Rabdosia rubescens stem aqueous extract and its preparation method, finger-prints and use as anti-tumor agent
A technology of fingerprint spectrum and Rubescens rubescens, which is applied in the field involving the water extract, and can solve the problems that the effect is not related to the fingerprint spectrum, and has no anti-tumor effect.
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Embodiment 1
[0012] The preparation of embodiment 1 Stem Water Extract
[0013] Wash 40g of dried Radix japonicus stems with tap water, dry them in air, cut them into about 1cm long stems, add 1000-1800mL of hot distilled water at a temperature of 70-90°C, and infiltrate, preferably add 1200mL of hot steamed water at a temperature of 80°C Filtration with water. The outflow rate of the leachate is 10-30 mL / min, preferably 20 mL / min. The effluent was concentrated under reduced pressure at 40-60° C., preferably at 50° C., to obtain 3 g of water extract of Rubescens stalks as a light yellow solid. Grind into powder for later research use.
Embodiment 2
[0014] Example 2 HPLC-(-)ESI-Q-TOF-MS / MS fingerprints and HPLC-(+)ESI-Q-TOF-MS / MS fingerprints of Radix Grass Stem Water Extract
[0015] HPLC: Waters 2795Separations Module;
[0016] Detector: Waters 2489Dual absorbance detector;
[0017] Kromasil C 18 (Dikma) reversed-phase column (5_μm, 250_mm_×_4.6_mm);
[0018] Guard column (5_μm, 10_mm_×_4.6_mm);
[0019] Mobile phase: acetonitrile / water (containing 0.5% and 0.05% glacial acetic acid);
[0020] Mobile phase flow rate: 0.3ml / min;
[0021] Injection volume: 50μl;
[0022] Elution method: gradient elution (see Table 1 for specific gradient).
[0023] Table 1 Gradient table of mobile phase for HPLC-analysis of water extract of Bossium sativa a
[0024]
[0025] a A=acetonitrile, B=water (containing 0.05% glacial acetic acid, v / v), C=water (containing 0.5% glacial acetic acid, v / v)
[0026] The ion current fingerprints of the water extract of the stem of Rubescens japonicus under the detection of HPLC-(-)ESI-Q-TO...
Embodiment 3
[0027] The (-)ESI-Q-TOF-MS ion current fingerprint of embodiment 3 Stem water extract
[0028] (-)ESI-Q-TOF-MS: using an optimized small molecule analysis method, the specific parameters are a) Source Type: ESI; b) Ion Polarity: Negative; c) Scan begin: 50m / z; d) Scan begin: 1500m / z; e) Set Capillary: 3500V; f) Set Nebulizer: 0.8Bar; g) Set Dry Heater: 200℃; h) Set DryGas: 8.0ml / min; i) Funnel 1RF: 300Vpp; j) Funnel 2RF: 300Vpp; k) ISCID Energy: 0eV; l) Hexapole RF: 200Vpp; m) Ion Energy: 5eV; n) Low Mass: 200m / z; o) Collision Energy: 14eV; p) Collision RF: 140) Vpp; q) Transfer Time: 110.8μS; r) Pre Puls Storage: 8.7μS; s) Source: 1400v, 2nA; t) Calibrate the mass spectrometer with sodium formate before each analysis.
[0029] Applying the well-explored high-performance liquid chromatography conditions and the system-optimized mass spectrometry conditions, the (-)ESI-Q-TOF-MS analysis of the water extract of the Stem of Ornithus sativa was carried out by using the negative i...
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