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Biologic polyamide quadripolymer and synthesis method thereof

A technology of bio-based polyamide and tetrapolymer, applied in the preparation of bio-based polyamide, aliphatic polyamide tetrapolymer and its preparation field, to achieve low degradation rate, expand the application range, and solve the problem of depletion of petroleum resources Effect

Active Publication Date: 2013-04-10
BEIJING UNIV OF CHEM TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among the existing bio-based polyamides, except for PA1010 and PA11, the others are partially bio-based polymers, and there are few literature reports on 100% bio-based polyamides

Method used

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  • Biologic polyamide quadripolymer and synthesis method thereof
  • Biologic polyamide quadripolymer and synthesis method thereof
  • Biologic polyamide quadripolymer and synthesis method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Add 1.9515g (ie 0.015mol) of itaconic acid and 17.1913g (ie 0.085mol) of sebacic acid into 150ml of absolute ethanol and heat to 65°C to dissolve them completely. Add 1.7630 g (ie 0.02 mol) of butanediamine and 13.9464 g (ie 0.08 mol) of decanediamine into 100 ml of absolute ethanol, and heat to 50° C. to completely dissolve them.

[0032] Pour the ethanol solution of the above-mentioned mixed diamine monomer into the ethanol solution of the above-mentioned mixed diacid monomer, continue stirring at 50°C for 10 minutes, obtain crystals after cooling and crystallization, and suction filtration, wash the obtained crystals with absolute ethanol 3 times, Then transfer it to a petri dish and put it into a vacuum drying oven at 30° C. for 12 hours to obtain the amide salt.

[0033]Add the above-mentioned amide salt, hydroquinone (0.03% of the total mass of amide salt) and phosphorous acid (0.01% of the total mass of amide salt) into a three-necked flask equipped with mechanic...

Embodiment 2

[0035] Add 1.9515g (ie 0.015mol) of itaconic acid and 17.1913g (ie 0.085mol) of sebacic acid into 150ml of absolute ethanol and heat to 65°C to dissolve them completely. Add 2.6445g (ie 0.03mol) of butanediamine and 12.2031g (ie 0.07mol) of decanediamine into 100ml of absolute ethanol, and heat to 50°C to dissolve them completely.

[0036] Pour the ethanol solution of the above-mentioned mixed diamine monomer into the above-mentioned ethanol solution of the mixed diacid monomer, continue stirring at 50°C for 10 minutes, obtain crystals after cooling and crystallization, and suction filtration, wash the obtained crystals with absolute ethanol 3 times, Then transfer it to a petri dish and put it into a vacuum drying oven at 30° C. for 12 hours to obtain the amide salt.

[0037] Add the above-mentioned amide salt and phosphorous acid (0.04% of the total mass of amide salt) into a three-necked flask equipped with mechanical stirring and a thermometer, and vacuum to completely remo...

Embodiment 3

[0039] Add 1.9515g (ie 0.015mol) of itaconic acid and 17.1913g (ie 0.085mol) of sebacic acid into 150ml of absolute ethanol and heat to 65°C to dissolve them completely. Add 3.5260g (ie 0.04mol) of butanediamine and 10.4598g (ie 0.06mol) of decanediamine into 100ml of absolute ethanol, and heat to 50°C to dissolve them completely.

[0040] Pour the ethanol solution of the above-mentioned mixed diamine monomer into the above-mentioned ethanol solution of the mixed diacid monomer, continue stirring at 50°C for 12 minutes, obtain crystals after cooling and crystallization, and suction filtration, and wash the obtained crystals with absolute ethanol for 5 times. Then transfer it to a petri dish and put it into a vacuum drying oven at 30° C. for 12 hours to obtain the amide salt.

[0041] Add the above-mentioned amide salt and hydroquinone (0.01% of the total mass of the amide salt) into a three-necked flask equipped with mechanical stirring and a thermometer, and vacuumize to comp...

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Abstract

The invention relates to a biologic polyamide quadripolymer and a synthesis method thereof, and belongs to the field of high molecular materials. The biologic polyamide quadripolymer is characterized in that the structural formula is shown as the specifications, wherein the four chain segments or chain links are arranged randomly. The invention also provides the synthesis method. The biologic polyamide quadripolymer has excellent environmental stability, a thermal crosslinking property, an irradiation crosslinking property and solvent corrosion resistance, and has physical and mechanical properties and a processing property which are equal to those of conventional polyamide.

Description

technical field [0001] The invention relates to an aliphatic polyamide tetrapolymer containing a C=C double bond in its molecular structure and a preparation method thereof, in particular to a preparation method of a bio-based polyamide based on renewable resources, belonging to the field of polymer materials . Background technique [0002] At present, human society's demand for energy and materials is highly dependent on the ever-decreasing non-renewable fossil resources. serious problems such as sharp decline and environmental pollution. Polymer materials play a very important role in modern social life due to their excellent performance and wide application. However, the sources of monomers of widely used polymer products such as plastics, rubber and fiber products are all dependent on non-renewable fossil resources. [0003] Polyamide (PA), also known as nylon, refers to a linear thermoplastic polymer with amide group (-CONH) repeating structural units on the main cha...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G69/26C08G69/28
Inventor 张立群贾清秀危涛何妙妙薛晓康海澜
Owner BEIJING UNIV OF CHEM TECH
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