A method for comprehensive utilization of lignocellulose
A technology of lignocellulose and lignocellulose, applied in the field of biomass refining engineering, can solve the problems of low raw material utilization rate, small production scale, random discharge, etc., and reduce the probability of secondary condensation reaction and subsequent separation The difficulty, the production process is energy-saving and efficient, and there is no effect of three wastes
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Embodiment 1
[0018] Example 1: Preparation of a series of green chemicals by microwave-assisted catalytic rice husk pyrolysis.
[0019] Take 2kg of rice husk to remove impurities, crush it into particles of about 1~2mm, spray it with 0.5kg of phosphoric acid solution with a mass fraction of 15%, and let it stand for 24 hours, then send it to a microwave pyrolysis device to confirm the gas content of the system. Tightness, using a small vacuum pump to maintain the system at a weak negative pressure of about -10Kpa; the first step is to set the microwave power to 5KW, control the reaction temperature to ≤120°C, keep it for 14min, and condense and collect 0.72kg of crude acetic acid for further purification; In the second step, set the microwave power to 7.5KW, increase the reaction temperature to ≤170°C, keep it for 8 minutes, and collect 0.22kg of crude furfural produced by condensation for further purification; after collecting the pyrolysis residual bio-coke, use a small amount of multiple...
Embodiment 2
[0020] Example 2: Preparation of a series of green chemicals by microwave-assisted catalytic corncob pyrolysis.
[0021] Take 2kg of corn cob after removing impurities, crush it into particles of about 1~2mm, spray it with 0.5kg of phosphoric acid solution with a mass fraction of 15%, and put it into a microwave pyrolysis device after standing for 12 hours to confirm the stability of the system. Airtightness, using a small vacuum pump to maintain the system at a weak negative pressure of about -10Kpa; the first step is to set the microwave power to 5KW, control the reaction temperature to ≤120°C, keep it for 14min, and condense and collect 0.74kg of crude acetic acid for further purification; In the second step, set the microwave power to 7.5KW, increase the reaction temperature to ≤170°C, keep it for 9 minutes, and collect 0.36kg of crude furfural produced by condensation for further purification; The bio-coke was leached with water, and the solid-liquid ratio was set to 1:3,...
Embodiment 3
[0022] Example 3: Microwave-assisted catalytic pyrolysis of bamboo chips to prepare a series of green chemicals.
[0023]Take 2kg of bamboo chips after removing impurities, crush them into particles of about 1~2mm, spray them with 0.4kg of phosphoric acid solution with a mass fraction of 12%, and after standing for 24 hours, send them to a microwave pyrolysis device to confirm the stability of the system. Airtightness, using a small vacuum pump to maintain the system at a weak negative pressure of about -10Kpa; the first step is to set the microwave power to 5KW, control the reaction temperature to ≤120°C, keep it for 12min, and condense and collect 0.62kg of crude acetic acid for further purification; In the second step, set the microwave power to 7.5KW, increase the reaction temperature to ≤170°C, keep it for 8 minutes, and collect 0.24kg of crude furfural produced by condensation for further purification; Bio-coke was leached with water, the solid-liquid ratio was set to 1:...
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