical field [0001] The invention relates to a high-mechanical-strength ammonia storage mixture containing ceramic fibers and a preparation method thereof, which are applied to a post-treatment system of automobile exhaust and a hydrogen fuel cell system of a new energy automobile. Background technique [0002] Today, the world is facing the dual challenges of energy crisis and environmental crisis. People are still facing many problems in the selection of technical means to meet the emission standards of traditional vehicles, and in the fuel supply technology of new energy vehicles. [0003] In terms of traditional automobiles, the SCR aftertreatment system relies on the precise supply of urea reducing agent and decomposes it into ammonia at the front end of the catalyst to remove NOX hazards, thereby achieving the purpose of purifying exhaust gas. However, in actual use, there are many deficiencies and difficulties in the metered injection of liquid urea that relies on...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/12B01J20/30C01C1/00
Inventor 张克金崔龙姜涛王丹王金星安宇鹏于力娜许德超
Owner CHINA FIRST AUTOMOBILE