Resin Composition For Laminating And Use Thereof
A resin composition and lamination technology, which can be applied in the direction of photographic filters, instruments, cameras, etc., can solve the problems of insufficient processability, insufficient heat resistance, and easy cracks, etc.
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preparation example 1
[0368] Preparation Example 1 (Synthesis of Powder B Containing TPB)
[0369] According to the synthesis method described in International Publication No. 1997 / 031924, 255 g of an Isopar E solution with a TPB (tris(pentafluorophenyl) boron) content of 7% was prepared. To this solution was added dropwise water at 60°C. White crystals began to precipitate during the dropwise addition. After the reaction solution was cooled to room temperature, the obtained slurry was suction-filtered and washed with n-heptane. The obtained cake was dried under reduced pressure at 60° C. to obtain 18.7 g of TPB·hydrate complex (TPB-containing powder B) as white crystals. The water content of the complex was 9.2% (Karl Fischer moisture analyzer), and the TPB content was 90.8%. For the dried complex implementation 19 In F-NMR analysis and GC analysis, peaks other than TPB were not detected.
[0370] 19 The measurement results of F-NMR are shown below.
[0371] 19 F-NMR (CDCl 3 )ppm (standar...
preparation example 2
[0375] Preparation example 2 (preparation of cationic curing catalyst A)
[0376] Add 2.1 g of γ-butyrolactone to TPB-containing powder B obtained in Preparation Example 1: 2 g (TPB purity: 1.816 g (3.547 mmol), water: 0.184 g (10.211 mmol)), and mix at room temperature for 10 minutes . Thereafter, ADKSTABLA-57 (hindered amine, manufactured by ADEKA) 0.778 g (0.984 mmol, N group mole number: 3.934 mol) was added, mixed at room temperature for 10 minutes, and further mixed at 60° C. for 20 minutes to obtain cationic curing. Homogeneous solution of catalyst (TPB catalyst). This was referred to as cationic curing catalyst A.
preparation example 3
[0377] Preparation Example 3 (Preparation of Cationic Curing Catalyst B)
[0378] Add 1.6 g of γ-butyrolactone to TPB-containing powder B obtained in Preparation Example 1: 2 g (TPB purity: 1.816 g (3.547 mmol), water: 0.184 g (10.211 mmol)), and mix at room temperature for 10 minutes . Thereafter, 2.1 g of a 2 mol / L ammonia-ethanol solution was added and mixed at room temperature for 60 minutes to prepare a homogeneous solution of the cationic curing catalyst (TPB catalyst). Let this be Cationic Curing Catalyst B.
[0379]
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