3D space net structure active carbon fiber skeleton and preparation method thereof
A technology of activated carbon fiber and network structure, applied in the field of activated carbon materials, can solve the problems of low production efficiency, high production cost and difficult mechanical strength of carbon fiber braided body, and achieve high content of activated carbon, low production cost and good integrity Effect
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[0031] The invention provides a method for preparing a three-dimensional space network structure activated carbon fiber skeleton, comprising the following steps:
[0032] Firstly, the wood fibers loaded or not loaded with activator and activated catalyst are bonded by polymer binder with or without activator and activated catalyst to obtain a three-dimensional space bonded by polymer binder. Non-fabric prefabricated body with network structure, wood fibers are distributed in three-dimensional and multi-directional, interweaved and cross-connected.
[0033] Then, the non-woven prefabricated body is subjected to carbonization and activation treatment to obtain an activated carbon fiber skeleton with a three-dimensional network structure loaded or not loaded with a catalyst.
[0034] In the preparation method of activated carbon fiber skeleton with three-dimensional space network structure of the present invention, the bonding between fibers in the aforementioned three-dimensiona...
Embodiment 1
[0051] Immerse coconut palm silk with a length of 30mm-250mm and a material-to-liquid ratio of 1:3-5 in ZnCl at 60°C 2 Immerse in the solution for 8 hours, the solution concentration is 50-57 degrees Baume, and the pH value is 1.0-3.5. After centrifugal drying, dry to a moisture content of 15%-20%, and the loaded ZnCl 2 Activator of coconut palm silk; the ZnCl 2 Added to natural latex aqueous solution to obtain a concentration of 6% ZnCl 2 Latex binder; Prepared coconut palm fiber is transported to cyclone separator, by free fall, obtains the fiber layer that thickness is 30mm; According to coconut palm fiber and natural latex dry matter weight ratio, be the glue consumption of 1:1, The prepared natural latex is evenly sprayed on the fiber layer, and the coconut palm fiber is bonded together, and then dried to obtain a coconut palm fiber mat with a moisture content of less than 20%. Bond 10 pieces of 30mm fiber felt to obtain a coconut palm felt with a thickness of 300mm; pu...
Embodiment 2
[0056] Dry the oil palm silk with a length of 30mm-250mm to a moisture content of 15%-20%; melt the asphalt to obtain an asphalt binder. The prepared oil palm silk is transported to the cyclone separator, and a fiber layer with a thickness of 20mm is obtained by free falling; according to the ratio of oil palm silk and asphalt mass ratio of 1:1.5, the prepared asphalt binder Spray evenly on the fiber layer to bond the fiber bundles into one. Put the oil palm flakes with a thickness of 20mm under the press, press statically for 10 seconds at a temperature of 120°C and a pressure of 5Mpa, and cut to obtain a density of 0.3g / cm 3 oil palm silk non-fabric preforms.
[0057] Put the oil palm silk non-fabric prefabricated body into the kiln and heat it at a heating rate of 10°C / min, heat it to 450°C-600°C and keep it warm for 90 minutes for carbonization; then continue heating at a heating rate of 15°C / min, and heat it to 800°C ℃~950℃, continuously inject superheated steam at 300℃...
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