Preparation method for NiCo2O4/MnO2/AC water system asymmetric super capacitor
A supercapacitor, asymmetric technology, applied in the direction of hybrid/electric double layer capacitor manufacturing, hybrid capacitor electrodes, etc., can solve the problem of low energy density, achieve high energy density, increase the voltage window, and improve the effect of energy density
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Embodiment 1
[0028] 1) NiCo 2 o 4 / MnO 2 Preparation of:
[0029] A Put the foam nickel of appropriate size into a solution containing 1M hydrochloric acid for ultrasonic cleaning, the purpose is to remove the nickel oxide on the surface of the foam nickel.
[0030] B takes by weighing raw material nickel nitrate hexahydrate (Ni(NO 3 ) 2 ·6H 2 O), cobalt nitrate hexahydrate (Co(NO 3 ) 2 ·6H 2 O) and urea were dissolved in water and stirred to obtain a mixed solution in which Ni(NO 3 ) 2 ·6H 2 O and Co(NO 3 ) 2 ·6H 2 O molar ratio is 1:2, urea quality is 0.6g
[0031] C pour the above mixed solution into the polytetrafluoroethylene hydrothermal reaction kettle, keep 80% filling degree, and put a piece of cleaned foamed nickel, put the hydrothermal reaction kettle into the blast drying box, 90 React under hydrothermal conditions at -150°C for 3-12 hours, then cool the reactor to room temperature.
[0032] D Take out the pink nickel foam, wash it with deionized water and ethan...
Embodiment 2
[0038] 1) NiCo 2 o 4 / MnO 2 Preparation of:
[0039] A Put the foam nickel of appropriate size into a solution containing 1M hydrochloric acid for ultrasonic cleaning, the purpose is to remove the nickel oxide on the surface of the foam nickel.
[0040] B takes by weighing raw material nickel nitrate hexahydrate (Ni(NO 3 ) 2 ·6H 2 O), cobalt nitrate hexahydrate (Co(NO 3 ) 2 ·6H 2 O) and urea were dissolved in water and stirred to obtain a mixed solution in which Ni(NO 3 ) 2 ·6H 2 O and Co(NO 3 ) 2 ·6H 2 The ratio of O moles is 1:2, and the quality of urea is 1.5g.
[0041] C pour the above mixed solution into the polytetrafluoroethylene hydrothermal reaction kettle, keep 80% filling degree, and put a piece of cleaned foamed nickel, put the hydrothermal reaction kettle into the blast drying box, 90 React under hydrothermal conditions at -150°C for 3-12 hours, then cool the reactor to room temperature.
[0042] D Take out the pink nickel foam, wash it with deioni...
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