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Pretreatment apparatus for biogas online laser Raman spectrometer, and use method thereof

A technology of laser Raman spectroscopy and preprocessing equipment, which is applied in the direction of material excitation analysis, Raman scattering, preparation of test samples, etc., to achieve the effects of easy use and maintenance, elimination of fluorescence interference, and simple structure

Active Publication Date: 2015-06-17
GUANGZHOU INST OF ENERGY CONVERSION - CHINESE ACAD OF SCI +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The purpose of the present invention is to detect the biogas on-line by the laser Raman spectrometer, because the tar, ash, water, impurities in the biogas to be detected interfere with the Raman fluorescence, the temperature of the sample is too high, the pressure and flow rate of the biogas In order to solve the problems such as fluctuations in the analysis data that affect the accuracy of the analysis data, sensitivity and continuous and stable operation, a pretreatment device and method for the online laser Raman spectrometer of biogas are provided to realize the purification, removal of impurities and cooling of the samples to be tested. Cooling and flow rate adjustment pretreatment to eliminate fluorescence interference to ensure the stable operation of the laser Raman gas analyzer and the accuracy, sensitivity and real-time performance of the Raman analysis data, providing for the continuous operation and real-time monitoring of biogas demonstration application devices data accumulation

Method used

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  • Pretreatment apparatus for biogas online laser Raman spectrometer, and use method thereof
  • Pretreatment apparatus for biogas online laser Raman spectrometer, and use method thereof
  • Pretreatment apparatus for biogas online laser Raman spectrometer, and use method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0036] Example 1: The biogas comes from the outlet of the gasifier, reformer and gas storage cabinet in the biomass gasification system

[0037] The inlet of the pretreatment device 1 used for the online laser Raman spectrometer of the biogas passes through the pipeline and the gasification furnace, the reformer and the gas holder outlet from the biomass gasification system containing H 2 , CO, N 2 , O 2 , a small amount of C 1 -C 4 Gaseous hydrocarbons, CO 2 It is connected with the biogas of tar and ash, and the outlet of the device 1 is connected to the laser Raman spectrometer 3 through a pipeline; the device 1 includes a tar purification unit 6, a cooling processing unit 4 and a constant speed control unit 5 connected in sequence; the inlet of the device 1 Connect with tar purification unit 6.

[0038] Preparatory work when the pretreatment device is in use: the inlet and outlet switch valves of the pretreatment device 1 are in a closed state. Turn on the cooling wa...

Embodiment 2

[0042] Example 2: The biogas comes from the deoxygenation tower, decarbonization tower, synthesis tower and tail gas outlet of the biomass synthesis system

[0043] The inlet of the pretreatment device 1 for the on-line laser Raman spectrometer of the biogas passes through the pipeline and the H containing H from the deoxygenation tower, the decarbonization tower, the synthesis tower and the tail gas outlet of the biomass synthesis system. 2 , CO, N 2 , a small amount of C 1 -C 4 Gaseous hydrocarbons, CO 2 The biogas connection of the device 1 is connected to the laser Raman spectrometer 3 through a pipeline; the device 1 includes an impurity adsorption unit 7, a cooling processing unit 4 and a constant speed control unit 5 connected in sequence; the entrance of the device 1 is connected to the impurity adsorption unit 7 connections.

[0044] Preparatory work when the pretreatment device is in use: the inlet and outlet switch valves of the pretreatment device 1 are in a cl...

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Abstract

The invention discloses a pretreatment apparatus for a biogas online laser Raman spectrometer, and a use method thereof. The apparatus is an integrated system, the inlet of the apparatus is connected with biogas, and the outlet of the apparatus is connected with the laser Raman spectrometer; the apparatus at least comprises, sequentially connected, an impurity processing unit, a cooling treatment unit and a constant speed control unit; and the impurity processing unit comprise a tar purifying unit and an impurity adsorbing unit paralleling to the tar purifying unit, and the inlet of the apparatus is provided with a triple valve in order to realize the connection between the inlet of the apparatus and the tar purifying unit or the impurity adsorbing unit. The apparatus has a simple structure, and the corresponding pretreatment apparatus can be flexible prepared by synthetically considering impurities carried in different gas samples according to the onsite practical conditions and the gas quality characteristic of a biomass combustion gas system in order to realize stable running of the e laser Raman gas spectrometer, the accuracy and sensitivity of Raman analysis data and real-time online continuous treatment.

Description

Technical field: [0001] The invention relates to a pretreatment device for an on-line analysis instrument of biogas, in particular to a pretreatment device for an on-line laser Raman spectrometer of a biogas and a use method thereof. Background technique: [0002] Energy is the basis for the survival and development of modern society. The supply capacity of clean fuel is related to the sustainable development of the national economy and is one of the foundations of national strategic security. In the past 100 years, due to the extensive use of fossil energy, the exploitable fossil energy reserves have been decreasing day by day, and the formation of fossil energy cannot be realized overnight, so the gap between energy storage and energy consumption is increasing day by day; in order to alleviate resource shortages and environmental pollution To achieve sustainable development, the dual pressures brought by the environment can be achieved by improving the utilization rate of ...

Claims

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Application Information

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IPC IPC(8): G01N21/65G01N1/34
Inventor 定明月王铁军马隆龙熊友辉刘志强王晨光
Owner GUANGZHOU INST OF ENERGY CONVERSION - CHINESE ACAD OF SCI
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