A kind of preparation method of copper/phosphorus bimetallic capillary

A technology of capillary and bimetal, which is applied in the field of metal composite capillary material preparation, can solve the problems of lowering the reliability of the instrument, shortening the service life, and low thermal conductivity of phosphorus, and achieves low production cost, long mold life and good surface quality Effect

Active Publication Date: 2016-12-28
枣庄铭世新型材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in places with strong seawater corrosion such as ships, seawater desalination and coastal power stations, copper and copper alloy capillary tubes will shorten their service life due to seawater corrosion and reduce the reliability of the instrument.
Pure phosphorus capillary has extremely good corrosion resistance, but the thermal conductivity of phosphorus is low, the heat exchange performance of thick-walled capillary is poor, and the mechanical properties of thin-walled capillary are difficult to meet the use requirements
[0003] At present, the preparation methods of copper / phosphorus composite pipes mainly include: Czochralski composite, hydraulic bulging composite and explosive welding, etc., which are usually realized by obtaining a small amount of plastic deformation of the base material or the base and cladding materials to obtain an interference fit. Composite, the interface bonding strength of the prepared composite tube is low, the deformation coordination of the double-layer metal is poor, it is difficult to make a capillary, especially the thickness of the phosphorus layer is uneven, and it is difficult to ensure the thickness of the phosphorus layer after the capillary is made.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Embodiment 1: A processing method for a copper / phosphorus bimetallic capillary with a size of Φ3.0 mm×1.5 mm.

[0017] Put a TA2 pure phosphorus tube with a size of Φ12.7mm×1.55mm into a T2 copper tube with a size of Φ19.0mm×2.0mm, insert a mandrel coated with mineral oil, and perform 3 passes with a section reduction rate of about 20%. Cold swaging to produce a copper / phosphorus composite pipe with a size of Φ14.1mm×1.3mm. Under the protection of argon, the composite tube was subjected to diffusion annealing treatment at 950°C for 10 minutes to form a metallurgical bond at the interface. After the diffusion treatment, the composite pipe was subjected to 5 passes of straight pulling with the moving core to obtain a Φ7.2mm×0.7mm composite pipe, and after annealing at 500°C for 1h, the moving core was pulled continuously for 5 passes to obtain a Φ3. 0mm×1.5mm copper / phosphorus bimetallic capillary. The section reduction rate of the straight pull pass is between 10% and ...

Embodiment 2

[0018] Embodiment 2: A processing method for a copper / phosphorus alloy bimetallic capillary with a size of Φ2.0mm×0.4mm.

[0019] Put the phosphorus alloy tube with the size of Φ12.0mm×1.5mm into the T2 copper tube with the size of Φ15.0mm×1.4mm, insert the mandrel coated with mineral oil, and carry out 4 passes of cooling with the section reduction rate of about 20%. Swivel forging to produce a copper / phosphorus alloy composite tube with a size of Φ11.0mm×1.0mm. Under the protection of argon, the composite tube was subjected to diffusion annealing at 920°C for 30 minutes to form a metallurgical bond at the interface. After the diffusion treatment, the composite pipe is straight-drawn by the moving core head for 5 times to obtain a composite pipe of Φ5.5mm×1.5mm, annealed at 500°C for 1 hour, and then pulled by the moving core head for 5 times to obtain a composite pipe of Φ2mm. ×0.4mm copper / phosphorus alloy bimetallic capillary. The section reduction rate of the straight p...

Embodiment 3

[0020] Embodiment 3: A processing method for a copper / phosphorus bimetallic capillary with a size of Φ1.5 mm×0.1 mm.

[0021] Put a TA2 pure phosphorus tube with a size of Φ8.0mm×0.4mm into a T2 copper tube with a size of Φ10.0mm×0.9mm, insert a mandrel coated with mineral oil and perform 5 passes with a section reduction rate of about 20%. Cold swaging to produce a copper / phosphorus composite pipe with a size of Φ9.0mm×0.6mm. Under the protection of argon, the composite pipe was subjected to diffusion annealing treatment at 900°C for 60 minutes to form a metallurgical bond at the interface. After the diffusion treatment, the composite pipe is pulled by the moving core head 4 times to obtain a Φ4.0mm×0.3mm composite pipe; after annealing at 500°C for 1h, the Φ2 .0mm×0.15mm composite tube; after annealing at 500°C for 1h, it will be drawn into a Φ1.5mm×0.1mm copper / phosphorus bimetallic capillary through 7 passes (an intermediary at 500°C for 1h is required during this period)...

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PUM

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Abstract

The invention belongs to the technical field of metal composite capillary material preparation, and relates to a method for preparing a copper / phosphorus bimetallic capillary. The method is to use rotary forging to realize the tight combination of copper tube and phosphorus tube, and obtain a copper / phosphorus composite tube whose interface reaches a metallurgical bonding state through high-temperature diffusion annealing treatment; then use floating core drawing or / and empty drawing processing, Combined with intermediate annealing, a high-performance copper / phosphorus bimetallic capillary is obtained. The invention adopts the method of combining the drawing of the floating core head and the empty drawing, together with the necessary intermediate annealing, the obtained composite capillary has high dimensional accuracy and good surface quality. After diffusion annealing and drawing processing, the deformation force required for forming is small, the life of tools and molds is long, the driving force required for equipment is small, and the production cost is low.

Description

Technical field: [0001] The invention relates to the technical field of preparing metal composite capillary tubes, in particular, it provides a production method applicable to copper / phosphorus bimetallic capillary tubes. technical background: [0002] Copper and copper alloy capillary tubes are a type of pipe with a small diameter and a thin wall thickness in the specification range of Φ(1.5~6.1)mm×(0.1~0.8)mm (outer diameter×wall thickness, the same below). , an important raw material widely used in modern household appliances, instruments and meters. It is characterized by high processing difficulty and high added value. With the rapid development of my country's equipment manufacturing industry, home appliance industry and marine industry, the market demand for copper and copper alloy capillary tubes is increasing. However, in places with strong seawater corrosion environments such as ships, seawater desalination and coastal power stations, copper and copper alloy capi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B21C37/06
Inventor 王栩
Owner 枣庄铭世新型材料有限公司
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