Unlock instant, AI-driven research and patent intelligence for your innovation.

Preparation method of photoluminescent carbon dots

A technology of carbon quantum dots and photoluminescence, which is applied in the field of preparation of photoluminescence carbon quantum dots, can solve the problems of low quantum efficiency and achieve the effect of simple operation

Active Publication Date: 2015-04-29
TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI
View PDF3 Cites 15 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Top-down methods include arc discharge, laser cutting, electrochemical oxidation, etc., which are characterized by exfoliating carbon materials into carbon nanoparticles by chemical or physical methods, and improving their luminous efficiency through further surface modification; bottom-up The methods include thermal decomposition of organic matter, template method and hydrothermal method, etc., which have the advantages of simple operation, the obtained quantum dots are amorphous, and the quantum efficiency is low.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Preparation method of photoluminescent carbon dots
  • Preparation method of photoluminescent carbon dots
  • Preparation method of photoluminescent carbon dots

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] Mix milk and deionized water evenly at a volume ratio of 1:100, then pour it into the reactor and place it in an oven for hydrothermal reaction. The temperature of the hydrothermal reaction is 150°C. After 10 hours of reaction, take out the reactor and cooled to room temperature to obtain a brownish-yellow aqueous solution dispersion system; stand still, take the supernatant containing photoluminescent carbon quantum dots for centrifugation, wash the obtained solid with deionized water, and after several times of centrifugation and washing, obtain An aqueous solution containing uniformly dispersed photoluminescent carbon quantum dots.

[0016] The test results show that: the carbon quantum dots are in a dispersed state, and the particle size distribution is mainly 20-25 nanometers, such as figure 1 Shown; The obtained carbon quantum dots are carried out fluorescence detection, and the result shows that with the wavelength of 365 nanometers of ultraviolet light irradiati...

Embodiment 2

[0018] Mix milk and deionized water evenly at a ratio of 1:1 by volume, then pour it into the reactor and place it in an oven for hydrothermal reaction. The temperature of the hydrothermal reaction is 170°C. After 5 hours of reaction, take out the reactor and cooled to room temperature to obtain a brownish-yellow aqueous solution dispersion system; stand still, take the supernatant containing photoluminescent carbon quantum dots for centrifugation, wash the obtained solid with deionized water, and after several times of centrifugation and washing, obtain An aqueous solution containing uniformly dispersed photoluminescent carbon quantum dots.

[0019] The test results show that the carbon quantum dots are in a dispersed state, and the particle size distribution is mainly 22-27 nanometers. Fluorescent detection of the obtained carbon quantum dots showed that the aqueous solution of carbon quantum dots was irradiated with ultraviolet light with a wavelength of 365 nanometers, and...

Embodiment 3

[0021] Mix milk and deionized water evenly at a ratio of 100:1 by volume, then pour it into the reactor and put it in an oven for hydrothermal reaction. The temperature of the hydrothermal reaction is 190°C. After 1 hour of reaction, take out the reactor and cooled to room temperature to obtain a brownish-yellow aqueous solution dispersion system; stand still, take the supernatant containing photoluminescent carbon quantum dots for centrifugation, wash the obtained solid with deionized water, and after several times of centrifugation and washing, obtain An aqueous solution containing uniformly dispersed photoluminescent carbon quantum dots.

[0022] The test results show that the carbon quantum dots are in a dispersed state, and the particle size distribution is mainly 22-27 nanometers. Fluorescent detection of the obtained carbon quantum dots showed that the aqueous solution of carbon quantum dots was irradiated with ultraviolet light with a wavelength of 365 nanometers, and ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention relates to the field of chemistry and nano materials, in particular to a preparation method of photoluminescent carbon dots. Milk and deionized water are uniformly mixed in any proportion and then are poured into a reaction kettle, the reaction kettle is placed in a drying oven, the mixture has a hydrothermal reaction, the reaction kettle is taken out and cooled to the room temperature after the reaction is completed, and a brown yellow aqueous solution disperse system is obtained; the brown yellow aqueous solution disperse system is left to stand, a supernatant containing the photoluminescent carbon dots is subjected to centrifugal separation, obtained solids are washed by deionized water, and an aqueous solution containing the uniformly dispersed photoluminescent carbon dots is obtained. The preparation method is simple to operate, green and environment-friendly, and the obtained photoluminescent carbon dots can be widely applied to the fields of a nanotechnology, drug delivery, biological detection, photovoltaic conversion and catalysis and the like.

Description

technical field [0001] The invention relates to the fields of chemistry and nanometer materials, in particular to a method for preparing photoluminescent carbon quantum dots. Background technique [0002] Due to the unique surface effect, small size effect, macroscopic quantum tunneling effect and quantum confinement effect, nanomaterials exhibit unique properties in terms of light, electricity, magnetism, heat, mechanics, and machinery, and have become a hot spot in material science research. Carbon nanomaterials such as fullerenes, carbon nanotubes, and graphene have become the focus of nanoscience research in recent years because of their unique properties (Shaojun Guo and Shaojun Dong. Graphene nanosheet: synthesis, molecular engineering, thin film, hybrids, and energy and analytical applications. Chem. Soc. Rev., 2011, 40, 2644-2672). In recent years, carbon quantum dots (Carbon dots, CDs) have become a new research hotspot in the fields of biosensing and imaging. Pho...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C01B31/02B82Y30/00C09K11/65
Inventor 马望京李智杨新民史瑶张林林赵艳艳张梅英
Owner TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI
Features
  • R&D
  • Intellectual Property
  • Life Sciences
  • Materials
  • Tech Scout
Why Patsnap Eureka
  • Unparalleled Data Quality
  • Higher Quality Content
  • 60% Fewer Hallucinations
Social media
Patsnap Eureka Blog
Learn More