Method for recovering iron, vanadium and titanium from schreyerite through shaft furnace reduction and electric furnace smelting and separating deep reduction

A technology for vanadium-titanium ore and iron recovery, applied in shaft furnaces, furnaces, furnace types, etc., can solve the problems of long reduction time, road transportation pressure, economic waste, etc., achieve high smelting efficiency, reduce dependence, and improve recovery rate Effect

Active Publication Date: 2013-12-18
TAIHE IRON MINE CHONGQING IRON & STEEL GROUP MINING +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

First, because of its strong dependence on metallurgical coke, although more than 6 billion tons of coal resources have been proven in the Panxi region, only 1 billion tons of coking coal can be used for metallurgical production, and 5 billion tons of non-coking coal cannot be used nearby
As a result, on the one hand, a large amount of metallurgical coal had to be purchased from other places, and on the other hand, Panxi African coking coal had to be shipped to various places, which not only caused a lot of economic waste, but also caused great pressure on road transportation
The second is that the process has a low comprehensive recycling capacity when dealing with polymetallic symbiotic ores
Due to the characteristics of vanadium and titanium resources and the resulting technical obstacles, this process can only recover ...

Method used

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  • Method for recovering iron, vanadium and titanium from schreyerite through shaft furnace reduction and electric furnace smelting and separating deep reduction
  • Method for recovering iron, vanadium and titanium from schreyerite through shaft furnace reduction and electric furnace smelting and separating deep reduction

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Embodiment 1

[0020] Embodiment 1: As shown in the figure, the method of shaft furnace reduction of vanadium-titanium ore in this embodiment-electric furnace melting deep reduction to recover iron, vanadium and titanium includes the production of vanadium-titanium oxide pellets, direct reduction of vanadium-titanium oxide pellets, metal Melting pelletizing electric furnace, extracting vanadium from molten iron containing vanadium, melting titanium slag to produce titanium dioxide and vanadium slag to produce V 2 o 5 ,

[0021] a. Production of vanadium-titanium oxide pellets: mix vanadium-titanium iron concentrate with binder and water to form pellets, in terms of mass percentage: vanadium-titanium iron concentrate with a particle size of less than 0.074 mm accounts for 80% %, in the mixed pelletizing raw material composed of vanadium-titanium iron concentrate, binder and water: binder accounts for 1.0%, water accounts for 6.5%; the diameter of the pellets is 10mm, and the pellets are preh...

Embodiment 2

[0033] Embodiment 2: The method of shaft furnace reduction of vanadium-titanium ore in this embodiment-electric furnace melting deep reduction to recover iron, vanadium and titanium, including production of vanadium-titanium oxide pellets, direct reduction of vanadium-titanium oxide pellets, and electric furnace melting of metallized pellets Extraction of vanadium from molten iron containing vanadium, melting titanium slag to produce titanium dioxide and vanadium slag to produce V 2 o 5 ,

[0034] a. Production of vanadium-titanium oxide pellets: Mix vanadium-titanium iron concentrate with binder and water to form pellets. In terms of mass percentage: vanadium-titanium iron concentrate with a particle size of less than 0.074 mm accounts for 82.5% of the vanadium-titanium iron concentrate %, in the mixed pelletizing raw material composed of vanadium-titanium iron concentrate, binder and water: binder accounts for 1.5%, water accounts for 7%; the diameter of the pellets is 15mm...

Embodiment 3

[0046] Embodiment 3: The method of shaft furnace reduction of vanadium-titanium ore in this embodiment-electric furnace melting deep reduction to recover iron, vanadium and titanium, including production of vanadium-titanium oxide pellets, direct reduction of vanadium-titanium oxide pellets, electric furnace melting of metallized pellets Extraction of vanadium from molten iron containing vanadium, melting titanium slag to produce titanium dioxide and vanadium slag to produce V 2 o 5 ,

[0047] a. Production of vanadium-titanium oxide pellets: Mix vanadium-titanium iron concentrate with binder and water to form pellets. In terms of mass percentage: vanadium-titanium iron concentrate with a particle size of less than 0.074 mm accounts for 85% %, in the mixed pelletizing raw material composed of vanadium-titanium iron concentrate, binder and water: binder accounts for 2.0%, water accounts for 7.5%; pellets;

[0048] b. Direct reduction of vanadium-titanium oxide pellets: load ...

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Abstract

The invention discloses a method for recovering iron, vanadium and titanium from schreyerite through shaft furnace reduction and electric furnace smelting and separating deep reduction. The method comprises the following steps of: producing a vanadium-titanium oxidized pellet; directly reducing the vanadium-titanium oxidized pellet; smelting and separating a metalized pellet through an electric furnace; extracting vanadium from molten vanadium-containing iron; smelting and separating titanium slag to manufacture titanium dioxide; smelting and separating vanadium slag to manufacture V2O5. According to the method, coal gas, converted coke oven gas or natural gas is used as a reducing agent to reduce original vanadium titanium magnetite, so that the dependency of the traditional blast furnace process to coking coal can be greatly reduced, and diversification of metallurgical energy is realized; by adopting the process, the vanadium titanium magnetite can be smelted completely; mixed smelting of common iron ore and vanadium titanium magnetite is not needed, so that the smelting efficiency is higher; titanium dioxide in the smelted and separated titanium slag produced in smelting accounts for more than 50%, therefore, the slag can be directly used as the raw material for preparing titanium dioxide, and as a result, the recovery rate of vanadium, titanium and iron can be raised; simultaneously, the smelted and separated titanium slag and vanadium slag can be directly utilized, thus the environmental pollution and land resource occupation caused by piling and storing the slag can be avoided.

Description

technical field [0001] The invention relates to a smelting process, in particular to a smelting process for vanadium-titanium ore. Background technique [0002] The reserves of vanadium-titanium magnetite in Panxi area are more than 10 billion tons, and it is rich in various useful elements such as iron, vanadium and titanium, and has extremely high comprehensive utilization value. After more than 40 years of development, the region has formed a production capacity of more than 10 million tons of vanadium-titanium magnetite concentrate, but the utilization of vanadium-titanium magnetite is still the traditional "blast furnace-converter" process. and huge production capacity, etc., but there are still inherent deficiencies. First, because of its strong dependence on metallurgical coke, although more than 6 billion tons of coal resources have been proven in the Panxi area, only 1 billion tons of coking coal can be used for metallurgical production, and 5 billion tons of non-c...

Claims

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Application Information

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IPC IPC(8): C22B1/24C22B1/214C22B34/22C22B34/12C21B11/10
CPCY02P10/143
Inventor 陈大元董荣华杨发均黄捷邓长江
Owner TAIHE IRON MINE CHONGQING IRON & STEEL GROUP MINING
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