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Preparation method of low-internal-loss medium-resistant polyurethane elastomer material for vibration isolators

A polyurethane elastomer and vibration isolator technology, applied in the field of material preparation, can solve the problems of material aging, poor mobility, insufficient aging resistance, etc., and achieve the effects of small internal friction, excellent oil resistance, and simple and feasible preparation method.

Active Publication Date: 2014-12-03
725TH RES INST OF CHINA SHIPBUILDING INDAL CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, with the extension of the service time of the rubber vibration isolator, there will be phenomena such as material aging and performance degradation, resulting in a short service life of the rubber vibration isolator, and various forms of failure will appear in only 7 to 10 years
[0003] In addition, due to the serious aging phenomenon of the rubber vibration isolator during storage, its service life is further shortened, and even some rubber vibration isolators have failed before installation. Once the rubber vibration isolator fails, it must be maintained and replaced in time, otherwise it will directly Affect the safety of equipment, and there are problems such as difficulty, high cost, and poor mobility when replacing
[0004] There are also TDI and MDI as reaction raw materials to synthesize cast polyurethane elastomer materials and manufacture polyurethane vibration isolators. The vibration damping effect is good, but the internal friction of the cast polyurethane elastomer material is large, and the heat generation is serious, resulting in insufficient aging resistance, which seriously affects the performance of the cast polyurethane vibration isolator and limits its application to a certain extent

Method used

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  • Preparation method of low-internal-loss medium-resistant polyurethane elastomer material for vibration isolators
  • Preparation method of low-internal-loss medium-resistant polyurethane elastomer material for vibration isolators
  • Preparation method of low-internal-loss medium-resistant polyurethane elastomer material for vibration isolators

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Embodiment Construction

[0021] The following table examples 1-3 are the formula quantities for preparing polyurethane raw rubber.

[0022]

[0023] After the polytetrahydrofuran ether PTMG was vacuum dehydrated at 120°C for 2 hours, the polytetrahydrofuran ether was placed in a three-necked flask in an oil bath at 100°C under the protection of nitrogen according to the formula in the above table, and 1 was added at a speed of 200rad / min. 5-Naphthalene diisocyanate NDI, increase the stirring speed to 1000rad / min, mix NDI in PTMG evenly and react, add glycerol α-allyl ether as a chain extender after mixing for 30min, and continue to react for 20min. The product was poured out and treated in an oven at 120° C. for 6 hours to obtain polyurethane synthetic raw rubber.

[0024] The following table examples 4-6 are the formula quantities for preparing the mixed rubber material.

[0025]

[0026] Accelerator D or Accelerator M are trade names. After kneading evenly on the open mill, put the sheet...

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Abstract

The invention relates to a preparation method of a low-internal-loss medium-resistant polyurethane elastomer material for vibration isolators. The preparation method comprises the following steps: preparing polyurethane unvulcanized rubber, preparing a mixed rubber material, and preparing the polyurethane elastomer material. The polyurethane unvulcanized rubber contains polyether glycol or polyester polyol, aromatic organic diisocyanates and glycerol alpha-allyl ether; and the mixed rubber material contains a reinforcing filler, a vulcanizing agent and an accelerator. The prepared mixed rubber material is subjected to sheet discharge, cutting, put in a metal mold, and subjected to heating and press vulcanization molding on a hot press, thereby preparing the polyurethane elastomer material, wherein the heating temperature is controlled at 130-150 DEG C, the pressure is controlled at 8-12 MPa, and the vulcanization molding is controlled at 25-50 minutes. The method eliminates the factors for increasing internal loss due to asymmetric molecular chain, and improves and enhances the medium resistance of the polyurethane elastomer material.

Description

technical field [0001] The invention belongs to the technical field of material preparation, in particular to a method for preparing a low internal friction and medium-resistant polyurethane elastomer material for a vibration isolator. Background technique [0002] Rubber vibration isolator is the most widely used type of vibration isolator. It has the advantages of compact structure, good manufacturability, and low cost. It can be vulcanized into any geometric shape according to the structural requirements of the load-bearing equipment. Generally, in order to adapt to the application environment, nitrile rubber and natural rubber with excellent oil resistance are mostly used. However, with the prolongation of the use time of the rubber vibration isolator, there will be phenomena such as material aging and performance degradation, resulting in a short service life of the rubber vibration isolator, and various forms of failure will appear in only 7 to 10 years. [0003] In a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L75/08C08L75/06C08K3/04C08K3/36C08K3/06C08G18/76C08G18/67C08G18/66C08G18/48C08G18/42
Inventor 王雯霏刘正马玉亮
Owner 725TH RES INST OF CHINA SHIPBUILDING INDAL CORP
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