The invention discloses a method for determining the content of bound
acrylonitrile in butadiene-
acrylonitrile rubber. The method includes the following steps: (1) heating an extracted butadiene-
acrylonitrile rubber sample with the weight being m1 to 400 DEG C,
cracking, collecting a crackate, and weighing the crackate constant weight being m2; (2) carrying out a test experiment, taking the crackate with the
mass being m3, dissolving in dilute
sulfuric acid, then putting into a container, dropping 2-3 drops of an
alizarin yellow-
thymolphthalein mixed indicator, and titrating the sample to light blue with a 0.1 mol / L
sodium hydroxide standard solution; adding 10 mL of a
sodium sulfite solution with the concentration of 126 g / L, making the solution become bluish violet, shaking evenly, covering with a
bottle plug, sealing well, placing for 5 min, then titrating to faint yellow with a 0.1 mol / L
sulfuric acid standard solution, and making the consumed
sulfuric acid standard solution be V1; and carrying out a blank experiment, and making the consumed sulfuric acid standard solution be V0; and (3) calculating test results. The method can be applicable to measurement of the content of bound acrylonitrile in vulcanized butadiene-acrylonitrile rubber simultaneously, and moreover, the measured results are accurate and convenient.