Nano catalytic viscosity reducer for thickened oil aqua-thermolysis and preparation method thereof

A technology of nano-catalysis and viscosity reducer, which is applied in the direction of chemical instruments and methods, drilling compositions, etc., can solve the problems of reduced catalytic activity of super-acid catalysts in contact with water, difficulty in field promotion and application, and poor contact with crude oil, etc., to achieve Viscosity reduction, good viscosity reduction effect, and the effect of increasing the hydrogen-to-carbon atomic ratio

Active Publication Date: 2013-12-04
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Solid heteropolyacids, superacid catalysts reduce catalytic activity when exposed to water
Moreover, some of the hydrothermal catalytic cracking viscosity reducers reported in the literature have the disadvantages of high operating temperature (greater than or equal to 240 ° C), poor universality, and poor contact with crude oil, so it is difficult to popularize and apply them in the field

Method used

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  • Nano catalytic viscosity reducer for thickened oil aqua-thermolysis and preparation method thereof
  • Nano catalytic viscosity reducer for thickened oil aqua-thermolysis and preparation method thereof
  • Nano catalytic viscosity reducer for thickened oil aqua-thermolysis and preparation method thereof

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Effect test

Embodiment 1

[0040] Nano-catalyzed viscosity reducer for hydrothermal cracking of heavy oil and preparation method thereof, comprising the following steps:

[0041]1) Selection of raw materials: iron salt: 2 parts by weight; solvent: 12 parts by weight; alcohol: 7 parts by weight; reducing agent: 6 parts by weight; alkali solution: 105 parts by weight; sulfonic acid: 55 parts by weight; distilled water: 100 parts by weight share. The iron salt is ferric nitrate, analytically pure, produced by Tianjin Jinhui Taiya Chemical Reagent Co., Ltd.; the alkaline solution is potassium hydroxide solution, with a concentration of 1mol / L, analytically pure, produced by Sinopharm Chemical Reagent Co., Ltd. ; Described solvent is n-heptane, analytically pure, produced by Sinopharm Chemical Reagent Co., Ltd.; described alcohol is n-butanol, analytically pure, produced by Beijing Yili Fine Chemicals Co., Ltd.; described reducing agent is boron Sodium hydride, analytically pure, produced by Kemiou Chemical...

Embodiment 2

[0045] Nano-catalyzed viscosity reducer for hydrothermal cracking of heavy oil and preparation method thereof, comprising the following steps:

[0046] 1) Selection of raw materials: cobalt salt: 15 parts by weight; solvent: 125 parts by weight; alcohol: 75 parts by weight; reducing agent: 82 parts by weight; alkaline solution: 300 parts by weight; sulfonic acid: 150 parts by weight; distilled water: 100 parts by weight share. The cobalt salt is cobalt sulfate, analytically pure, produced by Beijing Kangpu Huiwei Chemical Co., Ltd.; the alkali solution is sodium hydroxide solution, with a concentration of 2mol / L, analytically pure, produced by Sinopharm Chemical Reagent Co., Ltd.; The solvent is xylene, analytically pure, produced by Beijing Yili Fine Chemicals Co., Ltd.; the alcohol is n-amyl alcohol, analytically pure, produced by Beijing Yili Fine Chemicals Co., Ltd.; the reducing agent is hydration Hydrazine, analytically pure, produced by Kemiou Chemical Reagents; the su...

Embodiment 3

[0050] Nano-catalyzed viscosity reducer for hydrothermal cracking of heavy oil and preparation method thereof, comprising the following steps:

[0051] 1) Selection of raw materials: nickel salt: 24 parts by weight; solvent: 85 parts by weight; alcohol: 77 parts by weight; reducing agent: 79 parts by weight; alkali solution: 310 parts by weight; sulfonic acid: 181 parts by weight; distilled water: 100 parts by weight share. The nickel salt is nickel chloride, analytically pure, produced by Beijing Century Oriental Chemical Co., Ltd.; the alkali solution is sodium hydroxide solution, with a concentration of 3mol / L, analytically pure, produced by Sinopharm Chemical Reagent Co., Ltd.; The solvent described is toluene, produced by Kemiou Chemical Reagents; the alcohol described is n-amyl alcohol, analytically pure, produced by Beijing Yili Fine Chemicals Co., Ltd.; the reducing agent is potassium borohydride, analytically pure, produced by Kemiou Produced by European chemical rea...

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Abstract

The invention discloses a nano catalytic viscosity reducer for thickened oil aqua-thermolysis and a preparation method thereof. The catalytic viscosity reducer is prepared from following materials in parts by weight: 1 to 50 parts of metal salt, 10 to 200 parts of solvent, 5 to 150 parts of alcohol, 5 to 150 parts of reducing agent, 100 to 500 parts of alkali solution, 50 to 300 parts of sulfonic acid, and 100 parts of distilled water through reduction reactions, wherein the sizes of the viscosity reducer are in the range of 1 to 10 nm. The nano catalytic viscosity reducer for thickened oil aqua-thermolysis has the characteristics of strong universality, and good viscosity reducing effect, and is capable of catalyzing thickened oil to carry out catalytic cracking reactions in a lower temperature (not larger than 200 DEG C). The viscosity of thickened oil is largely reduced after the reactions, and the viscosity reducing rate reaches 80% or more.

Description

technical field [0001] The invention relates to the field of heavy oil exploitation, and more particularly relates to a heavy oil hydrothermolysis nano catalytic viscosity reducer and a preparation method thereof. Background technique [0002] The world's oil consumption is increasing year by year, but the recoverable oil reserves are decreasing year by year, especially the reserves of easy-to-recover thin oil are getting less and less. The world's energy crisis is becoming more and more serious. Many countries have raised the oil problem to the height of national security. . There are huge reserves of heavy oil in the world. In order to alleviate the tension of energy and maintain the continuous increase of oil production, the exploitation and utilization of heavy oil have attracted extensive attention, especially in our country. The exploitation of heavy oil has more realistic and urgent significance. . [0003] At present, several heavy oil recovery methods have been de...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/592
Inventor 吴川苏建政石在虹赵梦云龙秋莲王益维
Owner CHINA PETROLEUM & CHEM CORP
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