Polyacetamide methylene maleate systhesis method
A technology of methylene maleate and a synthesis method, which is applied in the field of textile sizing, can solve the problems of uneven quality, uneven prices, and reduced loom efficiency, and achieves a suitable reaction mechanism, reduced reject rate, and improved loom efficiency. Effect
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Embodiment 1
[0014] Formula quantity: acetamide: 6g; hexamethylenetetramine: 6g; maleic anhydride: 5g; mineral acid: 0.7g; water: 65g.
[0015] Preparation Process:
[0016] (1) In the reaction kettle with jacket and reflux, put acetamide, water, hexamethylenetetramine and other substances specified in the formula, start stirring and steaming, and raise the temperature to 60°C;
[0017] (2) At 60°C, add inorganic acid as a catalyst, and react for 3 hours to generate cyclic acetamide hydroxymethyl derivatives;
[0018] (3) At 40°C, use one or several inorganic acids to convert the system H + Adjust the content to 3;
[0019] (4) At 120°C, add maleic anhydride dropwise, complete the dropwise addition within 0.5h, and control the temperature at 120°C;
[0020] (5) At 120°C, continue the heat preservation reaction until there is no residual monomer in the system;
[0021] (6) Cool down to room temperature to obtain textile auxiliaries.
Embodiment 2
[0023] Formula quantity: acetamide: 15g; hexamethylenetetramine: 15g; maleic anhydride: 20g; inorganic acid: 5g; water: 85g
[0024] Preparation Process:
[0025] (1) In the reaction kettle with jacket and reflux, put acetamide, water, hexamethylenetetramine and other substances specified in the formula, start stirring and steaming, and raise the temperature to 90°C;
[0026] (2) At 90°C, add inorganic acid as a catalyst, and react for 3 hours to form a cyclic acetamide hydroxymethyl derivative;
[0027] (3) At 65°C, use one or several inorganic acids to convert the system H + Adjust the content to 6;
[0028] (4) At 150°C, add maleic anhydride dropwise, complete the dropwise addition within 3 hours, and control the temperature at 150°C;
[0029] (5) At 150°C, continue the heat preservation reaction until the system no longer has residual monomers;
[0030] (6) Cool down to room temperature to obtain textile auxiliaries.
Embodiment 3
[0032] Formula quantity: acetamide: 10g; hexamethylenetetramine: 10g; maleic anhydride: 13g; inorganic acid: 2.5g; water: 75g.
[0033] Preparation Process:
[0034] (1) In the reaction kettle with jacket and reflux, put acetamide, water, hexamethylenetetramine and other substances specified in the formula, start stirring and steaming, and raise the temperature to 75°C;
[0035] (2) At 75°C, add inorganic acid as a catalyst, and react for 3 hours to generate a cyclic acetamide hydroxymethyl derivative;
[0036] (3) At 55°C, use one or several inorganic acids to convert the system H + Adjust the content to 4;
[0037] (4) At 130°C, add maleic anhydride dropwise, complete the dropwise addition within 0.5-3 hours, and control the temperature at 135°C;
[0038] (5) At 135°C, continue the heat preservation reaction until there are no more residual monomers in the system;
[0039] (6) Cool down to room temperature to obtain textile auxiliaries.
[0040] In the production proces...
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