Method for processing organic wastewater by electro-fenton

A technology for organic wastewater and wastewater, applied in multi-stage water treatment, water/sewage treatment, chemical instruments and methods, etc., can solve the problems of difficult removal of iron ions and low efficiency of pollutant removal, so as to save investment and improve reaction efficiency , Overcoming the effect of difficult removal of iron ions and low removal efficiency of pollutants

Inactive Publication Date: 2015-02-04
SUZHOU FUQINUO WATER TREATMENT EQUIP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0016] In view of the above documents, the present invention provides a method that can use ultrasonic crushing reaction as a pre-treatment, and then use mineralized waste to participate in electrolytic sewage purification, thereby overcoming the shortcomings of difficult removal of iron ions and low efficiency of pollutant removal in the existing Fenton technology. A kind of electro-fenton method for treating organic wastewater

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] A method for electro-Fenton treatment of organic wastewater, the specific steps are as follows: (1) Add a sufficient amount of activated carbon powder to the wastewater, and the amount of the activated carbon powder added is 0.7wt% of the weight of the wastewater; (2) Wait for the activated carbon powder to absorb a large amount of water After impurities are removed, the waste water is filtered and then injected into the ultrasonic reactor; (3) Sonic wave crushing reaction, the sound energy density of the ultrasonic wave is 0.1 / m 3 (4) After 20 minutes of reaction, the waste water flows into the electrolytic cell, and mineralized waste, H 2 o 2 solution, the solid-to-liquid ratio of mineralized waste and waste water is 1:500, the H 2 o 2Solution consumption is that the addition amount in every liter of waste water is 0.1mL, and described electrolyzer anode electrode is iron electrode, and cathode electrode is graphite electrode, connects electrolyzer electric current,...

Embodiment 2

[0033] A method for electro-Fenton treatment of organic wastewater, the specific steps are as follows: (1) Add a sufficient amount of activated carbon powder to the wastewater, and the amount of the activated carbon powder added is 0.9wt% of the weight of the wastewater; (2) Wait for the activated carbon powder to absorb a large amount of water After impurities are removed, the waste water is filtered and then injected into the ultrasonic reactor; (3) sonic crushing reaction, the sound energy density of the ultrasonic wave is 0.2 / m 3 (4) After 30 minutes of reaction, the waste water flows into the electrolytic cell, and mineralized waste, H 2 o 2 solution, the solid-to-liquid ratio of mineralized waste and waste water is 1:700, the H 2 o 2 Solution consumption is that the addition amount in every liter of waste water is 0.15mL, and described electrolyzer anode electrode is iron electrode, and cathode electrode is graphite electrode, connects electrolyzer electric current, an...

Embodiment 3

[0036] A method for electro-Fenton treatment of organic wastewater. The specific steps are as follows: (1) Add a sufficient amount of activated carbon powder to the wastewater, and the amount of the activated carbon powder added is 1.1wt% of the weight of the wastewater; (2) Wait for the activated carbon powder to be adsorbed in a large amount of water After removing impurities, filter the waste water and then inject it into the ultrasonic reactor; (3) Sonic wave crushing reaction, the sound energy density of the ultrasonic wave is 0.3 / m 3 (4) After 40 minutes of reaction, the waste water flows into the electrolytic cell, and mineralized waste, H 2 o 2 solution, the solid-to-liquid ratio of mineralized waste and waste water is 1:900, the H 2 o 2 The solution consumption is that the addition amount in every liter of waste water is 0.2mL, and the anode electrode of the electrolytic cell is an iron electrode, and the negative electrode is a graphite electrode, and the electroly...

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Abstract

The invention relates to a method for processing an organic wastewater by electro-fenton. The method comprises the following specific steps: (1) adding enough activated carbon powder to the wastewater, wherein the adding amount of the activated carbon powder accounts for 0.7wt%-1.1wt% of the wastewater; (2) adsorbing a lot of impurities in water by the activated carbon powder, filtering the wastewater and injecting into an ultrasonic reactor; (3) carrying out ultrasonic crushing reaction, wherein the sound energy density of the ultrasonic wave is 0.1-0.3w/m<3>; (4) after reacting for 20-40 minutes, feeding the wastewater into an electrolytic cell, and adding mineralized refuse and an H2O2 solution to the electrolytic cell, wherein an anode electrode of the electrolytic cell is an iron electrode and a cathode electrode is a graphite electrode; connecting current of the electrolytic cell, and lastingly stirring in the overall process; and (5) after 2-4 hours, participating after reaction is ended, thus achieving solid-liquid separation, so as to finish wastewater treatment. The ultrasonic crushing reaction is utilized as earlier stage processing, and then the mineralized refuse is utilized to participate into electrolytic sewage purification, so that the defects that iron ions are difficult to remove and the removal efficiency of pollutants is low in an existing fenton technology are solved.

Description

technical field [0001] The invention relates to a method for treating organic wastewater by Fenton with the participation of mineralized garbage, in particular to a method for treating organic wastewater by electric Fenton. Background technique [0002] In the treatment of water resources and environment, wastewater can be treated by ultrasonic waves. The cavitation effect of ultrasonic waves provides the possibility of degrading harmful organic substances in water, so that the purpose of ultrasonic sewage treatment can be realized. In the process of sewage treatment, ultrasonic cavitation has a strong ability to degrade organic matter, and the degradation speed is very fast. The high energy generated by the collapse of ultrasonic cavitation bubbles is enough to break chemical bonds, and the collapse of cavitation bubbles produces hydroxyl groups ( Oh - ) and hydrogen radicals (H + ), and the oxidation reaction with organic matter can convert harmful organic matter in wate...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/08
CPCC02F9/00C02F1/281C02F1/36C02F1/4672C02F2101/30C02F2301/08
Inventor 吴彦
Owner SUZHOU FUQINUO WATER TREATMENT EQUIP
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