Polyurethane flame-retardant thermal-insulation material and preparation method thereof
A technology of flame retardant heat preservation and polyurethane, which is applied in the field of polyurethane flame retardant heat insulation materials and its preparation, and can solve the problems of conflicts between fire retardant properties and mechanical properties
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Embodiment 1
[0014] A polyurethane flame-retardant insulation material, which is composed of component A and component B, characterized in that component A consists of 10 parts by weight of phenolic resin, 10 parts by weight of brominated epoxy resin, phosphorus-containing flame-retardant polyether polyol 65 parts by weight, 4 parts by weight of silicone foam stabilizer, 3 parts by weight of catalyst dimethylethanolamine, 1 part by weight of catalyst dibutyltin dilaurate, 20 parts by weight of flame retardant and 25 parts by weight of blowing agent monofluorodichloroethane Components, B component is brominated polyphenyl polymethyl isocyanate.
[0015] The brominated epoxy resin is prepared from tetrabromobisphenol and epichlorohydrin as raw materials, and has an epoxy equivalent of 440-470g / eq, a bromine content of 47-51wt%, and a viscosity of 140-215cSt.
Embodiment 2
[0017] A polyurethane flame-retardant thermal insulation material, which is composed of component A and component B, characterized in that component A consists of 15 parts by weight of phenolic resin, 13 parts by weight of brominated epoxy resin, phosphorus-containing flame-retardant polyether polyol 75 parts by weight, 4 parts by weight of silicone foam stabilizer, 3 parts by weight of catalyst dimethylethanolamine, 1 part by weight of catalyst dibutyltin dilaurate, 30 parts by weight of flame retardant and 30 parts by weight of blowing agent monofluorodichloroethane Components, B component is brominated polyphenyl polymethyl isocyanate.
[0018] The brominated epoxy resin is prepared from tetrabromobisphenol and epichlorohydrin as raw materials, and has an epoxy equivalent of 440-470g / eq, a bromine content of 47-51wt%, and a viscosity of 140-215cSt.
Embodiment 3
[0020] A polyurethane flame-retardant insulation material, which is composed of component A and component B, characterized in that component A consists of 18 parts by weight of phenolic resin, 15 parts by weight of brominated epoxy resin, phosphorus-containing flame-retardant polyether polyol 85 parts by weight, 4 parts by weight of silicone foam stabilizer, 3 parts by weight of catalyst dimethylethanolamine, 1 part by weight of catalyst dibutyltin dilaurate, 40 parts by weight of flame retardant and 35 parts by weight of blowing agent monofluorodichloroethane Components, B component is brominated polyphenyl polymethyl isocyanate.
[0021] The brominated epoxy resin is prepared from tetrabromobisphenol and epichlorohydrin as raw materials, and has an epoxy equivalent of 440-470g / eq, a bromine content of 47-51wt%, and a viscosity of 140-215cSt.
[0022] The preparation method is:
[0023] Pre-mix phenolic resin, brominated epoxy resin and phosphorus-containing flame-retardant ...
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