Preparation method of self-adhesion silicon rubber foam material

A foam material and silicone rubber technology, which is applied in the field of preparation of self-adhesive silicone rubber foam materials, can solve the problems of silicone rubber performance impact, low foaming efficiency, and increasing the types of silicone rubber raw materials, achieving low cost and high foaming efficiency , the effect of fewer types of raw materials

Active Publication Date: 2014-09-24
NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in addition to the compounds required for the crosslinking and foaming of silicone rubber, the composition also needs to add silicate substances that give silicone rubber viscosity, resulting in an increase in the types of raw materials in the silicone rubber; and, the foaming agent used in it It is a compound containing embedded liquid or crystalline liquid, such as salt and protein, which has problems such as low foaming efficiency and residual substances that have a great impact on the performance of silicone rubber.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] (1) Prepare raw materials, the components of raw materials and their weight percentages are as follows:

[0028] Methyl vinyl silicone rubber: 90%

[0029] Hydrophobic vapor phase method white carbon black: 5%

[0030] Methyl silicone oil: 2%

[0031] Blowing agent AC: 1%

[0032] Crosslinking agent DBPMH: 2%

[0033] (2) Put the prepared raw materials into an internal mixer and mix evenly; put the mixture in an open mixer and open the mixer to obtain a mixture sheet with a thickness of 2mm; put the mixture sheet into a closed mold and heat it with a flat vulcanizer. The foamed sheet is obtained; the foamed sheet is subjected to post-heating treatment to obtain a self-adhesive silicone rubber foam board.

[0034] The self-adhesive silicone rubber foam board prepared above is subjected to a mechanical test, and the test result is: the density of the self-adhesive silicone rubber foam board is 350 g / L, and the permanent compression set becomes 2.3%.

[0035] The self-adhesive silicon...

Embodiment 2

[0038] (1) Prepare raw materials, the components of raw materials and their weight percentages are as follows:

[0039] Methyl vinyl silicone rubber: 50%, methyl phenyl silicone rubber: 45%

[0040] Methyl silicone oil: 3%

[0041] Foaming agent: sodium bicarbonate 1%

[0042] Crosslinking agent: dibenzoyl peroxide 1%

[0043] (2) Put the prepared raw materials into an internal mixer and mix evenly; put the mixture in an open mixer and open the mixer to obtain a mixture sheet with a thickness of 2mm; put the mixture sheet into a closed mold and heat it with a flat vulcanizer. The foamed sheet is obtained; the foamed sheet is subjected to post-heating treatment to obtain a self-adhesive silicone rubber foam board.

[0044] The self-adhesive silicone rubber foam board prepared above is subjected to a mechanical test, and the test result is: the density of the self-adhesive silicone rubber foam board is 295 g / L, and the permanent compression set becomes 2.8%.

[0045] The self-adhesive sili...

Embodiment 3

[0048] (1) Prepare raw materials, the components of raw materials and their weight percentages are as follows:

[0049] Methyl vinyl silicone rubber: 45%, fluorosilicone rubber: 45%

[0050] Hydrophobic vapor phase method white carbon black: 2%

[0051] Methyl silicone oil: 4%

[0052] Foaming agent: sodium bicarbonate 2%

[0053] Crosslinking agent: dicumyl peroxide 2%

[0054] (2) Put the prepared raw materials into an internal mixer and mix evenly; place the mixture in an open mixer and open the mixer to obtain a mixture sheet with a thickness of 2 mm; put the mixture sheet into a closed mold and use infrared heating to obtain Foam sheet: After heating the foam sheet, a self-adhesive silicone rubber foam board is obtained.

[0055] The self-adhesive silicone rubber foam board prepared above was subjected to a mechanical test, and the test result was: the density of the self-adhesive silicone rubber foam board was 231 g / L, and the permanent compression set became 3.2%.

[0056] The self...

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PUM

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Abstract

The invention provides a preparation method of a self-adhesion silicon rubber foam material. The method comprises the following steps: mixing silicon rubber, a foaming agent, a vulcanizing agent, a reinforcing agent and micromolecular silicon oil as raw materials, milling and sheeting, and performing heat treatment foaming to obtain the self-adhesion silicon rubber foam material. Compared with an existing preparation method, the method has the characteristics that the used raw materials have few varieties and are simple and easy to prepare, low in cost and free of environmental pollution; moreover, by adopting the heat treatment foaming technology, the prepared silicon rubber material is a foam material for foaming, which is high in foaming efficiency, light in weight, excellent in heat insulation property, high and low-temperature resistance, chemical stability and physiological inertia and good in self-adhesion performance, and the force of adhesion between the foam material and an aluminum plate is 10-25N/mm.

Description

Technical field [0001] The invention relates to the field of preparation methods of silicone rubber foam materials, in particular to a preparation method of self-adhesive silicone rubber foam materials. Background technique [0002] As a kind of semi-inorganic and semi-organic polymer foam, silicone rubber foam not only has the characteristics of light weight, heat insulation and good impact resistance, etc., but also has excellent characteristics that ordinary rubber foam cannot have at the same time, such as Excellent high and low temperature resistance, chemical stability, physiological inertia, etc., can be used as materials such as shock absorption, sound absorption and heat insulation, and are widely used in transportation, electronics, chemical, military and aerospace fields. [0003] Silicone rubber foam materials are often required to have stickiness on their surface during use, which is called self-adhesive silicone rubber foam materials. At present, most of the self-adh...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J9/08C08J9/10C08L83/04C08L83/07C08L83/08C08K5/14C08K3/36
Inventor 翟文涛郑文革陈忠
Owner NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI
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