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A kind of polyimide insulating cardboard and preparation method thereof

A technology of polyimide paper and polyimide, applied in the direction of insulators, organic insulators, chemical instruments and methods, etc., can solve the problem that the ultra-thick insulating cardboard cannot be resistant to high temperature, has high hygroscopicity, and the performance of the cardboard is vulnerable to weather Conditional influence and other problems, to avoid excessive heating time, low hygroscopicity, and reduce secondary pollution

Active Publication Date: 2016-04-20
CHANGCHUN HIPOLYKING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the shortcomings of laminated wood and laminated paperboard are overcome, the ultra-thick insulating paperboard produced by this method cannot withstand high temperatures, and the performance of the paperboard is easily affected by weather conditions, and has the disadvantage of high hygroscopicity

Method used

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  • A kind of polyimide insulating cardboard and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Such as figure 1 Shown, a kind of preparation method of polyimide insulating cardboard is prepared as follows:

[0031] 1) The semi-finished polyimide paper is prepared according to the following steps:

[0032] a) Using polyamic acid chopped fibers as raw materials, dispersing the raw materials in water to obtain a slurry;

[0033] b) After papermaking, pressing and drying the slurry obtained in step a), polyamic acid fiber paper is obtained;

[0034] c) Imidizing the polyamic acid fiber paper obtained in step b) to obtain a semi-finished polyimide paper. The temperature of the imidization treatment is 100°C.

[0035] 2) Laminate multiple layers of semi-finished polyimide paper to prepare polyimide cardboard; in the process of laminating polyimide semi-finished paper, two laminations are required, as follows: Put the semi-finished polyimide paper into the molding machine. Control the pressure of the molding machine to 10Mpa and the temperature to 150°C. After hot p...

Embodiment 2

[0040] The characteristics of this embodiment are:

[0041] In step 1), polyimide fibers and polyamic acid chopped fibers are mixed in a ratio of 1:1 to make polyimide paper, and the processing temperature of polyimide paper is 150°C.

[0042] In step 2), put 50 sheets of polyimide paper into the molding machine with a pressure of 10Mpa, a temperature of 200°C, hot pressing for 100min, and deflation for 5min. Put the semi-finished cardboard into the molding machine again, the pressure is 20Mpa, the temperature is 350°C, and it is hot-pressed for 1h. Take out the semi-finished cardboard and put it in a constant temperature and humidity storage for 30 hours.

[0043] A cardboard with a thickness of 10 mm is produced.

[0044] Others are the same as in Example 1.

[0045] After inspection, the weight of the cardboard is 1000g / m 2 , thickness 5mm, longitudinal tensile strength 621N / mm, transverse tensile strength 434N / mm; dielectric strength in air 35kv / mm, dielectric strength...

Embodiment 3

[0047] The characteristics of this embodiment are:

[0048] In step 1), polyimide fibers and polyamic acid chopped fibers are mixed in a ratio of 4:1 to make polyimide paper, and the processing temperature of polyimide paper is 100°C.

[0049] In step 2), put 80 sheets of polyimide paper into the molding machine with a pressure of 15Mpa, a temperature of 200°C, hot pressing for 100 minutes, and degassing for 5 minutes. Put the semi-finished cardboard into the molding machine again, press 25Mpa, temperature 400°C, and hot press for 2h. Take out the semi-finished cardboard and put it in a constant temperature and humidity storage for 48 hours.

[0050] A cardboard with a thickness of 20 mm is produced.

[0051] Others are the same as in Example 1.

[0052] After inspection, the weight of the cardboard is 1300g / m 2 ,Thickness 8mm, longitudinal tensile strength 811N / mm, transverse tensile strength 641N / mm; dielectric strength in air 46kv / mm, dielectric strength in insulating o...

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Abstract

The invention discloses a polyimide insulating paperboard and a preparation method thereof. The preparation method comprises the following steps: 1) preparing semi-finished polyimide paper; 2) putting a plurality of layers of semi-finished polyimide paper into a molding press, carrying out hot pressing at 150 DEG C under the pressure of 10MPa for 40 minutes, and taking out a semi-finished paperboard; and degassing for 3 minutes, putting the semi-finished paperboard into the molding press, carrying out hot pressing at 300 DEG C under the pressure of 15MPa for 1 hour, and taking out to obtain the polyimide insulating paperboard. The production technique does not use any adhesive, thereby reducing the secondary pollution of the product and saving the energy. The produced polyimide insulating paperboard has the characteristics of high temperature resistance, low hydroscopic property, high voltage resistance and temperature resistance grade, and can resist the high temperature of 300 DEG C above.

Description

technical field [0001] The invention relates to a polyimide insulating cardboard and a preparation method thereof, belonging to the fields of papermaking technology and insulating material manufacturing. Background technique [0002] Insulating paperboard is mainly used to replace laminated wood and laminated paperboard for transformer insulation. At present, the laminated wood and laminated cardboard used by transformers to make insulating structural parts are made of wood or cardboard bonded and dried. secondary pollution. [0003] The invention patent with the publication number CN101787665A discloses a production process of ultra-thick insulating cardboard. The process is: the wood pulp is purified and pretreated, and then the pulp crushed by the hydraulic pulper is concentrated to a concentration of 4.2-4.8% and enters the pulp pool, and the pulp is sent to the refiner for refining through the pulp pump, and the pulp is knocked out. Degree 30-34°SR, wet weight 11-15g...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D21H27/12D21H13/26B32B27/02B32B27/34B32B37/06B32B37/10
Inventor 谭洪艳丁孟贤刘斌吕晓义张万彬邵会千韩京成于暴
Owner CHANGCHUN HIPOLYKING