Method for olefin hydroformylation reaction through adopting solid heterogeneous catalyst

Abstract

The invention relates to a method for an olefin hydroformylation reaction of olefin through adopting a solid heterogeneous catalyst. The method is characterized in that the method adopts the solid heterogeneous catalyst, the solid heterogeneous catalyst is composed of a metal component and an organic ligand polymer with a hierarchical pore structure, the metal component is one or more of Rh, Ir and Co, the organic ligand polymer is a polymer formed by polymerizing an organic ligand monomer containing P, an alkylene group and optional N, and the metal component and the P atom or N in the skeleton of the organic ligand polymer form a coordination bond and exist in a monoatomic dispersion state. The olefin hydroformylation reaction of an olefin raw material and a CO / H2 mixed gas is carried out in the presence of the solid heterogeneous catalyst in a reactor. The method adopting the novel solid heterogeneous catalyst has the advantages of simple reaction process and apparatus, stable hydroformylation performance of the catalyst, high activity and yield, and wide industrial application prospect.

Description

technical field [0001] The invention relates to a method for catalyzing olefin hydroformylation by using a novel solid heterogeneous catalyst, which belongs to the field of heterogeneous catalytic reaction technology. Background technique [0002] The hydroformylation reaction is olefin and synthesis gas (CO+H 2 ) reaction to prepare an aldehyde with one carbon higher than the raw material olefin. The reason why hydroformylation technology is widely used in the chemical industry and has become one of the most important technologies is mainly because its product aldehyde is a useful chemical intermediate, which can synthesize carboxylic acids and their corresponding esters, and Fatty amine, etc., the most important use is that it can be converted into alcohol by hydrogenation, and alcohol itself can be widely used in the field of fine chemical industry as organic solvent, plasticizer and surfactant. With the increasing demand for aldehydes and alcohols in industries such as...

AI Technical Summary

Problems solved by technology

Although many innovative concepts have emerged in these catalytic systems, the loss of active metals in these systems is serious, or the stability of the catalyst is poor, or expensive organic ligands and solvents are used, or the preparation process of the catalyst is cumbersome. Complexity, etc., cannot meet the needs of industrial production

In heterogeneous catalytic systems, there are only a small number of reports on adding metal additives to heterogeneous catalysts to improve their catalytic performance, but because the catalytic activity of these systems is far lower than that of homogeneous catalytic systems, they cannot meet the needs of industrial production.

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