Degradable temporary plugging ball and preparation method thereof
A technology of temporarily blocking balls and degradable materials, applied in the direction of single-component copolyester artificial filaments, etc., can solve the problems of difficult steering, non-degradation of plastic balls, difficulties, etc., and achieve good mechanical strength and elasticity, good compression resistance and Effective degradation and easy control of the reaction process
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Embodiment 1
[0035] A degradable temporary blocking ball consists of the following formula (calculated by weight):
[0036] 65 parts of terephthalic acid; 75 parts of ethylene glycol; 15 parts of 1,4-butanedioic acid; 1 part of 1,3-propylene glycol; 3 parts of 1,4-benzenediol; 0.4 parts of ferric chloride; 0.2 parts of formaldehyde, 41 parts of water.
[0037] The preparation method of the degradable temporary blocking ball includes the following contents (produced in batches of 200kg):
[0038] (1) The preparation steps of the temporary plugging ball are as attached figure 1Shown: Preparation of degradable material: ① 32 parts by weight of terephthalic acid and 38 parts of ethylene glycol are esterified at 250°C, and 15 parts by weight of 1,4-butanediol are added acid, stirring, to obtain an esterification product; adding 1 part by weight of 1,3-propanediol to the esterification product for copolymerization, controlling the final vacuum to 150MPa, and reacting for 3 hours to obt...
Embodiment 2
[0047] A degradable temporary blocking ball consists of the following formula (calculated by weight):
[0048] 64 parts of terephthalic acid; 76 parts of ethylene glycol; 14 parts of 1,4-butanedioic acid; 2 parts of 1,3-propylene glycol; 3 parts of 1,4-benzenediol; 0.4 parts of ferric chloride; 0.2 parts of formaldehyde, 41 parts of water.
[0049] The preparation method of the degradable temporary blocking ball includes the following contents (produced in batches of 200kg):
[0050] The preparation steps of temporary blocking ball are as attached figure 1 Shown:
[0051] 1. Preparation of degradable materials:
[0052] a. In a clean reactor, first add 14kg of clear water, heat up to 30-40°C, add 30kg of terephthalic acid and 40kg of ethylene glycol while stirring, control the addition within 30 minutes, and stir until completely dissolved after adding, Add 14 kg of 1,4-butanedioic acid, raise the temperature to 250° C., stir at a constant temperature, then add 2 k...
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