Preparation method of composite molecular sieve material with photocatalysis performance

A composite molecular sieve and molecular sieve technology, which is applied in the field of preparation of composite molecular sieve materials, can solve the problems of limited application and poor adsorption capacity, and achieve the effects of inhibiting recombination, improving photocatalytic activity, and improving photocatalytic performance

Inactive Publication Date: 2015-02-04
SHENYANG LIGONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Anatase phase TiO 2 Although it has excellent photocatalytic activity, this crystal form of TiO 2 The poor adsorption capacity limits its further application.

Method used

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Experimental program
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Embodiment 1

[0016] A composite molecular sieve material with photocatalytic properties, characterized in that: the sol-gel method is used to load TiO on the molecular sieve after ion exchange with hydrochloric acid 2 Photocatalyst composition.

[0017] A method for preparing a composite molecular sieve material with photocatalytic performance, comprising the following process steps:

[0018] (1) Preparation of HY, HX and HZSM-5 molecular sieves

[0019] Put 100g of NaY, NaX or NaZSM-5 molecular sieves and 400mL of 0.3mol / L hydrochloric acid solution in a 1L four-necked flask, and use water cooling to reflux the water vapor. H at 90-95 °C + -Na + After ion exchange for 4 hours, the solution was filtered by suction filtration. The obtained filter cake was dried in an electric drying oven at 100-120°C for 4 hours, and then placed in a program-controlled box-type electric furnace for calcination at 550°C for 4 hours to obtain HY, HX or HZSM-5 molecular sieves.

[0020] (2) Sol-gel synthe...

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Abstract

A preparation method of a composite molecular sieve material with a photocatalysis performance is characterized in that the method comprises the following steps: carrying out ion exchange on Y, X or ZSM-5 molecular sieve by hydrochloric acid, and loading a TiO2 photocatalyst on the obtained molecular sieve through a sol-gel process. The composite molecular sieve material can inhibit electron-hole pair recombination to make organic matters adsorbed on the molecular sieve easily obtain free active groups in order to improve the photocatalytic activity of the photocatalyst.

Description

technical field [0001] The invention belongs to the field of water purification functional materials, and in particular relates to a preparation method of a composite molecular sieve material with photocatalytic performance. Background technique [0002] Molecular sieve is a kind of aluminosilicate, which uses silicon-oxygen tetrahedron as the basic structural unit, and the oxygen bridge formed by oxygen atoms connects the silicon-oxygen tetrahedron to form an anion skeleton with a regular cage or pore structure. Molecular sieve TO 4 (T is usually Si or Al atom) The tetrahedron is connected to each other through the oxygen atoms at the vertices to form a multi-component ring structure. These polycyclic rings constitute the pores in the molecular sieve, and their effective diameter is called the pore size. On the basis of the ring, it is connected to become a skeleton of three-dimensional space, and the cavity surrounded by it is called a cage. These different cages are pe...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J29/40B01J29/08
Inventor 张文杰
Owner SHENYANG LIGONG UNIV
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