Halogen-free inflaming retarding permanent antistatic polypropylene composite material and preparation method
A composite material and polypropylene technology, which is applied in the field of halogen-free flame retardant permanent antistatic polypropylene composite material and its preparation, can solve the problems of short-term non-permanence, low development prospect, and reduced impact of composite materials, and achieve excellent resistance. Combustion characteristics, broad application prospects, and the effect of mechanical properties optimization
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Examples
Embodiment 1~2
[0026] Embodiment 1~2 proportioning (weight %) sees Table 1.
[0027] Table 1
[0028] raw material name
Example 1
Example 2
70
64
antistatic agent
8
10
flame retardant
18
23
Compatibilizer
4
3
168 / 1010(1∶1)
0.4
0.4
0.3
0.3
[0029] Put all the components in proportion into a high mixer and mix for 3 minutes, then use a screw extruder to extrude and granulate. The processing temperature is 210° C., and the screw rotation speed is 200 rpm.
[0030] A kind of halogen-free flame-retardant permanent antistatic polypropylene composite material sample 1 and sample 2 obtained in Examples 1 and 2 were compared in performance tests, and the mechanical properties were tested by ASTM.
[0031] The performance comparison of sample 1 and sample 2 is shown in Table 2.
[0032] Table 2
[0033] Test items
Embodiment 3
[0035] A preparation method of a halogen-free flame-retardant permanent antistatic polypropylene composite material, the method comprising the following steps:
[0036] (1) Weighing raw materials: 40% crystallinity, 40g of copolymerized polypropylene with a melt index of 15g / 10min, 15g of polyether ester amide polymer permanent antistatic agent, maleic anhydride grafted polypropylene (PP-g- MAH) 8g, less hygroscopic melamine urate or melamine polyphosphate 30g, 0.05g antioxidant 1010 and 0.05g antioxidant 168, 0.1g fatty acid lubricant;
[0037] (2) Put all the raw materials into the high mixer and mix for 2 minutes, then discharge;
[0038] (3) Put the homogeneously mixed raw materials into a twin-screw extruder to extrude and granulate. The rotating speed of the screw machine is 180-450 rpm and the temperature is 180-230°C.
Embodiment 4
[0040] A preparation method of a halogen-free flame-retardant permanent antistatic polypropylene composite material, the method comprising the following steps:
[0041] (1) Raw materials are weighed by weight: 70g of copolymerized polypropylene with a crystallinity of 60% and a melt index of 15g / 10min, 5g of polyether ester amide polymer permanent antistatic agent, maleic anhydride grafted polypropylene (PP -g-MAH) 1g, less hygroscopic melamine urate or melamine polyphosphate 5g, 0.25g antioxidant 1010 and 0.25g antioxidant 168, fatty acid lubricant 0.5g;
[0042] (2) Put all the raw materials into the high mixer and mix for 5 minutes, then discharge;
[0043] (3) Put the homogeneously mixed raw materials into a twin-screw extruder to extrude and granulate. The rotating speed of the screw machine is 180-450 rpm and the temperature is 180-230°C.
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