Nano-chitosan composite material and nano-coated particle products

A nano-chitosan, composite material technology, applied in soil conditioning materials, organic fertilizers, fertilizer mixtures, etc., can solve problems such as soil pollution, long decomposition time, plant death, etc., to ensure survival and growth, good water retention, inhibiting The effect of water and fertilizer loss

Active Publication Date: 2015-05-20
马新亮
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] 1. It is refined from petroleum and its derivatives, which will pollute the soil and decompose in the soil for a long time
[0005] 2. The reaction stock solution of products such as water-retaining agent and water-absorbing resin is a highly toxic substance, which has toxins that attack nerves. Although the toxicity is reduced after the reaction, it has negative effects such as inhibiting the growth of soil microorganisms and plants.
[0006] 3. All chemical water-retaining products such as water-retaining agents on the market, after years of desert field tests and many experts' demonstrations, will absorb water back when the humidity of the soil is higher than the chemical water-absorbing substances such as water-retaining agents themselves, making their surroundings rapid inhalation of moisture, resulting in accelerated plant death

Method used

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  • Nano-chitosan composite material and nano-coated particle products
  • Nano-chitosan composite material and nano-coated particle products
  • Nano-chitosan composite material and nano-coated particle products

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] Embodiment 1 Preparation of nano-chitosan composite material and nano-coated particle products

[0039] In the present embodiment, PLA (polylactic acid), chitosan and hydroxypropyl methylcellulose are used as main raw materials, wherein, polylactic acid 2g, hydroxypropylmethylcellulose 10g, chitosan 5g, vinyl ketone 10g of quasi-polymer, 0.5g of oxygen release agent, 0.1g of dispersant, 0.1g of nano particle additive; 0.5g of curing agent, 200ml of distilled water. Concrete process steps are as follows:

[0040] (1) At normal temperature and pressure, dissolve 2g of polylactic acid in 20ml of dichloromethane to prepare a PLA organic solution with a mass percentage of 7.9%, then heat it to 50°C under normal pressure, and add 10g of hydroxypropylmethyl Cellulose, mixed evenly to form a PLA-hydroxypropyl methylcellulose mixed solution, under the conditions of normal pressure, 70°C, and nitrogen protection, a polymerization reaction occurred to obtain a jelly, and the reac...

Embodiment 2

[0046] Example 2 Preparation of nano-chitosan composite material and nano-coated particle products

[0047] In this embodiment, PLA (polylactic acid), chitosan and hydroxypropyl methylcellulose are used as main raw materials, wherein, polylactic acid 4g, hydroxypropylmethylcellulose 20g, chitosan 10g, vinyl ketone 15g of quasi-polymer, 1g of oxygen release agent, 0.16g of dispersant, 0.12g of nano particle additive; 0.8g of curing agent, 200ml of distilled water. Concrete process steps are as follows:

[0048] (1) Preparation of polymer composite solution:

[0049] Dissolve 4g of polylactic acid in 20ml of organic solvent methylene chloride under normal temperature and pressure to prepare a PLA organic solution with a mass percentage of 13.3%. base cellulose to form a PLA-hydroxypropyl methylcellulose mixed solution. Under normal pressure, 70° C., under the environment of nitrogen protection, a polymerization reaction occurs under the action of an initiator to obtain a jell...

Embodiment 3

[0050] Example 3 Preparation of nano-chitosan composite material and nano-coated particle products

[0051] In this embodiment, PLA (polylactic acid), chitosan and hydroxypropyl methylcellulose are used as main raw materials, wherein, polylactic acid 6g, hydroxypropylmethylcellulose 30g, chitosan 15g, vinyl ketone 20g of quasi-polymer, 1.5g of oxygen release agent, 0.18g of dispersant, 0.14g of nano particle additive; 1g of curing agent, 200ml of distilled water. Concrete process steps are as follows:

[0052] (1) Preparation of polymer composite solution:

[0053] Dissolve 6g of polylactic acid in 20ml of organic solvent dichloromethane under normal temperature and pressure, and prepare a PLA organic solution with a mass percentage of 18.7%. base cellulose to form a PLA-hydroxypropyl methylcellulose mixed solution. Under normal pressure, 70° C., under the environment of nitrogen protection, a polymerization reaction occurs under the action of an initiator to obtain a jelly...

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Abstract

The invention discloses a nano-chitosan composite material prepared from the following raw materials in parts by weight: 2-15 parts of polylactic acid, 5-35 parts of chitosan, 10-40 parts of hydroxypropyl methyl cellulose, 10-30 parts of a vinyl ketone polymer, 0.5-2 parts of an oxygen release compound, 0.1-0.2 part of a dispersing agent and 0.1-0.15 part of nano-particle additives. The invention also discloses a preparation method of the nano-chitosan composite material. The nano-chitosan composite material disclosed by the invention has good water-retaining performance and water resistance, and can be applied as a coating material, for example, the nano-chitosan composite material can be taken as the coating material for wrapping water or fertilizers to form nano-coated particle products. The invention discloses a preparation method of the nano-coated particle products. The nano-coated particle products disclosed by the invention have slow release performance, and after being mixed with soil, the water or fertilizers wrapped by the nano-coated particle products can be released to the soil in a slow release mode, so that the nano-coated particle products can be widely applied to desertification control processes and can be used for scientifically and efficiently performing desertification control operations.

Description

technical field [0001] The invention relates to a nano-chitosan composite material, a preparation method and application thereof, and a particle product coated with the nano-composite material and a preparation method thereof. Background technique [0002] The world's land area is 162 million square kilometers, of which the desert area accounts for 20% of the total land area, and 43% of the land is facing the threat of desertification. In my country, the desertification area accounts for 17% of the total land area of ​​the country. Desertification seriously destroys land resources, reduces the land area available for farming and animal husbandry, degrades the land's reproductive capacity, reduces the number of plants, reduces the livestock capacity of the land, and reduces the yield per unit area of ​​crops. Desertification has caused serious losses to agriculture, animal husbandry and people's living property in many countries and regions. The environment in the desertifi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L1/28C08L39/06C08L5/08C08L67/04C08K3/22C08K5/103C08K3/16C08K3/28C05G3/00C09K17/32C09K101/00
Inventor 马新亮马万龙李传波
Owner 马新亮
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