Low-grade heavy oil catalytic conversion process for increasing yield of low-carbon olefins and gasoline

A low-quality heavy oil and catalytic conversion technology, which is applied in the field of catalytic conversion of heavy oil, can solve the problems of not having gasoline and low-carbon olefin yields, reduce dry gas and coke yields, and prolong catalyst life.

Active Publication Date: 2014-01-29
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The above-mentioned patent uses a combined hydrogenation and catalytic cracking process or a two-stage catalytic cracking process to treat the oil slurry at the bottom of the catalytic cracking fractionation tower, which can increase the yield of gasoline or diesel oil or light olefins to a certain extent. But it does not have the effect of simultaneously increasing the yield of gasoline and low-carbon olefins

Method used

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  • Low-grade heavy oil catalytic conversion process for increasing yield of low-carbon olefins and gasoline
  • Low-grade heavy oil catalytic conversion process for increasing yield of low-carbon olefins and gasoline

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Experimental program
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Effect test

Embodiment 1

[0038] (1) The preheated low-quality heavy oil enters the bottom feed port 11 of the riser 1, and contacts with the catalytic cracking catalyst from the regenerated inclined pipe 4 at high temperature, short contact time, and large catalyst-to-oil ratio in the riser I area to carry out catalytic cracking reaction, The high-temperature catalytic cracking reaction occurs under the conditions of reaction temperature of 655°C, reaction time of 1.45 seconds, weight ratio of catalyst to heavy hydrocarbon feedstock of 11:1, and weight ratio of water to heavy hydrocarbon feedstock of 0.3%.

[0039] (2) The generated oil gas and the raw materials from the outlet 52 in the middle of the fractionation tower and the outlet 53 in the lower part of the fractionation tower undergo a relatively mild catalytic cracking reaction, hydrogen transfer reaction and isomerization reaction in the riser II area. The charcoal catalyst is separated from oil and gas in the settler 10, and the separated cat...

Embodiment 2

[0044] (1) The preheated low-quality heavy oil enters the bottom feed port 11 of the riser 1, and contacts with the catalytic cracking catalyst from the regenerated inclined pipe 4 at high temperature, short contact time, and large catalyst-to-oil ratio in the riser I area to carry out catalytic cracking reaction, The reaction temperature was 615°C. The reaction time is 1.9 seconds; the weight ratio of catalyst to heavy hydrocarbon feedstock is 10:1; the weight ratio of water to heavy hydrocarbon feedstock is 0.3% under the reaction conditions of high temperature catalytic cracking reaction.

[0045] (2) The generated oil gas and the raw materials from the outlet 52 in the middle of the fractionation tower and the outlet 53 in the lower part of the fractionation tower undergo a relatively mild catalytic cracking reaction, hydrogen transfer reaction and isomerization reaction in the riser II area. The charcoal catalyst is separated from oil and gas in the settler 10, and the se...

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Abstract

The invention relates to a low-grade heavy oil catalytic conversion process for increasing the yield of low-carbon olefins and gasoline. The process comprises the following steps: (1) low-grade heavy oil, namely raw oil, enters a first reaction zone (zone I) of a two-section riser, so as to be subjected to catalytic cracking reaction, and generated oil and gas enter a fractionating tower; (2) a top outlet material of the fractionating tower is a mixture of dry gas, liquefied gas and gasoline, a middle-part outlet material of the fractionating tower is diesel oil, a lower-part outlet material of the fractionating tower is catalyzing wax oil, a bottom outlet material of the fractionating tower is oil slurry, the catalyzing wax oil and the diesel oil enter a second reaction zone (zone II) of the two-section riser together, and the oil slurry enters a vacuum distillation tower; (3) a lower-carbon-residue light-distillate material of an upper-part outlet of the vacuum distillation tower and a higher-carbon-residue heavy-distillate material of a middle-part outlet of the vacuum distillation tower enter a hydrogenation device together, and ultrahigh-carbon-residue oil slurry at the bottom of the vacuum distillation tower enters a delayed coking device; (4) a low-carbon-residue easily-cracked material from the hydrogenation device enters the zone I of the riser and is subjected to reaction again. The process has the characteristics that the service life of the catalyst is prolonged, the yield of dry gases and coke is lowered, and meanwhile, the yield of low-carbon olefins and gasoline is increased.

Description

technical field [0001] The invention relates to a catalytic conversion process for heavy oil, more specifically, to a catalytic conversion process for low-quality heavy oil that improves the yield of low-carbon olefins and gasoline. Background technique [0002] Petroleum resources are becoming increasingly heavy and inferior, which is mainly manifested in the increase in density and viscosity of crude oil, and the content of heavy metals, sulfur, colloids and asphaltenes is getting higher and higher. Therefore, after atmospheric distillation and vacuum distillation The residual oil also presents an increasingly heavy trend. How to obtain more and better products from inferior heavy oil, such as gasoline, diesel, and low-carbon olefins, and maximize its economic utilization value has been a key issue that researchers have studied for a long time. [0003] Catalytic cracking unit is an important means of secondary processing of petroleum, and occupies a pivotal position in e...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G69/04
Inventor 樊江涛高雄厚王智峰柳召永张海涛马艳萍张晨曦孙艳波曹兰花马燕青田爱珍苏怡娄来银
Owner PETROCHINA CO LTD
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