Filtrate loss reducer for full oil-based drilling fluid, and preparation method of filtrate loss reducer

A fluid loss control agent and drilling fluid technology, which is applied in the field of oil exploration, can solve the problems of high softening point of fluid loss control agent, hindered application and popularization, and increased emulsifier dosage, so as to achieve superior environmental protection performance and reservoir protection Performance, far-reaching economic and social benefits, and the effect of improving the stability of emulsions

Active Publication Date: 2015-05-13
BC P INC CHINA NAT PETROLEUM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In recent years, water-in-oil drilling fluid (dispersed phase content ≥ 10%) has been widely used, but there are still some deficiencies: ① Drilling fluid contains a large number of emulsified water droplets, with high plastic viscosity, which affects the ROP and causes reservoir Emulsification blockage; ②In order to maintain the stability of the emulsion, the amount of emulsifier is increased, which will cause the wettability of the rock surface to change from hydrophilic to oil-friendly, resulting in reservoir damage; ③The activity of water in the formation and the drilling fluid water Phase activity is difficult to achieve equilibrium, thus destabilizing the wellbore
Although the full oil base oil has the above advantages, its application and popularization are hindered due to the difficulty in controlling its fluid loss.
[0003] Shale gas wells in Weiyuan-Changning area in China have high density (>2.0g / cm 3 ), low temperature (70°C-90°C), and small pore throat radius (nano-micron level), etc., bring the following technical difficulties to high-density oil-based drilling fluids: difficult plugging and large fluid loss; ordinary bitumen Fluid loss additives have a high softening point, and are less effective at low temperatures; common fluid loss additives have too large a particle size, which does not match the size of shale pores, and cannot form a sealing plug
[0004] Therefore, it is an urgent problem to be solved in this field to provide a kind of fluid loss control agent which can solve the problem that the full oil-based fluid loss control is difficult

Method used

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  • Filtrate loss reducer for full oil-based drilling fluid, and preparation method of filtrate loss reducer

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] This embodiment provides a method for preparing a fluid loss control agent for an all-oil-based drilling fluid, comprising the following steps:

[0029] Put 100 parts by weight of humic acid and 20 parts by weight of toluene into the autoclave, and after stirring evenly, pass nitrogen gas at 0.5 MPa, add 30 parts by weight of diethylenetriamine, heat to 200°C, and stir at this temperature for 3 After 1 hour, a black product was obtained;

[0030] Cool down to normal temperature, dry, and pulverize to obtain a black powder sample which is humic acid amide.

[0031] Add 10 parts by weight of sodium cetyl sulfonate to 60 parts by weight of 0# diesel oil and stir evenly, slowly inject nitrogen into the autoclave until the pressure is 0.7MPa, and heat the autoclave to 110°C;

[0032] Then add 60 parts by weight of petroleum asphalt to the emulsion, stir and react for 6 hours, after the macromolecular micelle compound is uniformly dispersed, put 20 parts by weight of humic a...

Embodiment 2

[0034] This embodiment provides a method for preparing a fluid loss control agent for an all-oil-based drilling fluid, comprising the following steps:

[0035] Put 100 parts by weight of humic acid and 20 parts by weight of benzene into the autoclave, stir evenly, then pass nitrogen gas at 0.5 MPa, add 30 parts by weight of diethanolamine, heat to 220°C, and stir at this temperature for 4 hours. , to obtain a black product;

[0036] Cool down to normal temperature, dry, and pulverize to obtain a black powder sample which is humic acid amide.

[0037] Add 10 parts by weight of oleic acid diethanolamide emulsifier to 60 parts by weight of 0# diesel oil and stir evenly, slowly feed nitrogen into the autoclave until the pressure is 0.7MPa, and heat the autoclave to 110°C;

[0038] Then add 60 parts by weight of petroleum resin to the emulsion, stir and react for 8 hours, after the macromolecular micelle compound is uniformly dispersed, put 20 parts by weight of humic acid amide i...

Embodiment 3

[0040] This embodiment provides a method for preparing a fluid loss control agent for an all-oil-based drilling fluid, comprising the following steps:

[0041] Put 100 parts by weight of humic acid and 20 parts by weight of carbon tetrachloride into an autoclave, and after stirring evenly, feed nitrogen gas at 0.5 MPa, add 30 parts by weight of triethanolamine, heat to 210°C, and stir at this temperature to react After 4 hours, a black product was obtained;

[0042] Cool down to normal temperature, dry, and pulverize to obtain a black powder sample which is humic acid amide.

[0043] Add 10 parts by weight of span-65 to 60 parts by weight of 0# diesel oil and stir evenly, slowly inject nitrogen into the autoclave until the pressure is 0.7MPa, and heat the autoclave to 110°C;

[0044] Then add 60 parts by weight of natural asphalt to the emulsion, stir and react for 6 hours, after the macromolecular micelle compound is uniformly dispersed, put 20 parts by weight of humic acid ...

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Abstract

The invention provides a filtrate loss reducer for full oil-based drilling fluid, and a preparation method of the filtrate loss reducer. The filtrate loss reducer comprises the following raw materials in parts by weight: 130-140 parts of an emulsion micelle compound and 20 parts of humic acid acetamide, wherein the emulsion micelle compound comprises the following raw materials in parts by weight: 60 parts of diesel oil, 10 parts of an emulsifying agent, and 60-70 parts of a macromolecular micelle compound. The filtrate loss reducer for full oil-based drilling fluid, which is provided by the invention, is simple in preparation technology, the performance of products is good, the rheological property and filtration reducing property of drilling fluids can be remained, the oil-gas layers can be effectively protected, the collapse of oil-gas layers is avoided, and the borehole diameter is prevented from enlarging.

Description

technical field [0001] The invention relates to a fluid loss reducer for full oil-based drilling fluid and a preparation method thereof, belonging to the field of petroleum exploration. Background technique [0002] In recent years, water-in-oil drilling fluid (dispersed phase content ≥ 10%) has been widely used, but there are still some deficiencies: ① Drilling fluid contains a large number of emulsified water droplets, with high plastic viscosity, which affects the ROP and causes reservoir Emulsification blockage; ②In order to maintain the stability of the emulsion, the amount of emulsifier is increased, which will cause the wettability of the rock surface to change from hydrophilic to oil-friendly, resulting in reservoir damage; ③The activity of water in the formation and the drilling fluid water The phase activity is difficult to achieve equilibrium, thus destabilizing the wellbore. Full oil-based drilling fluid contains a small amount of water (dispersibility content ≤...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/035C09K8/32
CPCC09K8/035C09K8/32
Inventor 张洁赵志良李英敏杨海军王立辉王发云郑建龙孙明皓王建华王双威
Owner BC P INC CHINA NAT PETROLEUM CORP
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