The invention provides an oil-bases stuck freeing agent composition for drilling fluid and a preparation method for the oil-based stuck freeing agent composition. The composition contains span-80 or span-60, span-20 or span-40, alkyl benzene sulfonic acid, petroleum acid, poly acid and mineral oil. The preparation method includes pumping raw material components into a reaction kettle, stirring, heating to 65 DEG C-95 DEG C, heat-preserving, stirring for reacting for 120-180 minutes, cooling to the room temperature and discharging for packaging. A using method of the stuck freeing agent includes determining density of stuck freeing spotting fluid according to safe density of the drilling fluid needed on the spot, stirring water, diesel, kerosene, or other mineral oil and the stuck freeing agent, adding barite and stirring to form stuck freeing spotting fluid emulsion, pumping the formed emulsion into a sticking section for soaking to unfreeze, and continuously pumping into the stuck freeing spotting fluid at a speed of 0.16-0.36M3/h at the soaking stage until the sticking is released. The oil-based stuck freeing agent composition for the drilling fluid is convenient to use on the spot, small in using amount, convenient to conventionally carry for drilling crew, the maximum using amount is 8.7% of the stuck freeing spotting fluid, fluctuation range of stuck freeing time is narrow, the stuck freeing time of the stuck freeing spotting fluid with a density of 2.28g.cm<-3> ranges from 80 minutes to 160 minutes.