Method for preparing novel denitration catalyst
A denitrification catalyst, a new type of technology, applied in the direction of catalyst activation/preparation, chemical instruments and methods, physical/chemical process catalysts, etc., can solve the problems of high raw material cost for carrier manufacturing and increased catalyst preparation cost, etc.
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Embodiment 1
[0028] Embodiment 1 Preparation method steps are:
[0029] A, attapulgite 25wt%, bentonite 8%wt%, alumina powder 15wt%, 4A molecular sieve 42wt%, diatomaceous earth 5.5wt% and methyl cellulose 4.5wt% are mixed into powder;
[0030] B. The powder is kneaded, vacuum smelted, stale, extruded, and dried to make a carrier semi-finished product, and then the semi-finished product is fired into a carrier at a temperature of 500°C~700°C with an oxidizing flame in a kiln;
[0031] C. Put ammonium metavanadate and ammonium metatungstate into hot water at a temperature of 88°C at a ratio of 16% by weight of hot water and 8% by weight of hot water, and stir slowly until they are fully dissolved;
[0032] D, take water as solvent, prepare 25% ethanol solution and nitric acid solution of ethanol solution weight 28%, ethanol solution and nitric acid solution are mixed to form mixed solution, then add mixed solution gross weight 24% titanate in mixed solution, Constantly stir the solution to...
Embodiment 2
[0036] Embodiment 2 preparation method steps are:
[0037] A, attapulgite 18wt%, bentonite 5%wt%, alumina powder 30wt%, 4A molecular sieve 41wt%, diatomaceous earth 2.5wt% and methyl cellulose 3.5wt% are mixed into powder;
[0038] B. The powder is kneaded, vacuum smelted, stale, extruded, and dried to make a carrier semi-finished product, and then the semi-finished product is fired into a carrier at a temperature of 500°C~700°C with an oxidizing flame in a kiln;
[0039] C. Put ammonium metavanadate and ammonium metatungstate into hot water at a temperature of 86°C at a ratio of 5% by weight of hot water and 25% by weight of hot water, and stir slowly until they are fully dissolved;
[0040] D. Using water as a solvent, prepare 78% ethanol solution and 10% carboxylic acid solution by weight of the ethanol solution, mix the ethanol solution and carboxylic acid solution to form a mixed solution, and then add 12% titanic acid by total weight of the mixed solution to the mixed so...
Embodiment 3
[0048] Embodiment 3 preparation method steps are:
[0049] a, attapulgite 12wt%, bentonite 15%wt%, alumina powder 10wt%, 4A molecular sieve 53wt%, diatomite 9wt% and hydroxypropyl methylcellulose 1wt% are mixed into powder;
[0050] b. Weigh 20% of the weight of the powder in deionized water and heat it to 83°C, and maintain this temperature;
[0051] c. Weigh 1.8% and 4% ammonium metavanadate and ammonium metatungstate, respectively, of the weight of the powder that removed the weight of the auxiliary agent in step a, add them to the hot water in step b, and keep stirring to make them fully dissolve. into solution;
[0052] d. Add the powder obtained in step a and the solution obtained in step c into the kneader, stir for 1-2 hours, then heat and vacuumize to make mud;
[0053] e. Send the mud made in step d into the stale room to seal and stale for 24 hours. When stale, control the relative humidity of the environment at 70-75%, and the temperature at 20-30°C;
[0054] f....
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