Degradable temporary plugging ball and preparation method thereof

A technology of temporarily blocking balls and degradable materials, applied in the direction of single-component copolyester artificial filaments, etc., can solve the problems of difficult steering, non-degradation of plastic balls, difficulties, etc., and achieve good mechanical strength and elasticity, good compression resistance and Effective degradation and easy control of the reaction process

Active Publication Date: 2015-04-15
四川川庆井下科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The advantage of tool physical delamination is accurate delamination, but there are problems such as only large-section (greater than 10m) delamination, complex tool string and subsequent operation difficulties; the advantage of fiber physical diversion is that it can reduce the pressure difference of acid suction Reservoirs with 8MPa can be diverted and transformed, but there are disadvantages such as difficulty in realizing diversion in productive layers with a stress difference greater than 8MPa and complicated pumping process; physical diversion of plastic balls has the obvious advantages of blocking blastholes and diverting, but this plastic ball does not degrade , it is easy to block the process in the later stage of drainage; diverting acid chemical diversion can realize diversion transformation for reservoirs with acid suction pressure difference less than 5MPa, but it is difficult to realize diversion for productive layers with stress difference greater than 5MPa

Method used

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  • Degradable temporary plugging ball and preparation method thereof
  • Degradable temporary plugging ball and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] A degradable temporary blocking ball consists of the following formula (calculated by weight):

[0036] 65 parts of terephthalic acid; 75 parts of ethylene glycol; 15 parts of 1,4-butanedioic acid; 1 part of 1,3-propylene glycol; 3 parts of 1,4-benzenediol; 0.4 parts of ferric chloride; 0.2 parts of formaldehyde, 41 parts of water.

[0037] The preparation method of the degradable temporary blocking ball includes the following contents (produced in batches of 200kg):

[0038] (1) The preparation steps of the temporary plugging ball are as attached figure 1Shown: Preparation of degradable material: ① 32 parts by weight of terephthalic acid and 38 parts of ethylene glycol are esterified at 250°C, and 15 parts by weight of 1,4-butanediol are added acid, stirring, to obtain an esterification product; adding 1 part by weight of 1,3-propanediol to the esterification product for copolymerization, controlling the final vacuum to 150MPa, and reacting for 3 hours to obt...

Embodiment 2

[0047] A degradable temporary blocking ball consists of the following formula (calculated by weight):

[0048] 64 parts of terephthalic acid; 76 parts of ethylene glycol; 14 parts of 1,4-butanedioic acid; 2 parts of 1,3-propylene glycol; 3 parts of 1,4-benzenediol; 0.4 parts of ferric chloride; 0.2 parts of formaldehyde, 41 parts of water.

[0049] The preparation method of the degradable temporary blocking ball includes the following contents (produced in batches of 200kg):

[0050] The preparation steps of temporary blocking ball are as attached figure 1 Shown:

[0051] 1. Preparation of degradable materials:

[0052] a. In a clean reactor, first add 14kg of clear water, heat up to 30-40°C, add 30kg of terephthalic acid and 40kg of ethylene glycol while stirring, control the addition within 30 minutes, and stir until completely dissolved after adding, Add 14 kg of 1,4-butanedioic acid, raise the temperature to 250° C., stir at a constant temperature, then add 2 k...

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Abstract

The invention discloses a degradable temporary plugging wall and a preparation method thereof. The method comprises the following steps: esterifying and polymerizing water, terephthalic acid, ethylene glycol, 1,4-succinic acid, 1,3-propylene glycol and 1,4-hydroquinone; processing and grinding into balls in later phase to obtain a finished product. According to the degradable temporary plugging ball prepared by the preparation method provided by the invention, a blasthole can be plugged, working fluid is enforced to turn to other reforming layers, so that the degradable temporary plugging ball has the remarkable advantage of remarkable turning effect, and is easy to operate. After the construction is completed, the temperature of the stratum can be recovered, the temporary plugging wall is hydrolyzed into water-soluble acid and alcohol, and is drained with other fluids, so that the clean reformation of the stratum can be achieved, and longitudinal physical layering reformation can be realized, and the risk of ground flow plugging can be reduced. The degradable temporary plugging ball can be used in testing and completion stages.

Description

technical field [0001] The invention belongs to the technical field of oil testing engineering, and in particular relates to a degradable temporary plugging ball and a preparation method thereof. Background technique [0002] With the development of oil testing engineering technology, in the case of running a simple completion string, there is an increasing demand for simple and fast steering methods to achieve three-dimensional reconstruction. [0003] At present, the methods used to deal with complex reservoirs and strong heterogeneity in the vertical direction include: tool physical layering, fiber physical steering, plastic ball physical steering, and acid chemical steering to carry out vertical three-dimensional reconstruction. [0004] The advantage of tool physical delamination is accurate delamination, but there are problems such as only large-section (greater than 10m) delamination, complex tool string and subsequent operation difficulties; the advantage of fiber p...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L67/03C08L59/02C08K3/16C08G63/191C08G63/183D01F6/84
Inventor 管彬陈英田亚莉李嘉周怡陈锐陆丽王亚南张晓虎牟泽知孙亚东
Owner 四川川庆井下科技有限公司
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