PTC (Positive Temperature Coefficient) macromolecular composite heating material based on iron and copper powder and preparation method thereof

A heating material and polymer technology, which is applied in the field of polymer-based PTC heating materials and its preparation, can solve the problems of low PTC strength, wide room temperature resistance distribution, and low stability, and achieve increased service life, stable PTC characteristics, and high Effect of PTC stability

Inactive Publication Date: 2013-09-18
ANBANG ELECTRICAL GRP
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AI Technical Summary

Problems solved by technology

The current organic PTC materials mainly use graphite and carbon black as conductive fillers, which mainly

Method used

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Embodiment Construction

[0009] The PTC polymer heating material based on iron powder and copper powder is made of the following raw materials in parts by weight (kg): polycaprolactam 30, low-density polyethylene 50, iron powder 25, copper powder 15, aluminum nitride 25, wheat Rice stone powder 10, decabromodiphenylethane 5, silicon dioxide 12, zinc fluoride 6, clay 14, methyltriethoxysilane 4, N-(β-aminoethyl)-γ-aminopropyltrimethyl (B) Oxysilane 3, Epoxy Dioctyl Tetrahydrophthalate 5, Sodium Dihydrogen Phosphate 2.

[0010] The preparation method of the PTC polymer heating material based on the composite of iron powder and copper powder comprises the following steps: adding water to low-density polyethylene and stirring to form a suspension, then adding copper powder and aluminum nitride, and dispersing at high speed for 10-20 minutes, Add silicon dioxide, zinc fluoride, dioctyl epoxy tetrahydrophthalate, N-(β-aminoethyl)-γ-aminopropyltrimethyl(ethyl)oxysilane, stir well, and put in Grinding at 80-...

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Abstract

The invention discloses a PTC (Positive Temperature Coefficient) macromolecular composite heating material based on iron and copper powder. The PTC macromolecular composite heating material is prepared from the following raw materials in parts by weight: 20-30 parts of polycaprolactam, 50-55 parts of low-density polyethylene, 20-25 parts of iron powder, 10-15 parts of copper powder, 20-25 parts of aluminum nitride, 10-15 parts of maifanite powder, 3-5 parts of decabromodiphenyl ethane, 10-12 parts of silica, 4-6 parts of zinc fluoride, 12-14 parts of argil, 4-6 parts of methyl triethoxysilane, 3-4 parts of N-(beta-aminoethyl)-gamma-aminopropyl trimeth(eth)oxysilane, 5-6 parts of epoxy tetrahydro-dioctyl phthalate and 1-2 parts of sodium dihydrogen phosphate. The PTC macromolecular composite heating material and the preparation method thereof have the advantages that the PTC strength and PTC stability of the material are improved greatly, the resistance is stable, the temperature is uniform, the PTC characteristic is stable, and the service life of the material is prolonged.

Description

technical field [0001] The invention belongs to the field of polymer materials, and in particular relates to a polymer-based PTC heating material and a preparation method thereof. Background technique [0002] PTC polymer heating materials are widely used in communication, computer, automobile, industrial control, household appliances and many other fields as overheating, overcurrent protection and self-control heating materials. The current organic PTC materials mainly use graphite and carbon black as conductive fillers, which mainly have problems such as wide distribution of room temperature resistance, low PTC strength, and low stability. Contents of the invention [0003] The purpose of the present invention is to provide a PTC polymer heating material based on iron powder and copper powder and its preparation method, which has low room temperature resistivity, long-term stable flow performance, high PTC strength and high PTC stability . [0004] Technical scheme of ...

Claims

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Application Information

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IPC IPC(8): C08L23/06C08L77/02C08K13/02C08K3/08C08K3/28C08K3/36C08K3/34C08K5/544C08K3/32
Inventor 李贻连
Owner ANBANG ELECTRICAL GRP
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