High value element-containing and iron hydroxide-based raw material and application thereof
An iron hydroxide-based, high-value technology, applied in the direction of iron oxide/iron hydroxide, process efficiency improvement, etc., can solve problems that restrict the comprehensive utilization of resources and the development of circular economy, affect trade and cooperation, and analyze and sample difficulties. , to achieve the effect of convenient further utilization, not easy to escape and burn, and strong resource
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Embodiment 1
[0036] To the NdFeB waste slag (in the form of hard clay lumps, REO23.11wt% in terms of oxides, CoO1.22wt% and 42.53wt% of Fe in terms of elements, 3.85wt% of combustible organic matter in terms of C elements, water 15.02wt%, can be ignited with a match, spontaneously ignites when heated to about 75°C, and the fire point is 104.4°C according to the measurement) add a small amount of hydrochloric acid and an appropriate amount of water, and mix with 5-20M 3 / (M 3 *min) flow into the air, the gas (air) flow = gas (air) volume / (time * total volume of liquid and solid materials after batching), the unit is M 3 / (M 3 *min) (the same below). Control the reaction temperature to be 50-90°C, and at the Reynolds number Re=ρND 2 / μ ≥ 10000 React under mechanical stirring and ultrasonic wave for more than 3 hours, then dry in air to make ferric hydroxide-based raw materials containing high-value elements. The iron hydroxide-based raw material containing high-value elements cannot b...
Embodiment 2
[0060] Oil-free cobalt ice with an average particle size of 0.054mm, containing CoO5.77wt%, NiO17.33wt%, CuO4.78wt%, and Fe58.42wt% in terms of oxides was obtained from nickel-smelting converter slag through "electric furnace depletion" and other processes Copper is used as raw material, add a small amount of sulfuric acid, ammonium sulfate and appropriate amount of water, and use 5-20M 3 / (M 3 *min) flow into the air, control the reaction temperature is 50-90 ° C, and at the Reynolds number Re = ρND 2 / μ ≥ 10000 Reacted for more than 3 hours under stirring conditions, and then dried to produce iron hydroxide-based raw materials containing high-value elements, in which iron hydroxide and other iron elements are TFe32.41wt% as elements, and cobalt is 3.2wt% as CoO , nickel is 9.61wt% as NiO, copper is 2.65wt% as CuO, moisture is 13.34wt%, Y(Fe) is 0.25wt%, Y(Fe 3+ ) is 19.45wt%.
[0061] Cobalt matte has a large proportion of alloyed substances. It is generally believed tha...
Embodiment 3
[0065] Add a small amount of hydrochloric acid and an appropriate amount of water to the cement agglomerated NdFeB waste residue containing 1.65wt% of flammable organic matter in terms of C elements, and add 5-20M 3 / (M 3 *min) flow into the air, control the reaction temperature is 50-90 ° C, and at the Reynolds number Re = ρND 2 / μ ≥ 10000 under stirring conditions for more than 3 hours, and then make iron hydroxide-based raw materials containing high-value elements mainly composed of iron hydroxide, rare earth elements, cobalt elements and water. It cannot be ignited with a match, and the ignition source should be kept heated to 200 ℃ and heat preservation for one hour the material did not catch fire. Among them, iron hydroxide and other iron elements are TFe3.58wt% as elements, cobalt is 0.24wt% as CoO, rare earth elements are 2.2wt% as REO, moisture is 52wt%, combustible organic matter is 0.13wt% as C elements, Y( Fe) is 0.02wt%, Y (Fe 3+ ) is 3.41wt%.
[0066] The ab...
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