Phosphor-nitrogen halogen-free flame-retardant master batch used for engineering plastics, and preparation method thereof

A technology for engineering plastics and flame retardant masterbatch, which is applied in the field of phosphorus-nitrogen halogen-free flame-retardant masterbatch for engineering plastics and its preparation, can solve the problems of not easy to mix evenly, pollute the surrounding environment, affect health, etc. The effect of production, simplifying production process and improving production efficiency

Inactive Publication Date: 2014-04-09
QINGDAO XINZHAN PLASTIC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, since flame retardants are all powders, it is extremely difficult to mix them evenly when mixed with raw materials, and the dust rais

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] A phosphorus-nitrogen halogen-free flame-retardant masterbatch for engineering plastics, the components of which are: 80% pentaerythritol polyphosphate melamine salt, 15% polypropylene (PP), 3% polypropylene wax, silane di Joint agent 2%.

[0018] Preparation method: (1) Weigh each component according to the weight ratio for use; (2) Add pentaerythritol polyphosphate melamine salt, polypropylene (PP), polypropylene wax and silane coupling agent into a high-speed mixer , fully mixed for 3 to 15 minutes; (3) Put the above mixture into a twin-screw extruder to extrude and granulate, then dry and package to obtain a phosphorus-nitrogen-halogen-free flame-retardant masterbatch for engineering plastics.

Embodiment 2

[0020] A phosphorus-nitrogen halogen-free flame-retardant masterbatch for engineering plastics, the composition of which is: neopentyl glycol polyphosphate melamine salt 75%, polystyrene (PS) 20%, polyethylene wax 4 %, phosphate coupling agent 1%.

[0021] Preparation method: (1) weigh each component according to the weight ratio for use; (2) mix neopentyl glycol polyphosphate melamine salt, polystyrene (PS), polyethylene wax and phosphate coupling agent Add it into a high-speed mixer and mix thoroughly for 3 to 15 minutes; (3) Put the above mixture into a twin-screw extruder to extrude and granulate, then dry and pack to obtain a phosphorus nitrogen halogen-free flame retardant masterbatch for engineering plastics grain.

Embodiment 3

[0023] A phosphorus-nitrogen-halogen-free flame-retardant masterbatch for engineering plastics, the composition of which is: pentaerythritol phosphate melamine salt (PPM) and pentaerythritol phosphate (PEPA) compound flame retardant 86%, ternary Ethylene-propylene rubber (EPDM) 10%, EVA wax 3%, phosphate coupling agent 1%.

[0024] Preparation method: (1) weigh each component according to the weight ratio for use; (2) mix pentaerythritol phosphate melamine salt (PPM) and pentaerythritol phosphate (PEPA) compound flame retardant, EPDM rubber Add (EPDM), EVA wax and phosphate ester coupling agent into a high-speed mixer and mix thoroughly for 3 to 15 minutes; (3) Put the above mixture into a twin-screw extruder to extrude and granulate, then dry and pack to obtain A phosphorus nitrogen halogen-free flame retardant masterbatch for engineering plastics.

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Abstract

The invention discloses a phosphor-nitrogen halogen-free flame-retardant master batch used for engineering plastics, and a preparation method thereof. The phosphor-nitrogen halogen-free flame-retardant master batch used for the engineering plastics comprises components by mass: 70%-90% of a phosphor-nitrogen halogen-free flame retardant, 10%-20% of a carrier, 3%-5% of a dispersant and 1%-3% of a coupling agent. The prepared master batch has the characteristics of high concentration, low cost and convenient use. Due to the adoption of the phosphor-nitrogen halogen-free flame retardant, the master batch has the characteristics of small dosage, small influence on mechanical and electrical properties of a plastic matrix, good flame-retardant effect and excellent processing properties. By using the master batch to modify the flame retardance of the plastics, not only can production process be simplified, but also production efficiency can be increased; and the problems of non-uniform distribution and dust pollution possibly caused by directly adding the flame retardant can be prevented. The master batch provided by the invention also meets flame-retardant and environment-friendly requirements of efficiency, low smoke, halogen free and no poison gas release, fits a development trend of non-halogen, non-toxicity, no dust pollution and reduced cost for flame retardance of the plastics, and has wide market prospects.

Description

technical field [0001] The invention relates to a flame-retardant masterbatch and a preparation method thereof, in particular to a phosphorus-nitrogen-halogen-free flame-retardant masterbatch for engineering plastics and a preparation method thereof. Background technique [0002] Engineering plastics are a class of high-performance polymer materials that can be used as structural materials, withstand mechanical stress in a wide temperature range, and are used in harsh chemical and physical environments, and have good mechanical properties and dimensional stability. Engineering plastics are widely used in various fields due to their exceptional performance, but overall there are too many products with relatively low technical content, and some still have defects such as insufficient flame retardancy. In the 21st century, the issue of sustainable development has been paid more and more attention by the governments of various countries. Green chemistry and technology and the in...

Claims

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Application Information

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IPC IPC(8): C08K5/521C08K5/3492C08K5/527C08K5/18C08L23/12C08L25/06C08L23/06C08L23/16C08L23/08C08L31/04C08L55/02C08L67/02C08L53/02C08L75/04C08J3/22
Inventor 不公告发明人
Owner QINGDAO XINZHAN PLASTIC
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