Halogen-free inflaming retarding permanent antistatic polypropylene composite material and preparation method

A composite material and polypropylene technology, which is applied in the field of halogen-free flame retardant permanent antistatic polypropylene composite material and its preparation, can solve the problems of short-term non-permanence, low development prospect, and reduced impact of composite materials, and achieve excellent resistance. Combustion characteristics, broad application prospects, and the effect of mechanical properties optimization

Inactive Publication Date: 2013-06-05
SHANGHAI SUNNY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, a variety of flame-retardant and antistatic polypropylene composite materials have appeared at home and abroad, and the scope of application is gradually expanding, but the halogen-free flame-retardant permanent antistatic polypropylene composite with high-efficiency permanent antistatic and excellent environmental protection and halogen-free flame retardancy Fewer materials and relatively expensive
At present, the addition of halogenated flame retardants is often used to meet the flame retardancy of composite materials, but the price is relatively high and does not meet environmental protection requirements. Highly filled flame retardants also lead to a decrease in the impact of composite materials
However, general halogen-free flame retardants are easy to absorb water and precipitate out of flame retardants, which affect the processing of composite materials and the appearance of products.
Now the general antistatic agent is ionic antistatic agent, although the effect is good, but the short-term effect is not permanent; conductive carbon black can be used as a permanent antistatic agent, but because of the large amount of use, the production operability is difficult, and the development prospect is not good. Big

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~2

[0026] Embodiment 1~2 proportioning (weight %) sees Table 1.

[0027] Table 1

[0028] raw material name

Example 1

Example 2

Polypropylene

70

64

antistatic agent

8

10

flame retardant

18

23

Compatibilizer

4

3

168 / 1010(1∶1)

0.4

0.4

lubricant

0.3

0.3

[0029] Put all the components in proportion into a high mixer and mix for 3 minutes, then use a screw extruder to extrude and granulate. The processing temperature is 210° C., and the screw rotation speed is 200 rpm.

[0030] A kind of halogen-free flame-retardant permanent antistatic polypropylene composite material sample 1 and sample 2 obtained in Examples 1 and 2 were compared in performance tests, and the mechanical properties were tested by ASTM.

[0031] The performance comparison of sample 1 and sample 2 is shown in Table 2.

[0032] Table 2

[0033] Test items

Embodiment 3

[0035] A preparation method of a halogen-free flame-retardant permanent antistatic polypropylene composite material, the method comprising the following steps:

[0036] (1) Weighing raw materials: 40% crystallinity, 40g of copolymerized polypropylene with a melt index of 15g / 10min, 15g of polyether ester amide polymer permanent antistatic agent, maleic anhydride grafted polypropylene (PP-g- MAH) 8g, less hygroscopic melamine urate or melamine polyphosphate 30g, 0.05g antioxidant 1010 and 0.05g antioxidant 168, 0.1g fatty acid lubricant;

[0037] (2) Put all the raw materials into the high mixer and mix for 2 minutes, then discharge;

[0038] (3) Put the homogeneously mixed raw materials into a twin-screw extruder to extrude and granulate. The rotating speed of the screw machine is 180-450 rpm and the temperature is 180-230°C.

Embodiment 4

[0040] A preparation method of a halogen-free flame-retardant permanent antistatic polypropylene composite material, the method comprising the following steps:

[0041] (1) Raw materials are weighed by weight: 70g of copolymerized polypropylene with a crystallinity of 60% and a melt index of 15g / 10min, 5g of polyether ester amide polymer permanent antistatic agent, maleic anhydride grafted polypropylene (PP -g-MAH) 1g, less hygroscopic melamine urate or melamine polyphosphate 5g, 0.25g antioxidant 1010 and 0.25g antioxidant 168, fatty acid lubricant 0.5g;

[0042] (2) Put all the raw materials into the high mixer and mix for 5 minutes, then discharge;

[0043] (3) Put the homogeneously mixed raw materials into a twin-screw extruder to extrude and granulate. The rotating speed of the screw machine is 180-450 rpm and the temperature is 180-230°C.

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Abstract

The invention relates to a halogen-free inflaming retarding permanent antistatic polypropylene composite material and a preparation method. The halogen-free inflaming retarding permanent antistatic polypropylene composite material is manufactured by the composite materials with the following weight preparation ratio: 40%-70% of polypropylene,5%-15% antistatic agents,1%-8% compatilizer, 5%-30% fire retardant, 0.1%-0.5% antioxygen, and 0.1%-0.5% lubricant. The preparation method comprises the following steps: weighing materials based on the weight preparation ratio; putting all the materials into a high-effective mixing machine to mix for 2-5 minutes and discharging the materials; and putting the uniformly blended materials in a double screw extruder and squeezing out prilling. Compared with the prior art, the halogen-free inflaming retarding permanent antistatic polypropylene composite material has an excellent inflaming retarding feature, 1.6 millimeters inflaming retarding V0 level, and permanent anti-static electricity. The surface resistance is 1010 omega. The halogen-free inflaming retarding permanent antistatic polypropylene composite material has the advantages of being good in mechanics performance, capable of satisfying product requirements and inflaming retarding performance, greatly improving the surface resistance of the composite material, and achieving a good antistatic level.

Description

technical field [0001] The invention relates to a halogen-free flame-retardant permanent antistatic polypropylene composite material and a preparation method thereof. The material can be used to produce environmentally friendly products with high flame retardancy and good antistatic properties, and has great potential in the fields of electronics, home appliances, and packaging. Very broad application prospects. Background technique [0002] Polypropylene material is widely used in many fields because of its excellent mechanical properties and cost performance. The development of flame-retardant PP has expanded the new field of PP product application. The addition of antistatic agent will further add a new direction in the field of PP materials within a certain filling range, so that the composite material has good mechanical properties and excellent flame retardancy. , It also prevents accidents caused by static electricity, and has extremely broad application prospects in...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/14C08L77/12C08L51/06B29B9/06B29C47/92B29C48/92
CPCB29C48/40B29C48/92B29C2948/9259B29C2948/92704B29C2948/92885B29C2948/92895
Inventor 黄晓明孟成铭杨涛
Owner SHANGHAI SUNNY
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