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Technology for separating copper, zinc and iron in scrap copper smelting slag leaching process

A technology for smelting slag and waste miscellaneous copper, which is applied in the field of separation of copper, zinc and iron, can solve the problems of increasing the iron removal process and increasing the burden on enterprises, and achieves the effects of improving economic benefits, improving the level of comprehensive utilization of resources, and reducing environmental pollution.

Inactive Publication Date: 2014-07-02
有研资源环境技术研究院(北京)有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

These methods all require a separate iron removal step, increasing the iron removal process and increasing the burden on the enterprise

Method used

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  • Technology for separating copper, zinc and iron in scrap copper smelting slag leaching process

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Embodiment Construction

[0025] Below in conjunction with specific implementation examples the present invention will be further described, please refer to figure 1 , is the flow chart of copper-zinc and iron separation process in the leaching process of waste miscellaneous copper smelting slag of the present invention.

[0026] (1) Preparatory work for leaching

[0027] Take a large scrap copper smelting and recycling enterprise in my country as an example. The enterprise produces a large amount of waste miscellaneous copper smelting slag every year. The slag contains a large amount of copper, zinc and iron, and its occurrence state is mainly oxide and metal alloy state. Waste miscellaneous copper smelting slag has a wide particle size distribution and must be screened. The sieving limit is 60 mesh, and the part with large particle size is separated by sieving, and the part with small particle size passes through magnetic separation to recover part of the metal iron, and re-selects to recover metal...

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Abstract

The invention relates to a technology for separating copper, zinc and iron in a scrap copper smelting slag leaching process. The technology for separating the copper, zinc and iron in the scrap copper smelting slag leaching process comprises the following steps: (1) performing selective zinc leaching on the scrap copper smelting slag; (2) performing weak acid leaching on the selectively leached slag; (3) heating a solution after weak acid is leached and adding an oxidizing agent, so that copper zinc alloy is contained in acid leaching solution, and iron is contained in acid leaching slag; (4) extracting copper from the acid leaching solution, so that copper is separated from zinc and iron; (5) returning raffinate into the selective zinc leaching step, wherein zinc is recycled after being returned into selective leaching solution, and residual copper and iron are sedimented into the selective leaching slag by virtue of a selective leaching process. The technology for separating the copper, zinc and iron in the scrap copper smelting slag leaching process has the advantages of short technological process, low investment and operating cost, simple operation, short leaching period, high recovery rate of copper and zinc and the like, copper and zinc in scrap copper smelting slag can be environmental friendly, efficiently and quickly leached out, and copper can be separated from copper; the technology for separating the copper, zinc and iron in the scrap copper smelting slag leaching process is especially applicable to treatment on scrap copper smelting slag with high iron content and high copper zinc content.

Description

technical field [0001] The invention relates to a new process for separating copper, zinc and iron in the leaching process of waste miscellaneous copper smelting slag. Background technique [0002] In recent years, with the strengthening of circular economy and national environmental protection policy, resource regeneration has been paid more and more attention. As an important part of the regeneration of copper resources, a large amount of smelting slag will be produced during the recycling process of scrap copper. These smelting slags are mostly treated by pyrolysis. With the increasing demand for energy conservation and environmental protection in the country, wet treatment of these smelting slags has become a trend of development. In the process of wet treatment, there must be a problem of iron removal, and the introduction of the iron removal program alone will inevitably lead to a long treatment process and high energy consumption. Therefore, it is necessary to explor...

Claims

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Application Information

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IPC IPC(8): C22B7/04C22B3/06C22B3/26C22B15/00C22B19/00
CPCY02P10/20
Inventor 王巍徐政杨丽梅李岩
Owner 有研资源环境技术研究院(北京)有限公司
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