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Silicon carbide foamed ceramics and preparation method thereof

A foamed ceramic and silicon carbide technology, which is applied in the field of functional materials and their preparation, can solve the problems of the limitation of the wide application of silicon carbide foamed ceramics, the difficulty in controlling the pore volume and size, and the incompactness of the foamed ceramics, and achieves low cost and high yield. , easy to formulate effect

Inactive Publication Date: 2013-04-03
GUIZHOU NORMAL UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Because the first three methods do not have a hot pressing process, the initial density is not high, the prepared foamed ceramics are not dense, the strength is low, and the pore volume and size of the solid-state reaction sintering method and the silicon-containing resin pyrolysis method are difficult to control; while the vapor deposition method costs higher, less efficient
Due to the above problems, the wide application of silicon carbide foam ceramics is restricted

Method used

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  • Silicon carbide foamed ceramics and preparation method thereof

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Embodiment 1

[0017] Embodiment 1 of the present invention: silicon carbide foamed ceramics, calculated in parts by weight, its material includes 90 parts of silicon carbide micropowder particles with an average particle size of 0.3 μm (using a commercially available β-SiC model product), 10 parts of poly Carbosilane powder, 40 parts tetrahydrofuran; its template is polyurethane sponge.

[0018] The preparation method of silicon carbide foam ceramics is to add silicon carbide micropowder particles and polycarbosilane powder into tetrahydrofuran for mixing, and then obtain an organic solvent slurry after fully stirring; after cutting the polyurethane sponge into the required shape and size, extrude it Put it in the organic solvent slurry after depressurizing and removing the air, let it stretch freely and keep stirring, extruding and kneading, so that the organic solvent slurry is evenly coated on the polyurethane sponge, and the excess organic solvent slurry on the polyurethane sponge is rem...

Embodiment 2

[0019] Embodiment 2 of the present invention: silicon carbide foamed ceramics, calculated in parts by weight, its material includes 85 parts of silicon carbide micropowder particles with an average particle size of 0.3 μm (using commercially available β-SiC model products), 15 parts of poly Carbosilane powder, 40 parts tetrahydrofuran; its template is polyurethane sponge.

[0020] The preparation method of silicon carbide foam ceramics is to add solid silicon carbide micropowder particles and solid polycarbosilane powder into tetrahydrofuran for mixing, and obtain an organic solvent slurry after fully stirring; after cutting the polyurethane sponge into the required shape and size, the Put it in the organic solvent slurry after extruding to remove the air, let it stretch freely and continue to stir, extrude and knead, so that the organic solvent slurry is evenly coated on the polyurethane sponge, and the excess organic solvent slurry on the polyurethane sponge is removed. Make...

Embodiment 3

[0021] Embodiment 3 of the present invention: silicon carbide foamed ceramics, calculated in parts by weight, its material includes 95 parts of silicon carbide micropowder particles with an average particle size of 5 μm (using commercially available β-SiC model products), 20 parts of polycarbonate Silane powder, 170 parts tetrahydrofuran; its template is polyurethane sponge.

[0022] The preparation method of silicon carbide foam ceramics is to add silicon carbide micropowder particles and polycarbosilane powder into tetrahydrofuran for mixing, and then obtain an organic solvent slurry after fully stirring; after cutting the polyurethane sponge into the required shape and size, extrude it Put it in the organic solvent slurry after depressurizing and removing the air, let it stretch freely and keep stirring, extruding and kneading, so that the organic solvent slurry is evenly coated on the polyurethane sponge, and the excess organic solvent slurry on the polyurethane sponge is r...

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Abstract

The invention discloses silicon carbide foamed ceramics which comprises the following raw materials in parts by weight: 80-95 parts of silicon carbide micro powder particles, 5-20 parts of polycarbosilane powder and 40-170 parts of organic solvent. A template of the silicon carbide foamed ceramics is made of polymeric sponge. According to the invention, by using the characteristic that the polycarbosilane can be dissolved in the organic solvent, the polycarbosilane and ceramic powder are made into organic solvent slurry, polyurethane foam is dipped in the organic solvent slurry through adopting a powder sintering process principle, and thermally oxidized so that the yield of polycarbosilane ceramics is increased, the silicon carbide foamed ceramics is prepared through sintering under an inert atmosphere. A preparation method has the advantages of low sintering temperature, high efficiency and high production purity, and effectively avoids the difficulties of complex procedures, too many introduced impurities and high sintering temperature of the traditional preparation method for preparing the silicon carbide foamed ceramics.

Description

technical field [0001] The invention relates to a functional material and a preparation method thereof, in particular to a silicon carbide foamed ceramic. Background technique [0002] As a new type of functional material, silicon carbide foam ceramics has light weight, high dielectric constant, large specific surface area, excellent chemical resistance, and can be used for a long time in harsh environments. It is widely used in aerospace, electronics, biomedicine, metallurgy , composite materials and other fields have broad application prospects. [0003] At present, silicon carbide foam ceramics are prepared by the following four methods: powder sintering method, solid state reaction sintering method, silicon resin pyrolysis method and vapor deposition method. The powder sintering method is to adjust the silicon carbide micropowder containing a certain amount of sintering aid and the linking agent into a slurry with a suitable concentration, then use polyurethane foam to ...

Claims

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Application Information

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IPC IPC(8): C04B38/06C04B35/565C04B35/622
Inventor 黎阳刘卫陈璐
Owner GUIZHOU NORMAL UNIVERSITY
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