Adhesive combination and surface protective film
A composition and adhesive technology, applied in the direction of adhesive types, ester copolymer adhesives, polyurea/polyurethane adhesives, etc., can solve the problems of easy reduction of reworkability, difficulty in peeling, and easy occurrence, etc. Achieve the effect of preventing adhesive residue and excellent antistatic performance
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Embodiment 1
[0090] Nitrogen was introduced into a reaction device equipped with a stirrer, a thermometer, a reflux condenser, and a nitrogen introduction pipe, and the air in the reaction device was replaced with nitrogen. Then, 100 parts by weight of 2-ethylhexyl acrylate, 0.9 parts by weight of 8-hydroxyoctyl acrylate, 0.5 parts by weight of acrylic acid, and 60 parts of solvent (ethyl acetate) were added to the reaction device. Then, 0.1 parts by weight of azobisisobutyronitrile as a polymerization initiator was dropped over 2 hours, and reacted at 65°C for 6 hours to obtain acrylic copolymer solution 1 used in Example 1 with a weight average molecular weight of 500,000 .
Embodiment 2~9 and comparative example 1~9
[0092] The composition of the monomers was set as described in (A) to (C) of Table 1. Except for this, in the same manner as in the acrylic copolymer solution 1 used in Example 1 above, Examples 2 to were obtained. 9 and the acrylic copolymer solution used in Comparative Examples 1-9.
[0093]
[0094] [Example 1]
[0095] As described above, to the prepared acrylic copolymer solution 1 (wherein the acrylic copolymer is 100 parts by weight), 1.5 parts by weight of 1-octylpyridinium hexafluoride phosphate, KF-351A (HLB=12 polyether Modified siloxane compound) 0.1 parts by weight, 2.5 parts by weight of acetylacetone and stirring, add 1.5 parts by weight of Corone HX (isocyanurate body of hexamethylene diisocyanate compound), dilauric acid After 0.02 part by weight of octyltin, the mixture was stirred and mixed to obtain the adhesive composition of Example 1. After applying the adhesive composition on a release film made of a silicone resin-coated polyethylene terephthalate (PET) f...
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