A kind of medical polyurethane film and preparation method thereof

A polyurethane film, polyurethane technology, applied in the fields of medical science, bandages, absorbent pads, etc., can solve the problems of limited application, induced infection, insignificant water absorption effect, etc., and achieves the effect of good water vapor transmission rate and excellent mechanical properties.

Active Publication Date: 2016-08-24
南通华盛高聚物科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, its disadvantage is that the moisture permeability cannot meet the needs of practical applications, which may easily lead to the accumulation of exudate under the membrane and induce infection
[0005] Polyurethane film has good elasticity, flexibility, wear resistance and tear resistance, and has good compliance, can be very good waterproof, antibacterial, and has excellent biocompatibility, and it is increasingly used in dressing applications The more attention is paid to it, and the polyurethane film as a dressing mainly relies on the transfer of water vapor to control the exudate, but the moisture permeability of the pure polyurethane film is not high, and the water absorption effect is not obvious, which greatly limits its application.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] A kind of medical polyurethane film, raw material comprises by weight: 80 parts of polyurethane, 15 parts of polyethylene, 8 parts of polyethylene glycol, 5 parts of superfine chitosan powder, 3 parts of dihexyl phthalate, 4, 4 parts of dioctyl 5-epoxytetrahydrophthalate, 6 parts of epoxy soybean oil, 7 parts of benzyl silicone oil, 5 parts of calcium carbonate, 4 parts of N-cyclohexylethanolamine, 3 parts of triphenyl phosphite , 7 parts of 1,4-dioxane, 8 parts of N,N-dimethylformamide.

[0019] The molecular weight of the above-mentioned polyethylene glycol is 2000, and the particle diameter of the ultrafine chitosan powder is 20 μm.

[0020] The preparation method of above-mentioned medical polyurethane film, comprises the following steps:

[0021] Step 1, adding each component into a mixing mixer, stirring and mixing evenly, the stirring speed is 300rpm, and the stirring time is 40min, to obtain the mixed material;

[0022] Step 2, adding the mixed material obtain...

Embodiment 2

[0025] A kind of medical polyurethane film, raw material comprises by weight: 95 parts of polyurethane, 18 parts of polyethylene, 12 parts of polyethylene glycol, 7 parts of superfine chitosan powder, 5 parts of dihexyl phthalate, 4, 7 parts of dioctyl 5-epoxytetrahydrophthalate, 9 parts of epoxy soybean oil, 9 parts of benzyl silicone oil, 8 parts of calcium carbonate, 6 parts of N-cyclohexylethanolamine, 4 parts of triphenyl phosphite , 10 parts of 1,4-dioxane, 10 parts of N,N-dimethylformamide.

[0026] The molecular weight of the above-mentioned polyethylene glycol is 2500, and the particle diameter of the ultrafine chitosan powder is 40 μm.

[0027] The preparation method of above-mentioned medical polyurethane film, comprises the following steps:

[0028] Step 1, adding each component into a mixing mixer, stirring and mixing evenly, the stirring speed is 400rpm, and the stirring time is 20min, to obtain the mixed material;

[0029] Step 2, adding the mixed material obt...

Embodiment 3

[0032] A kind of medical polyurethane film, raw material comprises by weight: 105 parts of polyurethane, 20 parts of polyethylene, 15 parts of polyethylene glycol, 9 parts of superfine chitosan powder, 6 parts of dihexyl phthalate, 4, 9 parts of dioctyl 5-epoxytetrahydrophthalate, 12 parts of epoxy soybean oil, 10 parts of benzyl silicone oil, 12 parts of calcium carbonate, 7 parts of N-cyclohexylethanolamine, 5 parts of triphenyl phosphite , 12 parts of 1,4-dioxane, 13 parts of N,N-dimethylformamide.

[0033] The molecular weight of the above-mentioned polyethylene glycol is 3000, and the particle diameter of the ultrafine chitosan powder is 40 μm.

[0034] The preparation method of above-mentioned medical polyurethane film, comprises the following steps:

[0035] Step 1, adding each component into a mixing mixer, stirring and mixing evenly, the stirring speed is 350rpm, and the stirring time is 30min, to obtain the mixed material;

[0036] Step 2, adding the mixed material...

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Abstract

The invention provides a medical polyurethane thin film and a preparation method thereof. The polyurethane thin film comprises the following raw materials: polyurethane, polyethylene, polyethylene glycol, ultra-fine chitosan powder, dihexyl phthalate, 4,5-epoxytetrahydrophthalate, epoxidized soybean oil, polymethylphenyl siloxane fluid, calcium carbonate, N-cyclohexylethanolamine, triphenyl phosphite, 1,4-dioxane and N,N-dimethylformamide. The preparation method comprises the following steps: firstly feeding each component into a mixing stirrer, uniformly mixing and stirring, then adding an obtained mixed material into a reaction kettle, heating, performing stirring reaction, finally pouring an obtained film preparing liquid into one side of a glassine paper matrix, uniformly pushing the liquid to the other side by using a coating machine, putting a coated film preparing liquid and the matrix into clear water together, taking out after film forming, washing, drying, and stripping off from the matrix to obtain the medical polyurethane thin film. The medical polyurethane thin film provided by the invention has excellent mechanical performance, and also has a very good water vapor transmission rate.

Description

technical field [0001] The invention belongs to the technical field of medical polymer materials, and in particular relates to a medical polyurethane film and a preparation method thereof. Background technique [0002] Polyurethane (PU) is the abbreviation of polyurethane. It is a general term for a class of polymers containing repeated urethane structural units (-NHCOO- groups) on the main chain of the polymer. Typical multi-embedded segment copolymers. Polyurethane elastomers contain blocks with dissimilar chemical properties, that is, soft segments and hard segments. Due to the incompatibility of soft and hard segments, polyurethane has obvious microphase separation, which is very similar to biological membranes, so it has good physical properties, biocompatibility and blood compatibility, and is a widely used medical Polymer Materials. [0003] Since polyurethane came out in 1937, it has been widely used in the biomedical field because of its excellent physical and ch...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): A61L15/26A61L15/42A61L15/24A61L15/28A61L15/34
Inventor 张春华
Owner 南通华盛高聚物科技股份有限公司
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