Filled polypropylene composite material applied to rapid forming component
A technology for forming parts and composite materials, which is applied in the field of polypropylene composite materials, can solve the problems of poor material flow stability, large material shrinkage, and easy deformation, and achieve good dimensional stability, low shrinkage, and low cost.
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[0035] A method for preparing a filled polypropylene composite material applied to rapid prototyping parts, comprising the following steps:
[0036] (1) Preparation of nano-filler masterbatch: In the solution, swell the nano-filler organized with stearyl ammonium salt with maleic anhydride and a small amount of auxiliary swelling agent; the swollen organic nano-filler is mixed with powdered High-fluidity polypropylene and an appropriate amount of initiator are melted and reacted in a mixer, so that the nano-filler and grafted polypropylene are fully dispersed and contacted, and a polypropylene / nano-filled grafted intercalation blend is obtained, which is the improved Non-toxic nano filler masterbatch;
[0037] (2) Weigh the raw materials according to the weight ratio;
[0038] (3) Dry blend polypropylene, modified nano filler, toughener, heat stabilizer DSTP, antioxidant 1010, and antioxidant 168 in a high-speed mixer for 3-5 minutes;
[0039] (4) Put the mixed raw materials...
Embodiment 1
[0043] Preparation of modified montmorillonite masterbatch: swell organic montmorillonite with octadecyl ammonium salt in solution with maleic anhydride and a small amount of auxiliary swelling agent; swell organic montmorillonite with powdery high The weight ratio of fluid polypropylene is 45:55, 0.5% initiator is melted and reacted in the mixer, so that the montmorillonite and grafted polypropylene are fully dispersed and contacted, and a polypropylene / montmorillonite grafted plug is obtained. Layer blends, that is, modified nano-montmorillonite masterbatches.
[0044] Prepare materials according to the group distribution ratio in the following table:
[0045] Types of name Content (parts) Polypropylene Blends of homo- and copolymer polypropylenes with different flow properties 77.7 Toughener B-octyl rubber 1 Mineral powder filler talcum powder 19 Modified montmorillonite masterbatch Polypropylene / montmorillonite graft intercalati...
Embodiment 2
[0048] Prepare materials according to the group distribution ratio in the following table:
[0049] Types of name Content (parts) Polypropylene Blends of homo- and copolymer polypropylenes with different flow properties 74.7 Toughener B-octyl rubber 4 Mineral powder filler talcum powder 18 Modified montmorillonite masterbatch Polypropylene / montmorillonite graft intercalation blend 2 Nucleating agent β crystal nucleating agent Y-619 0.3 Thermal Oxygen Stabilizer DSTP octadecyl thiodipropionate 0.2 Antioxidant 1010 Tetrakis[β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate]pentaerythritol ester 0.3 Antioxidant 168 Tris(2,4-di-tert-butylphenyl)phosphite 0.5
[0050] Dry mix the above materials in a high-speed mixer for 3-5 minutes, then melt and extrude them in a twin-screw extruder, and granulate. Zone 200~210℃, Zone 4 210~215℃, Zone 5 210~215, Zone 6 210~215, Zone 7 215~225, Zone 8 215~225, Zone 9 21...
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