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A kind of unsaturated polyester coating for ceramics

A polyester coating, unsaturated technology, applied in the direction of coating, etc., can solve the problems of long drying time, poor chemical and water resistance, easy to wrinkle, etc., and achieve the effect of friction resistance hardness

Active Publication Date: 2016-06-15
SUZHOU SHENGPULA NEW MATERIAL SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In view of the above technical problems, the present application provides an unsaturated polyester coating for ceramics, which solves the technical problems of existing unsaturated polyester coatings for ceramics such as easy wrinkling, long drying time, poor chemical and water resistance, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] An unsaturated polyester coating for ceramics. The raw materials are as follows in parts by weight: 100 parts of epoxy acrylate; 30 parts of dipentaerythritol hexaacrylate; 15 parts of cadmium oxide; 35 parts of benzoin dimethyl ether; 80 parts of water 10 parts of isophthalic acid; 5 parts of phthalocyanine blue; 20 parts of N-vinylpyrrolidone; 25 parts of monobutyl maleate; 25 parts of triisocyanate; 1 part of hexamethoxymethylmelamine; 15 parts of maleic anhydride Parts; 10 parts of borax; 5 parts of adipic acid; 20 parts of clay.

[0014] Put the above-mentioned raw materials in a reaction kettle, stir while blowing nitrogen, after mixing uniformly, heat up to 180°C for 1 hour, continue to heat up to 210°C, and react for 1 hour to obtain the product.

[0015] The gloss of the product is 90%, the tensile strength is 3MPa; the surface-drying time is 30s, and the drying time is 25min. After soaking in water for 10d, there is no blistering or shedding. It is soaked in satura...

Embodiment 2

[0017] An unsaturated polyester coating for ceramics. The raw materials are as follows in parts by weight: 100 parts of epoxy acrylate; 40 parts of dipentaerythritol hexaacrylate; 25 parts of cadmium oxide; 45 parts of benzoin dimethyl ether; 100 parts of water ; 20 parts of isophthalic acid; 15 parts of phthalocyanine blue; 30 parts of N-vinylpyrrolidone; 35 parts of maleic acid monobutyl ester; 45 parts of triisocyanate; 10 parts of hexamethoxymethyl melamine; 35 parts of maleic anhydride Parts; 30 parts of borax; 25 parts of adipic acid; 40 parts of clay.

[0018] Put the above-mentioned raw materials in a reaction kettle, stirring while blowing nitrogen, after mixing uniformly, heat up to 180°C for 1 hour, continue to heat up to 230°C, and react for 1 hour to obtain the product.

[0019] The gloss of the product is 100%, the tensile strength is 4MPa; the surface drying time is 25s, and the hard drying time is 20min. After soaking in water for 20d, there will be no blistering or...

Embodiment 3

[0021] An unsaturated polyester coating for ceramics. The raw materials are as follows in parts by weight: 100 parts of epoxy acrylate; 35 parts of dipentaerythritol hexaacrylate; 20 parts of cadmium oxide; 40 parts of benzoin dimethyl ether; 90 parts of water ; 15 parts of isophthalic acid; 10 parts of iron oxide red; 25 parts of N-vinylpyrrolidone; 30 parts of maleic acid monobutyl ester; 35 parts of triisocyanate; 5 parts of hexamethoxymethyl melamine; 25 parts of maleic anhydride Parts; 20 parts of borax; 15 parts of adipic acid; 30 parts of clay.

[0022] Put the above-mentioned raw materials in a reaction kettle, stir while blowing nitrogen, after mixing uniformly, heat up to 180°C for 1 hour, continue to heat up to 220°C, and react for 1 hour to obtain the product.

[0023] The gloss of the product is 110%, the tensile strength is 5MPa; the surface drying time is 20s, and the hard drying is 15min. There is no blistering or shedding after soaking in water for 30d; there is no...

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Abstract

The invention discloses an unsaturated polyester paint for ceramics, which is prepared from epoxy acrylate, dipentaerythritol hexaacrylate, cadmium oxide, 2,2-dimethoxy-2-phenylacetophenone, water, m-phthalic acid, a tinting pigment, N-vinyl-2-pyrrolidone, monobutyl maleate, triisocyanate, a crosslinking agent, maleic anhydride, borax, adipic acid and clay. The product glossiness is 90-110%, and the tensile strength is 3-5 MPa; the surface drying time is 20-30 seconds, and the solid drying time is 15-25 minutes; after being immersed in water for 10-30 days, the paint has no phenomenon of blistering or shedding; after being immersed in saturated calcium hydroxide for 5-15 days, the paint does not blister or wrinkle; and the product has high friction resistance and high hardness, and can be widely produced and used instead of the existing materials.

Description

Technical field [0001] The application belongs to the field of coatings, and particularly relates to an unsaturated polyester coating for ceramics. Background technique [0002] The output of daily-use ceramics produced in China accounts for about 70% of the world's total, the output of decorative art ceramics accounts for 65% of the global output, and the output of architectural ceramics also accounts for half of the world's total output. The ceramic industry occupies a pivotal position in the world's building materials industry. With the popularization of the concept of humanization and the formation of a new harmonious society, it is very necessary to design an unsaturated polyester coating for ceramics that is wrinkle-free, non-sticky, and has good drying properties. Summary of the invention [0003] Technical problems solved: [0004] In view of the above technical problems, the present application provides an unsaturated polyester coating for ceramics, which solves the techn...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D4/02
Inventor 费金华
Owner SUZHOU SHENGPULA NEW MATERIAL SCI & TECH