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Clay-resistant polycarboxylate water-reducer compoundable with naphthalene-based water-reducer and preparation method thereof

A naphthalene-based water-reducer and anti-clay technology, applied in the field of clay-resistant polycarboxylate water-reducer, polycarboxylate water-reducer, concrete admixture, the preparation of the polycarboxylate water-reducer, can solve Small loss of fresh concrete over time, high strength of hardened concrete, good durability, etc., to achieve good electrostatic repulsion stabilization, good dispersion stability, and good durability

Active Publication Date: 2016-02-03
SHIJIAZHUANG CHANGAN YUCAI BUILDING MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The object of the present invention is to provide a clay-resistant polycarboxylate water-reducer that can be compounded with naphthalene-based water-reducers. Carboxylic acid superplasticizer is incompatible with naphthalene-based superplasticizers. At the same time, it has good clay resistance and can significantly improve the workability and slump retention of concrete with aggregates with high mud content. The loss of freshly mixed concrete is small over time. , Hardened concrete has high strength and good durability

Method used

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  • Clay-resistant polycarboxylate water-reducer compoundable with naphthalene-based water-reducer and preparation method thereof
  • Clay-resistant polycarboxylate water-reducer compoundable with naphthalene-based water-reducer and preparation method thereof

Examples

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Embodiment 1

[0016] Example 1: The anti-clay polycarboxylate water reducer of the present invention that can be compounded with naphthalene-based water reducers is made of the following raw materials in parts by mass (parts by weight) (or it is made of The components in the following amounts are polymerized): 47.08 parts of comonomer, 0.30 parts of chain transfer agent, 1.44 parts of initiator, and 180 parts of deionized water. The present invention can be carried out under laboratory conditions, and the mass unit of each component is g. 47.08g comonomers include 27g acrylic acid, 13.9g hydroxyethyl acrylate and 6.18g sodium p-styrene sulfonate, chain transfer agent is 0.30g thioglycolic acid, 1.44g initiator includes 0.19g ascorbic acid, 1.25g hydrogen peroxide, peroxide The hydrogen peroxide is 30% (mass percent) hydrogen peroxide solution, and 180 g of deionized water is about 180 ml. The above-mentioned (meth)acrylic monomer (acrylic acid) accounts for 57.4% of the total mass of comon...

Embodiment 2

[0018] Example 2: The anti-clay polycarboxylate water reducer of the present invention that can be compounded with naphthalene-based water reducers is made of the following raw materials in parts by mass (parts by weight) (or it is made of The components in the following amounts are polymerized): 45.0 parts of comonomer, 1.1 parts of chain transfer agent, 1.3 parts of initiator, and 180 parts of deionized water. The present invention can be carried out under laboratory conditions, and the mass unit of each component is g. 45.0 g of comonomers consisted of 26.6 g of methacrylic acid, 13.4 g of hydroxyethyl methacrylate and 5.0 g of sodium p-styrenesulfonate, the chain transfer agent was 1.1 g of sodium bisulfite, and the initiator was 1.3 g of sodium persulfate, 180g deionized water is about 180ml.

[0019] The preparation method of the above-mentioned clay-resistant polycarboxylate water-reducer that can be compounded with naphthalene-based water-reducers includes the followi...

Embodiment 3

[0020] Example 3: The anti-clay polycarboxylate water reducer of the present invention that can be compounded with naphthalene-based water reducers is made of the following raw materials in parts by mass (parts by weight) (or it is made of The components in the following amounts are polymerized): 48.3 parts of comonomer, 1.26 parts of chain transfer agent, 1.0 part of initiator, and 180 parts of deionized water. The present invention can be carried out under laboratory conditions, and the mass unit of each component is g. 48.3 g comonomers including 27.9 g methacrylic acid, 15.0 g hydroxypropyl methacrylate and 5.4 g sodium p-styrene sulfonate, 1.26 g chain transfer agent including 1.06 g sodium allyl sulfonate and 0.2 g bisulfite Sodium, the initiator is 1.0g ammonium persulfate, 180g deionized water about 180ml.

[0021] The preparation method of the above-mentioned clay-resistant polycarboxylate water-reducer that can be compounded with naphthalene-based water-reducers inc...

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Abstract

The invention relates to an anti-clay polycarboxylate water reducer capable of being compounded with a naphthalene water reducer and a preparation method thereof. The anti-clay polycarboxylate water reducer is prepared from the following raw materials: a comonomer, a chain transfer agent, an initiator and deionized water. The preparation method comprises the following steps: adding the deionized water into a four-mouth flask and heating to 60-80 DEG C; filling the comonomer, the chain transfer agent and the deionized water in a beaker to prepare a solution A; filling the initiator and the deionized water in another beaker to prepare a solution B; respectively, simultaneously and uniformly dropping the solutions A and B into the four-mouth flask by a constant flow pump, and after reaction, cooling and adjusting the pH value to 6.5-7.0 to obtain the anti-clay polycarboxylate water reducer. The polycarboxylate water reducer provided by the invention can be compounded with the naphthalene water reducer in use, so that the problem that the prior art, the polycarboxylate water reducer and the naphthalene water reducer are incompatible is solved. The anti-clay polycarboxylate water reducer is good in anti-clay performance and can be used for remarkably improving the working performance of high silt content aggregate prepared concrete, and the fresh concrete is good in peaceability, less in gradual loss, high in strength and suitable for industrial production.

Description

technical field [0001] The invention relates to a concrete admixture, in particular to a polycarboxylate water-reducer, belonging to the technical field of building materials, in particular to a clay-resistant polycarboxylate water-reducer that can be compounded with a naphthalene-based water-reducer. The invention also relates to a preparation method of the polycarboxylate water reducer. Background technique [0002] In recent years, polycarboxylate superplasticizers have been favored by people in the concrete industry due to their advantages such as high water reducing rate, low dosage, good cement adaptability and environmental protection. However, in the actual application process, it was found that the adverse effect of soil on concrete mixed with polycarboxylate superplasticizer is very prominent. In the past, sand and gravel with stable quality, good particle gradation and low mud content are less and less, especially in industrial and civil construction projects, a ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08F220/06C08F220/28C08F212/14C08F220/58C08F2/38C04B24/22C04B24/16C04B103/30
Inventor 万甜明王进春刘昭洋苏荣杨晓锋
Owner SHIJIAZHUANG CHANGAN YUCAI BUILDING MATERIALS
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