Method for preparing lithium-rich manganese-based layered lithium battery cathode material based on efficient solid-phase chemical complexation reaction
A technology of solid-phase complexation and positive electrode materials, applied in battery electrodes, secondary batteries, electrochemical generators, etc., can solve the problem of low synthesis temperature and achieve the effects of low calcination temperature, low production cost and high production efficiency
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[0046] Example 1:
[0047] such as figure 1 Shown in the present invention based on solid-phase complexation chemical reaction to prepare lithium-rich manganese-based layered lithium battery cathode material (molecular formula is: Li[Li 0.067 Ni 0.138 Co 0.148 Mn 0.647 ]O 2 ) method, including the following steps:
[0048] (1) Material preparation: prepare lithium nitrate, nickel acetate, cobalt nitrate and manganese acetate as raw materials, prepare citric acid as solid coordination complexing agent;
[0049] (2) Grinding: According to the molecular formula (Li[Li 0.067 Ni 0.138 Co 0.148 Mn 0.647 ]O 2 ) in the metering ratio of each metal element, the raw material prepared in the step (1) and the solid coordination complexing agent are dry-mixed according to the ratio of 0.8:1, and ball-milled for 3 hours at room temperature;
[0050] (3) drying the mixture obtained in the above step (2) in an oven at 90° C. for 4 hours to obtain a solid phase complex precursor;
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[0053] Example 2:
[0054] A lithium-rich manganese-based layered lithium battery cathode material prepared based on solid-phase complexation chemical reaction of the present invention (molecular formula is: Li[Li 0.157 Ni 0.138 Co 0.134 Mn 0.571 ]O 2 ) method, including the following steps:
[0055] (1) Material preparation: prepare lithium nitrate, nickel acetate, cobalt acetate and manganese acetate as raw materials, prepare citric acid as solid coordination complexing agent;
[0056] (2) Grinding: According to the molecular formula (Li[Li 0.157 Ni 0.138 Co 0.134 Mn 0.571 ]O 2 ) in the metering ratio of each metal element, the raw material prepared in the step (1) and the solid coordination complexing agent are dry-mixed according to the molar ratio of 0.6: 1, and ball-milled for 2 hours at room temperature;
[0057] (3) drying the mixture obtained in the above step (2) in an oven at 80° C. for 5 hours to obtain a solid phase complex precursor;
[0058] (4) place...
Example Embodiment
[0060] Example 3:
[0061] such as image 3 Shown in the present invention based on solid-phase complexation chemical reaction to prepare lithium-rich manganese-based layered lithium battery cathode material (molecular formula is: Li[Li 0.205 Ni 0.132 Co 0.134 Mn 0.529 ]O 2 ) method, including the following steps:
[0062] (1) Material preparation: prepare lithium acetate, nickel nitrate, cobalt nitrate and manganese acetate as raw materials, prepare citric acid as solid coordination complexing agent;
[0063] (2) Grinding: According to the molecular formula (Li[Li 0.205 Ni 0.132 Co 0.134 Mn 0.529 ]O 2 ) in the metering ratio of each metal element, the raw material prepared in the step (1) and the solid coordination complexing agent are dry-mixed according to the molar ratio of 1: 1, and ball-milled at room temperature for 3.5 hours;
[0064] (3) drying the mixture obtained in the above step (2) in an oven at 90° C. for 4 hours to obtain a solid phase complex precur...
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