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Latent epoxy resin composite suitable for insulative impregnation of conformal felt and binding rope of motor and preparation method of composite

An epoxy resin and insulation impregnation technology, applied in latent epoxy resin composition and its preparation, in the field of latent epoxy resin composition, can solve problems such as poor temperature resistance, poor operation processability, large material loss, etc., to achieve Excellent electrical insulation, good compatibility, and high heat resistance

Active Publication Date: 2014-03-12
CHINA BLUESTAR CHENGRAND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005]1. The operation time is short, it must be prepared and used immediately, the material loss is large, and it is difficult to meet the production process requirements;
[0006]2. It is not easy to adjust after construction;
[0007]3. Sticky hands during operation, poor operation process and low production efficiency;
[0008]4. The system has poor temperature resistance and cannot meet the long-term stable working requirements of motors with power above 300MW
[0009] In addition, Ni Miaomiao, Harbin Institute of Electrical Engineering, etc. have developed a latent epoxy resin composition system ("China Adhesive Symposium Proceedings", 1998), the operating process performance of this system has not been reported, and the storage period at room temperature meets the requirements
However, the material must be fully cured at 130°C, which cannot meet the requirements of the motor assembly process; if the material is cured at 85-95°C for 12 hours, it can only be basically cured, and the glass transition temperature can only reach 85.67°C, which cannot meet the requirements of high-power motors. temperature requirements

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] Add 100 parts of F-44 novolac type epoxy resin, 60 parts of E-51 double A-type epoxy resin, 30 parts of carboxy-terminated nitrile rubber modified epoxy resin (brand 861340) into the reactor, and heat to 90~ 100°C, after fully stirring evenly, add 80 parts of common solvent (ethanol: acetone = 2:1) dropwise under reflux and stirring state, after the dropwise addition is completed for 30 minutes, cool and discharge, marked as 1-A.

[0047] In a reactor, 82 parts of 2-ethyl-4-methylimidazole and 40 parts of acrylonitrile were bulk reacted at 100°C for 4 hours to prepare modified imidazole. Then 27 parts of NiCl 2 The solution composed of 90 parts of ethanol is slowly dropped into the modified imidazole to carry out the complexation reaction, the reaction process will be violently exothermic, and the temperature is controlled to be lower than 40°C. After the dropwise addition is completed, cool down to room temperature and react for 40 minutes, add 30 parts of acetic acid...

Embodiment 2

[0050] 1. Self-made polyether modified epoxy resin toughening agent

[0051] Mix 360 parts of polypropylene glycol with a molecular weight of 1000 and 100 parts of methyltetrahydrophthalic anhydride in a reactor and heat it to 140-150°C for 3 hours, then at this temperature, less than 5×10 4 The reaction was carried out for 2 hours under the vacuum environment of Pa. Add 360 parts of double A-type epoxy resin E-51 and 1 part of triphenylphosphine, and react at 150-160°C for 3 hours. After cooling, a polyether modified epoxy resin is obtained.

[0052] 2. Add 15 parts of polyether modified epoxy resin toughening agent prepared by the above reaction in the reactor, 100 parts of E-44 bisphenol A epoxy resin, 60 parts of E-51 bisphenol A epoxy resin, Heat to 90-100°C, stir well, add 80 parts of common solvent (ethanol: acetone = 2:1) dropwise under reflux and stirring state, cool and discharge after 30 minutes after the dropwise addition, marked as 2-A.

[0053] 2-A and 1-B pre...

Embodiment 3

[0055] In the reactor, 60 parts of E-44 double parts of A-type epoxy resin, 40 parts of E-51 double parts of A-type epoxy resin, 60 parts of E-20 double parts of A-type epoxy resin, and 40 parts of polyurethane modified ring Oxygen resin (brand HyPox UA10), heated to 90-100°C, fully stirred evenly, and 100 parts of common solvent (ethanol: acetone = 2:1) was added dropwise under reflux stirring state. After the dropwise addition was completed for 30 minutes, the material was cooled and discharged, which was marked as 3-A.

[0056] 3-A and 1-B prepared in Example 1 were formulated into impregnating glue at a weight ratio of 10:1. The gelation time at 120°C is 23 minutes. The conformable felt and binding rope are impregnated with glue and then dried at 40°C. The obtained conformable felt and binding rope are relatively hard, and epoxy powder will fall off when bent. The impregnation glue is vacuum removed at room temperature, cured at 100°C for 18 hours, the glass transition t...

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Abstract

The invention discloses a latent epoxy resin composite suitable for insulative impregnation of a conformal felt and a binding rope of a motor and a preparation method of the composite. The latent epoxy resin composite comprises the following raw materials in parts by weight: 40-60 parts of epoxy resin, 5-15 parts of a flexibilizer, 2-6 parts of modified imidazole, 0.5-1.5 parts of a metallic compound, 0-3 parts of organic acid and 20-50 parts of a diluent. The modified imidazole is a cyanoethyl compound of imidazole and acrylonitrile. The impregnation glue prepared by the invention is high in heat resistance, the glass-transition temperature reaches over 125 DEG C, the Matin heat resistance reaches over 135 DEG C and the temperature resistant grade reaches 160 DEG C (Grade F). The impregnation glue is excellent in electrical insulating property, has the characteristics of long-term storage at constant temperature and quick curing at high temperature, and can fully satisfy the requirements on insulative impregnation of the conformal felt and the binding rope of the motor.

Description

technical field [0001] The invention relates to a latent epoxy resin composition, in particular to a latent epoxy resin composition for insulation impregnation of conformal felts and binding ropes for motors and a preparation method thereof, belonging to the technical field of polymer materials and motors. Background technique [0002] With the improvement of motor manufacturing technology, my country has been able to mass-produce motors with a power of more than 600MW on a large scale, and even 700MW water turbine motors, 1000MW ultra-zero thermal motors and 1000MW nuclear power motors. The increase of motor power is accompanied by the increase of operating temperature, and the local operating temperature may be above 80-100°C, which puts forward new requirements for the temperature resistance of the internal insulation and sealing materials of the motor, so the temperature resistance level of the insulation material is gradually changed from B-level rose to F-level, H-leve...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J163/04C09J163/02C09J163/10C09J163/00C09J11/06C08G59/40
Inventor 王洪杨旭明王芳
Owner CHINA BLUESTAR CHENGRAND CO LTD
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