Method for producing white rubber filling oil base oil from catalytic slurry oil

A technology of rubber filler oil and catalytic oil slurry, which is applied in the petroleum industry, hydrocarbon oil treatment, hydrogenation process, etc., can solve the problems of high metal content, limited application, environmental pollution, etc., achieve low ring-opening activity, ensure yield The effect of excellent rate and rubber miscibility

Active Publication Date: 2015-05-06
CHINA PETROLEUM & CHEM CORP +1
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the high content of sulfur and nitrogen, high metal content, and aromatics accounting for more than 50% of catalytic oil slurry, its application is limited. Except for a small amount of raw materials used in other secondary processing processes, most of them are burned as fuel oil, which not only wastes resources , causing environmental pollution

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  • Method for producing white rubber filling oil base oil from catalytic slurry oil

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preparation example Construction

[0033] The preparation process of the hydrogenation modification catalyst of the present invention comprises: after uniformly mixing the amorphous silica-alumina and the modified Y zeolite, adding a binder, kneading, rolling into agglomerates, extruding on an extruder to obtain a carrier, Reload the hydrogenation active metal.

[0034] The preparation method of amorphous silicon aluminum used comprises the steps:

[0035] a. Prepare sodium aluminate solution and sodium silicate solution;

[0036] b. Add the sodium aluminate solution and the sodium silicate solution into the gel forming tank concurrently, and ventilate and feed CO at the same time 2 gas, adjust sodium aluminate solution, sodium silicate solution and CO 2 Flow rate, control the pH value of the material in the gel tank to 9-11, control the neutralization reaction temperature to 20-50°C, and the neutralization reaction time to 0.5-1.5 hours;

[0037] c. Under the controlled temperature and pH value of step b, t...

Embodiment 1

[0054] Prepare 700 solid sodium aluminate to a concentration of 200gAl 2 o 3 / L concentrated sodium aluminate solution, then diluted to a concentration of 35gAl 2 o 3 / L sodium aluminate working solution (a), take SiO 2 28wt% sodium silicate solution, then diluted to a concentration of 150gSiO 2 / L sodium silicate working solution 2L (b). Take a 30L steel plastic tank, open the container valves containing (a) and (b) respectively, and ventilate and feed CO with a concentration of 45v% at the same time 2 Gas, set the flow rate of (a) and (b) so that the reaction time is 1 hour, and quickly adjust the CO 2 flow rate, keep the pH of the system at about 10.0, and the reaction temperature is 30°C. After the reaction of (a) and (b) is completed, stop feeding CO 2 , and then the ventilation was stable for 40 minutes, and the slurry was filtered and washed with 85°C deionized water until neutral. Dry at 120°C for 8 hours, crush and sieve to obtain amorphous silica-alumina GL. ...

Embodiment 2

[0056] Get 80g silicon aluminum GL, 30g modified Y zeolite (SiO 2 / Al 2 o 3 40, unit cell constant 2.432nm, infrared acidity 0.19mmol / g specific surface 866m 2 / g, pore volume 0.52ml / g) and 250g adhesive made by peptizing nitric acid and SB alumina, kneading, rolling, making extrudable paste, extruding into strips. Carrier A was obtained by drying at 110°C for 6 hours and calcining at 550°C for 4 hours. Then 80 g of A was impregnated with 200 ml of a Mo-Mi co-impregnation solution in excess for 2 hours, dried at 110° C. for 6 hours, and calcined at 500° C. for 4 hours to obtain hydrogenation upgrading catalyst A. The physical properties of the hydrogenation upgrading catalyst are shown in Table 2.

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Abstract

The invention discloses a method for producing white rubber filling oil base oil through catalytic slurry oil hydrogenation. The method comprises the following steps: catalytic slurry oil is subjected to fractionation, such that a light fraction and a heavy fraction are obtained; the light fraction is mixed with hydrogen, and the mixture enters a hydrogenation treatment reaction zone; the mixture sequentially contacts a hydrogenation protection catalyst, a hydro-refining catalyst and a hydro-upgrading catalyst A, such that a hydrogenation reaction is carried out; a hydrogenation treatment effluent enters a hydro-upgrading reaction zone; a hydro-upgrading catalyst B containing amorphous silica-alumina and modified Y zeolite is adopted in the hydro-upgrading reaction zone, and a hydro-upgrading reaction is carried out under the existence of hydrogen; a hydro-upgrading effluent enters a hydro-finishing reaction zone, and is subjected to a hydro-finishing reaction; and a hydro-finishing product is separated, such that the rubber filling oil base oil is obtained. According to the invention, the catalytic slurry oil is adopted as a raw material, and can be used for producing the white rubber filling oil base oil with good low-temperature fluidity, good intersolubility with rubber, and good oxidation stability.

Description

technical field [0001] The present invention relates to a production method of rubber extension oil base oil, specifically a method for producing white rubber extension oil base oil by using hydrogenation treatment-hydrogenation modification-hydrogenation supplementary refining combined hydrogenation process method of catalytic oil slurry method. Background technique [0002] Naphthenic crude oil to produce rubber extension oil: In order to improve some properties of rubber, mineral oil needs to be filled into synthetic rubber, so it is called rubber extension oil. In synthetic rubber, the rubber chain structure usually contains benzene ring structure. According to the principle of similarity and mutual solubility, aromatic oil should be the ideal rubber oil, followed by naphthenic oil. However, because aromatic oil is a highly toxic substance, as people's calls for health, safety, and environmental protection are increasing day by day, and some high-end products such as sp...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G67/14
CPCC10G67/14
Inventor 赵威全辉姚春雷张志银孙国权林振发
Owner CHINA PETROLEUM & CHEM CORP
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