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Novel preparation method of super-hydrophobic polyvinyl alcohol film

A polyvinyl alcohol film and super-hydrophobic technology, which is applied in the field of preparing super-hydrophobic polyvinyl alcohol films, can solve the problems of difficult popularization and application, expensive materials and the like, and achieve the effects of simple operation process, good reproducibility and good industrial application prospect.

Inactive Publication Date: 2015-02-04
HUNAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, these existing methods either use expensive materials, or require special processing equipment or complex processes, making it difficult to popularize and apply

Method used

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  • Novel preparation method of super-hydrophobic polyvinyl alcohol film
  • Novel preparation method of super-hydrophobic polyvinyl alcohol film
  • Novel preparation method of super-hydrophobic polyvinyl alcohol film

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] The first step is to select a fresh canna leaf, wash off the dust on the surface of the fresh canna leaf with tap water, and cut it into a size of 15cm long and 10cm wide as the original template;

[0020] In the second step, the canna leaf after cleaning is placed in a pouring mold corresponding to the length and width of the canna leaf, and the height of the pouring mold is 2cm;

[0021] The third step is to mix polydimethylsiloxane prepolymer, ethyl orthosilicate, and dibutyltin dilaurate in a ratio of 100:4:1 and stir for 20 minutes, then place it in a vacuum box The air bubbles in the mixture are drawn out, and then the mixture composed of polydimethylsiloxane prepolymer, tetraethyl orthosilicate, and dibutyltin dilaurate is poured on the fresh canna leaves in the mold and placed in the room temperature atmosphere. Curing for 24 hours to obtain a polydimethylsiloxane template, and then gently peel off the polydimethylsiloxane template from the canna leaf;

[0022]...

Embodiment 2

[0024] The first step is to select fresh canna leaves, wash off the dust on the surface of fresh canna leaves with tap water, and cut them into 15cm long and 15cm wide as the original template;

[0025] In the second step, the canna leaf after cleaning is placed in a pouring mold corresponding to the length and width of the canna leaf, and the height of the pouring mold is 3 cm;

[0026] The third step is to mix polydimethylsiloxane prepolymer, ethyl orthosilicate, and dibutyltin dilaurate in a ratio of 100:3:2 and stir for 30 minutes, then place it in a vacuum box The air bubbles in the mixture are drawn out, and then the mixture composed of polydimethylsiloxane prepolymer, tetraethyl orthosilicate, and dibutyltin dilaurate is poured on the fresh canna leaves in the mold and placed in the room temperature atmosphere. Curing for 24 hours to obtain a polydimethylsiloxane template, and then gently peel off the polydimethylsiloxane template from the canna leaf;

[0027] The four...

Embodiment 3

[0029] The first step is to select fresh canna leaves, wash off the dust on the surface of fresh canna leaves with tap water, and cut them into 10cm long and 10cm wide as the original template;

[0030] In the second step, the canna leaf after cleaning is placed in a pouring mold corresponding to the length and width of the canna leaf, and the height of the pouring mold is 5cm;

[0031] The third step is to mix polydimethylsiloxane prepolymer, ethyl orthosilicate, and dibutyltin dilaurate in a ratio of 100:3:1 and stir for 10 minutes, then place it in a vacuum box The air bubbles in the mixture are drawn out, and then the mixture composed of polydimethylsiloxane prepolymer, tetraethyl orthosilicate, and dibutyltin dilaurate is poured on the fresh canna leaves in the mold and placed in the room temperature atmosphere. Curing for 24 hours to obtain a polydimethylsiloxane template, and then gently peel off the polydimethylsiloxane template from the canna leaf;

[0032] The fourt...

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Abstract

The invention provides a novel preparation method of a super-hydrophobic polyvinyl alcohol film. The method comprises the following main preparation steps: (1) selecting a fresh canna leaf as an original template; (2) mixing and stirring a polydimethylsiloxane prepolymer, tetraethoxysilane and dibutyltin dilaurate in proportion, afterwards pouring the mixture into the fresh canna leaf and curing to obtain a polydimethylsiloxane template; and (3) soaking the polydimethylsiloxane template in a stearic acid solution, afterwards taking out and drying, subsequently pouring a polyvinyl alcohol solution onto the polydimethylsiloxane template, and drying for 10 hours to obtain the super-hydrophobic polyvinyl alcohol film, wherein the contact angle between the film and water is from 150 degrees to 160 degrees, and the roll angle of water drops on the surface of the film is smaller than 10 degrees. The preparation method of the super-hydrophobic polyvinyl alcohol film, which is provided by the invention, is simple in operation process and good in reproducibility, needs no expensive equipment and has quite good industrial application prospect.

Description

technical field [0001] The invention relates to a new method for preparing a superhydrophobic polyvinyl alcohol film in an atmospheric environment. Background technique [0002] Polyvinyl alcohol film is non-toxic, tasteless and harmless to the human body. It has good affinity with the natural environment and is biodegradable. It is an environmentally friendly polymer material that can be mass-produced by non-petroleum routes. The price is low. It is oil-resistant, It has excellent solvent resistance and gas barrier performance, and has unique advantages in food and pharmaceutical packaging. However, the biggest disadvantage of polyvinyl alcohol film is its poor water resistance. How to improve the water resistance or hydrophobicity of polyvinyl alcohol film has become a key problem that needs to be solved urgently in the field of polyvinyl alcohol film. [0003] Inspired by the lotus leaf effect, superhydrophobic surface materials with water contact angles larger than 150o...

Claims

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Application Information

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IPC IPC(8): C08J5/18C08L29/04
Inventor 袁志庆王梦蕾黄娟
Owner HUNAN UNIV OF TECH