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Polyurethane flame-retardant thermal-insulation material and preparation method thereof

A technology of flame retardant heat preservation and polyurethane, which is applied in the field of polyurethane flame retardant heat insulation materials and its preparation, and can solve the problems of conflicts between fire retardant properties and mechanical properties

Inactive Publication Date: 2014-04-23
广西宾阳县荣良农业科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In view of the main problems existing in the combination of polyurethane rigid foam insulation systems at home and abroad, combined with the current research progress of polyurethane rigid foam fire and flame retardant technology, polyurethane insulation materials have reached the national standard B1 or higher fire protection level, and the single addition of flame retardant technology The problem cannot be solved, and there is a problem that the fire-proof and flame-retardant performance of the polyurethane rigid foam insulation material is contradictory to the mechanical performance. At the same time, a systematic solution is proposed in combination with the addition of flame retardants and flame retardant curing agents

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] A polyurethane flame-retardant insulation material, which is composed of component A and component B, characterized in that component A consists of 10 parts by weight of phenolic resin, 10 parts by weight of brominated epoxy resin, phosphorus-containing flame-retardant polyether polyol 65 parts by weight, 4 parts by weight of silicone foam stabilizer, 3 parts by weight of catalyst dimethylethanolamine, 1 part by weight of catalyst dibutyltin dilaurate, 20 parts by weight of flame retardant and 25 parts by weight of blowing agent monofluorodichloroethane Components, B component is brominated polyphenyl polymethyl isocyanate.

[0015] The brominated epoxy resin is prepared from tetrabromobisphenol and epichlorohydrin as raw materials, and has an epoxy equivalent of 440-470g / eq, a bromine content of 47-51wt%, and a viscosity of 140-215cSt.

Embodiment 2

[0017] A polyurethane flame-retardant thermal insulation material, which is composed of component A and component B, characterized in that component A consists of 15 parts by weight of phenolic resin, 13 parts by weight of brominated epoxy resin, phosphorus-containing flame-retardant polyether polyol 75 parts by weight, 4 parts by weight of silicone foam stabilizer, 3 parts by weight of catalyst dimethylethanolamine, 1 part by weight of catalyst dibutyltin dilaurate, 30 parts by weight of flame retardant and 30 parts by weight of blowing agent monofluorodichloroethane Components, B component is brominated polyphenyl polymethyl isocyanate.

[0018] The brominated epoxy resin is prepared from tetrabromobisphenol and epichlorohydrin as raw materials, and has an epoxy equivalent of 440-470g / eq, a bromine content of 47-51wt%, and a viscosity of 140-215cSt.

Embodiment 3

[0020] A polyurethane flame-retardant insulation material, which is composed of component A and component B, characterized in that component A consists of 18 parts by weight of phenolic resin, 15 parts by weight of brominated epoxy resin, phosphorus-containing flame-retardant polyether polyol 85 parts by weight, 4 parts by weight of silicone foam stabilizer, 3 parts by weight of catalyst dimethylethanolamine, 1 part by weight of catalyst dibutyltin dilaurate, 40 parts by weight of flame retardant and 35 parts by weight of blowing agent monofluorodichloroethane Components, B component is brominated polyphenyl polymethyl isocyanate.

[0021] The brominated epoxy resin is prepared from tetrabromobisphenol and epichlorohydrin as raw materials, and has an epoxy equivalent of 440-470g / eq, a bromine content of 47-51wt%, and a viscosity of 140-215cSt.

[0022] The preparation method is:

[0023] Pre-mix phenolic resin, brominated epoxy resin and phosphorus-containing flame-retardant ...

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Abstract

The invention provides a polyurethane flame-retardant thermal-insulation material and a preparation method thereof. The polyurethane flame-retardant thermal-insulation material is composed of a component A and a component B, wherein the component A is composed of phenol formaldehyde resin, a brominated epoxy resin, phosphorous flame-retardant polyether glycol, an organosilicon foam stabilizer, a catalyst dimethylethanolamine, a catalyst dibutyltin dilaurate, a flame retardant and a foaming agent monofluorodichloroethane; and the component B is a flame-retardant polyisocyanate curing agent. The invention also provides a preparation method of the outer wall thermal-insulation material. The thermal-insulation material has excellent mechanical properties and high flame retardancy, solves the problem of contradiction between the flame retardancy and mechanical properties of the original polyurethane hard foam thermal-insulation material, and is suitable for outer wall thermal-insulation construction with higher requirements for fire-protection rating.

Description

technical field [0001] The invention relates to a polyurethane flame-retardant thermal insulation material and a preparation method thereof. Background technique [0002] In recent years, with the continuous deepening of energy-saving work in residential construction in my country and the continuous improvement of energy-saving standards, many new energy-saving technologies and materials have been introduced and developed, and their use has been vigorously promoted in residential buildings. Among them, various foam plastic insulation materials used in external wall insulation, such as EPS boards, XPS boards and foamed polyurethane boards, have excellent comprehensive performance and are eye-catching. [0003] At present, the organic insulation materials used on a large scale in my country mainly include EPS (polystyrene foam), PS (extruded polystyrene foam) and PU (polyurethane foam), all of which are flammable organic insulation materials, and the biggest advantage is light...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/77C08G18/58C08G18/54C08G18/50C08G18/18C08G18/24C08J9/14C08L75/08C08G101/00
CPCC08G18/165C08G18/1825C08G18/242C08G18/4027C08G18/4045C08G18/5075C08G18/542C08G18/582C08G18/773C08J9/144C08J2203/142C08J2375/08C08G2110/0025
Inventor 李益忠梁志坚吴定超
Owner 广西宾阳县荣良农业科技有限公司
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