Polyurethane composite hard polyfoam as well as preparation method and application of polyurethane composite hard polyfoam

A technology of rigid foam and polyurethane, which is applied in the field of preparation of polyurethane composite rigid foam plastics, can solve the problems of high production cost of polyurethane rigid foam, poor heat resistance, flame retardancy, antistatic performance, etc., and achieve Excellent performance, wide range of applications, and simple process control

Active Publication Date: 2012-11-21
HENAN TIANFON ENERGY SAVING PANEL SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, compared with building energy-saving materials such as rock wool, glass wool, cement polystyrene board, and silicate composite thermal insulation mortar, the production cost of polyurethane rigid foam is relatively high, and its heat resistance, flame retardancy, and antistatic properties are poor. , limiting its further application
This will cause certain obstacles to its large-scale application, so how to reduce the production cost of polyurethane rigid foam and improve its physical properties has become a difficult problem to overcome

Method used

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  • Polyurethane composite hard polyfoam as well as preparation method and application of polyurethane composite hard polyfoam
  • Polyurethane composite hard polyfoam as well as preparation method and application of polyurethane composite hard polyfoam
  • Polyurethane composite hard polyfoam as well as preparation method and application of polyurethane composite hard polyfoam

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Experimental program
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Embodiment 1

[0028] The polyurethane composite rigid foam plastic of this embodiment is composed of component A and component B, wherein component A is formed by mixing isocyanate and inorganic materials; component B is formed by mixing polyether, catalyst and foaming agent into; the weight ratio of component A to component B is component A: component B=1.1:1; wherein, in component A, the weight ratio of isocyanate to inorganic material is: (152-154): (2- 10); in component B, the weight ratio of the combined polyether, catalyst and blowing agent is: combined polyether: catalyst: blowing agent = 100:1.4:16. The catalyst is N,N-dimethylcyclohexylamine, and the blowing agent is HCFC-141b, both of which are commercially available; the inorganic material in this embodiment is sodium carbonate or barium sulfate.

Embodiment 2

[0030] The polyurethane composite rigid foam plastic of this embodiment is composed of component A and component B, wherein component A is formed by mixing isocyanate and inorganic materials; component B is formed by mixing polyether, catalyst and blowing agent into; the weight ratio of component A to component B is component A:component B=1.3:1; wherein, in component A, the weight ratio of isocyanate to inorganic material is: (152-155): (5- 13); In component B, the weight ratio of the combination polyether, catalyst and foaming agent is: combination polyether:catalyst:foaming agent=100:1.6:(15-17). The catalyst used is dibutyltin dilaurate, and the blowing agent is HCFC-245fa; the inorganic material in this embodiment is perlite.

Embodiment 3

[0032] The polyurethane composite rigid foam plastic of this embodiment is composed of component A and component B, wherein component A is formed by mixing isocyanate and inorganic materials; component B is formed by mixing polyether, catalyst and foaming agent into; the weight ratio of component A to component B is component A: component B=1.4:1; wherein, in component A, the weight ratio of isocyanate to inorganic material is: (152-158): (3- 7) In component B, the weight ratio of the combined polyether, catalyst and blowing agent is: combined polyether: catalyst: blowing agent = 100:2.8: (15-17). The catalyst is dibutyltin dilaurate, and the blowing agent is pentane; the inorganic material in this embodiment is aluminum hydroxide or magnesium hydroxide.

[0033] The preparation method embodiment 1 of polyurethane composite rigid foam plastic

[0034] The preparation method of the polyurethane composite rigid foam plastic of the present embodiment may further comprise the ste...

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Abstract

The invention relates to polyurethane composite hard polyfoam as well as a preparation method and application of the polyurethane composite hard polyfoam, wherein the polyurethane composite hard polyfoam consists of ingredients A and ingredients B, wherein the ingredients A are formed by mixing isocyanate and inorganic materials, the ingredients B are formed by mixing combined polyether, catalysts and foaming agents, and the weight ratio of the ingredients A to the ingredients B is (1.1-.14):1. The isocyanate in the ingredients A used by the polyurethane composite hard polyfoam contains -N-C=0 which can easily take reaction with active-hydrogen-atom-containing compounds such as amine, water, alcohol, acid and alkali. The isocyanate is a vacuum dehydration raw material, the dispersion of superfine powder cannot be influenced, and the uniform dispersion can be realized in organic solvents. Meanwhile, some inorganic materials can also be added into the ingredients B, for example, hydroxyl ions are contained in the oxyhydrate and can be possibly and perfectly compatible with the combined polyether containing hydroxy functional groups. The added inorganic materials can be one single ingredient and can also be composite materials obtained through compounding polyurethane inorganic materials and adding other fire retardants. Various kinds of inorganic materials are adopted for compounding, and the problem of poor foam performance generated by the single use can be solved.

Description

technical field [0001] The invention relates to a polyurethane composite rigid foam plastic, and also relates to a preparation method and application of the polyurethane composite rigid foam plastic. Background technique [0002] Polyurethane has become one of the six major synthetic materials, and its application range ranks first among all kinds of materials. Polyurethane rigid foam plastic, referred to as polyurethane rigid foam, mostly has a closed-cell structure and is generally room temperature foaming. It is mainly used for refrigeration and refrigeration equipment in food and other industries; it can also be used for heat preservation of industrial equipment. However, compared with building energy-saving materials such as rock wool, glass wool, cement polystyrene board, and silicate composite thermal insulation mortar, the production cost of polyurethane rigid foam is relatively high, and its heat resistance, flame retardancy, and antistatic properties are poor. , l...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/78C08G18/48C08K3/26C08K3/30C08K3/34C08K3/38C08K3/22C08J9/14C08L75/08
Inventor 马洁霞刘存芳王振丽胡蓓蓓
Owner HENAN TIANFON ENERGY SAVING PANEL SCI & TECH
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