A method for comprehensive utilization of lignocellulose

A technology of lignocellulose and lignocellulose, applied in the field of biomass refining engineering, can solve the problems of low raw material utilization rate, small production scale, random discharge, etc., and reduce the probability of secondary condensation reaction and subsequent separation The difficulty, the production process is energy-saving and efficient, and there is no effect of three wastes

Active Publication Date: 2016-02-24
A ZENITH HOME FURNISHINGS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The traditional furfural industry is a resource-consuming, labor-intensive, and environment-polluting industry. The production scale of furfural manufacturers in my country is generally small, and most of them are produced by one-step hydrolysis of sulfuric acid. A large amount of waste residues are produced during the process, or they are discharged randomly, or directly burned, all of which have caused huge environmental pollution problems. Therefore, furfural production enterprises in my country are facing huge environmental protection problems, and the furfural industry is in urgent need of technological upgrading.
Although there are some improvement measures for the above problems at present, such as the invention patent application number 200810305612.6 "No pollution production of furfural, acetic acid, activated carbon energy-saving new process", but still use dilute sulfuric acid impregnation, high-pressure steam hydrolysis, mixed collection of crude aldehyde vapor, The problems of high energy consumption, high water consumption and high emission are still prominent in processes such as fractional distillation and high-temperature carbonization

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Example 1: Preparation of a series of green chemicals by microwave-assisted catalytic rice husk pyrolysis.

[0019] Take 2kg of rice husk to remove impurities, crush it into particles of about 1~2mm, spray it with 0.5kg of phosphoric acid solution with a mass fraction of 15%, and let it stand for 24 hours, then send it to a microwave pyrolysis device to confirm the gas content of the system. Tightness, using a small vacuum pump to maintain the system at a weak negative pressure of about -10Kpa; the first step is to set the microwave power to 5KW, control the reaction temperature to ≤120°C, keep it for 14min, and condense and collect 0.72kg of crude acetic acid for further purification; In the second step, set the microwave power to 7.5KW, increase the reaction temperature to ≤170°C, keep it for 8 minutes, and collect 0.22kg of crude furfural produced by condensation for further purification; after collecting the pyrolysis residual bio-coke, use a small amount of multiple...

Embodiment 2

[0020] Example 2: Preparation of a series of green chemicals by microwave-assisted catalytic corncob pyrolysis.

[0021] Take 2kg of corn cob after removing impurities, crush it into particles of about 1~2mm, spray it with 0.5kg of phosphoric acid solution with a mass fraction of 15%, and put it into a microwave pyrolysis device after standing for 12 hours to confirm the stability of the system. Airtightness, using a small vacuum pump to maintain the system at a weak negative pressure of about -10Kpa; the first step is to set the microwave power to 5KW, control the reaction temperature to ≤120°C, keep it for 14min, and condense and collect 0.74kg of crude acetic acid for further purification; In the second step, set the microwave power to 7.5KW, increase the reaction temperature to ≤170°C, keep it for 9 minutes, and collect 0.36kg of crude furfural produced by condensation for further purification; The bio-coke was leached with water, and the solid-liquid ratio was set to 1:3,...

Embodiment 3

[0022] Example 3: Microwave-assisted catalytic pyrolysis of bamboo chips to prepare a series of green chemicals.

[0023]Take 2kg of bamboo chips after removing impurities, crush them into particles of about 1~2mm, spray them with 0.4kg of phosphoric acid solution with a mass fraction of 12%, and after standing for 24 hours, send them to a microwave pyrolysis device to confirm the stability of the system. Airtightness, using a small vacuum pump to maintain the system at a weak negative pressure of about -10Kpa; the first step is to set the microwave power to 5KW, control the reaction temperature to ≤120°C, keep it for 12min, and condense and collect 0.62kg of crude acetic acid for further purification; In the second step, set the microwave power to 7.5KW, increase the reaction temperature to ≤170°C, keep it for 8 minutes, and collect 0.24kg of crude furfural produced by condensation for further purification; Bio-coke was leached with water, the solid-liquid ratio was set to 1:...

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Abstract

A comprehensive utilization method of lignocelluloses comprises the following steps: performing acidation pretreatment on lignocelluloses with phosphoric acid solution; adopting microwave as a heat source of a pyrolytic reaction so as to exert an auxiliary function of accelerating the organic reaction; controlling the progress of the reaction through regulating the temperature of the lignocelluloses pyrolytic reaction via controlling the microwave power; condensing and collecting liquid pyrolysis products acetic acid and furfuraldehyde according to phrases; extracting the residual biomass semicoke through water-ultrasonic extraction to obtain carbohydrate and plant nutrition salt; manufacturing low sulfur smoke-free biomass honeycomb briquette through biomass semicoke. According to the invention, three main components of the lignocelluloses biomass are subject to pyrolysis according to chemical reactivity; the probability of secondary condensation reaction of the pyrolysis product and the difficulty in follow-up separation are both reduced; the manufacturing technology saves energy and is efficient; no 'three wastes' are generated; a new approach is provided for compositive and efficient utilization of bulk and cheap biomass of agriculture and forestry.

Description

technical field [0001] The invention belongs to the technical field of biomass refining engineering. It involves comprehensive utilization of lignocellulose. Background technique [0002] With the depletion of fossil energy, human beings have to face the increasingly serious energy crisis and chemical resource crisis. Searching for clean and renewable energy and green chemicals has become the focus of research in various countries. Biomass resources, as a cheap, easy-to-obtain and widely sourced renewable resource, have great potential for development and application. Researchers from all over the world have conducted active exploration and experimental research on the utilization of biomass resources, and have achieved certain research results. . However, these studies often focus on a certain aspect of the utilization of biomass resources, which belongs to the way of "separate efforts" and does not comprehensively utilize biomass resources. Therefore, the present invent...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C07D307/50C07C53/08C07C51/00C01B25/26C13K1/02C13K13/00C10L5/44
CPCY02E50/10Y02E50/30
Inventor 刘玉环王允圃阮榕生李筠刘童莹万益琴姚远
Owner A ZENITH HOME FURNISHINGS CO LTD
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