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Green ink capable of fading by hydrolyzing and preparation method thereof

A kind of ink and green technology, applied in the field of teaching stationery, can solve the problems such as the inability to retain handwriting for a long time, the high proportion of ethanol solvent, and short color retention time, etc., to overcome the problems of short color retention time, long retention time, and stable storage Effect

Active Publication Date: 2014-07-09
山西奇色环保科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, there are some defects in the inks sold in the market in different degrees: if some inks use color couplers, most of them are easily soluble in ethanol, but the solubility in water is very small, so the proportion of ethanol solvent used in the formula is relatively high
Some inks can be wiped clean, but the color retention time is short after writing, and the handwriting cannot be retained for a long time. This phenomenon is more obvious in the south or in seasons with high humidity, so there are great disadvantages in use

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] Raw material ratio: p-nitrophenol 5.5g, sodium hydroxide 7.5g, water 500ml, urea 14g, glycerin 6.6g, formaldehyde 2.75ml, hydroxyethyl cellulose 0.55g, fatty alcohol polyoxyethylene ether sodium sulfate 5.5g, Thymolphthalein basket complexing agent 3.3g, triethanolamine 5.5ml.

[0015] Preparation:

[0016] According to the above ratio, in a 800ml beaker, add carboxyethyl cellulose, heat to dissolve it completely, cool down to about 50 degrees Celsius, add p-nitrophenol, sodium hydroxide, deionized water, urea, triethanolamine in sequence , glycerin, formaldehyde and fatty alcohol polyoxyethylene ether sodium sulfate, in a water bath at 40 degrees Celsius, stir with a stirring device at a low speed for 30 minutes until the dispersion is uniform, then add the thymolphthalein basket complexing agent, and continue stirring to obtain a bright-coloured Green ink product.

[0017] Using the obtained ink to write on the plastic whiteboard has the characteristics of smooth wr...

Embodiment 2

[0019] Raw material ratio: p-nitrophenol 11.0g, sodium hydroxide 7.5g, water 460ml, urea 11g, glycerin 14.0g, formaldehyde 3.0ml, hydroxyethyl cellulose 1.1g, fatty alcohol polyoxyethylene ether sodium sulfate 2.75g, Thymolphthalein basket complexing agent 16.5g, triethanolamine 16.5ml.

[0020] The preparation method is the same as in Example 1.

[0021] Using the obtained ink to write on a plastic whiteboard, the writing is smooth, the handwriting is clear, and the color is bright; the handwriting can be easily erased with water without leaving any traces.

Embodiment 3

[0023] Raw material ratio: p-nitrophenol 13.7g, potassium hydroxide 8.2g, water 465ml, urea 12.0g, glycerin 16.5g, formaldehyde 2.75ml, hydroxyethyl cellulose 0.55g, fatty alcohol polyoxyethylene ether sodium sulfate 8.25g , thymolphthalein basket complexing agent 11.0g, triethanolamine 12.1ml.

[0024] Preparation method, except that sodium hydroxide is replaced with potassium hydroxide, all the other are with embodiment 1.

[0025] Using the obtained ink to write on a plastic whiteboard, the writing is smooth, the handwriting is clear, and the color is bright; the handwriting can be easily erased with water without leaving any traces.

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PUM

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Abstract

The invention provides green ink capable of fading by hydrolyzing and a preparation method thereof. The green ink comprises the following components in percent by weight: 1%-5% of p-nitrophenol, 1%-6% of sodium hydroxide, 80%-92% of water, 1%-5% of urea, 1%-4% of glycerol, 0.1%-1% of formaldehyde, 0.05%-0.5% of hydroxyethyl cellulose, 0.5%-3% of fatty alcohol-polyoxyethylene ether sodium sulfate, 0.5%-5% of thymolphthalein blue complexing agent, and 0.5%-3% of triethanolamine. The ink can be quickly faded to be colorless while meeting water under a neutral condition, can be used as ink for white board teaching and writing, and also can be used as writing and drawing ink for children. The ink disclosed by the invention is easy in obtaining materials, simple in preparation method, bright in color, long in color holding time; and handwriting can be directly erased out by water without marks, so that board surface is not contaminated.

Description

technical field [0001] The invention relates to stationery for teaching, in particular to writing materials, in particular to a hydrolyzable and fadeable green ink and a preparation method thereof. Background technique [0002] The safety of teaching stationery directly affects the health of teachers, students and users, and inferior writing ink has a great impact on the physical development of young children. The inks currently on the market have some defects in varying degrees: if some inks use couplers that are mostly soluble in ethanol, but have little solubility in water, so the proportion of ethanol solvent used in the formula is relatively high. Although this type of ink can also be hydrolyzed and faded after writing, its hydrolyzed products cannot be dissolved in water, and can form colorless precipitates that are stained on the whiteboard. If you write again, traces will appear again soon, and it is difficult to clean the paint on the hands of the writer. Some ink...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D11/17C09D11/16
Inventor 李俊芬李笃信
Owner 山西奇色环保科技股份有限公司
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