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Pulverized coal fired boiler with ultralow nitric oxide emission

A nitrogen oxide, pulverized coal boiler technology, applied in the field of pulverized coal boilers, can solve the problems of high operating cost, large energy consumption, environmental pollution, etc., and achieve the effects of efficiently utilizing furnace space, reducing NOx concentration, and reducing catalyst costs.

Active Publication Date: 2015-09-09
HUANENG CLEAN ENERGY RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] (1) It is necessary to arrange a catalyst layer in the flue at the tail of the boiler. The reconstruction project is difficult to construct, and the catalyst layer has body resistance, which affects the operating economy of the unit;
[0006] (2) The catalyst has a service life, and needs to be replaced regularly after deactivation, resulting in high follow-up costs, and it is difficult to regenerate and dispose of the deactivated denitrification catalyst, which is likely to cause environmental pollution;
[0008] (4) The denitrification reaction requires the use of an amino reducing agent, which has high operating costs and potential safety problems, and the amino reducing agent itself needs to consume a lot of energy in the production process, and it also pollutes the environment

Method used

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  • Pulverized coal fired boiler with ultralow nitric oxide emission
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] Such as figure 1 The pulverized coal boiler with ultra-low NOx emissions shown includes a furnace 1, a boiler burner 2 with a reducing agent generator, and a water-cooled wall heating surface 3, a panel heating surface 4, and convection heating installed in the furnace 1. Surface 5. During the operation of the boiler, the low-nitrogen burner LNB deep air classification is used, the excess air coefficient of combustion is 0.6, the original production of NO is 120ppm, the molar ratio of CO and NO is adjusted to 2.5 by using the overfired air OFA, and the concentration of CO production is 300ppm. The regional temperature is 1100°C. In order to improve the denitrification reaction efficiency, a 1mm-thick attached catalyst layer A is welded and attached to the screen-type heating surface 4. The surface temperature of the screen-type heating surface 4 is 750°C, and the main component of the attached catalyst layer is Fe 2 o 3 and CuO. After the denitration reaction, the N...

Embodiment 2

[0039] Such as figure 2 The pulverized coal boiler with ultra-low nitrogen oxide emissions shown in the figure sets an independent independent catalyst layer B to improve the denitrification efficiency. The independent catalyst layer B adopts a honeycomb catalyst and is arranged in one layer. The main component of the attached catalyst layer is Fe 2 o 3 and oxides of rare earth elements. After the denitration reaction, the NO emission concentration is reduced to 10ppm, and the denitration efficiency is increased to 92%.

Embodiment 3

[0041] In the pulverized coal boiler with ultra-low nitrogen oxide emissions in this embodiment, the excess air coefficient of the low-nitrogen burner LNB combustion is 0.8, the original production amount of NO is 200ppm, and the molar ratio of CO and NO is adjusted to 3 by using the overfired air OFA, corresponding to The CO generation concentration is 600ppm, and the combustion zone temperature is 1200°C. On the panel heating surface 4 and the convection heating surface 5, a catalyst layer A with a thickness of 1.5mm is welded and attached. The surface temperature of the panel heating surface 4 is 800°C, and the surface temperature of the convection heating surface 5 is 600°C. The main component of the catalyst layer is Fe 2 o 3 and CuO. After the denitration reaction, the NO emission concentration is reduced to 50ppm, and the denitration efficiency is 75%.

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Abstract

The invention provides a pulverized coal fired boiler with ultralow nitric oxide emission, and belongs to the technical field of coal-fired power generation and environmental protection. The pulverized coal fired boiler comprises a hearth, a boiler burner, a boiler internal water-cooled wall heating surface, a screen type heating surface and a convection heating surface, wherein the boiler burner is provided with a reducing agent generating device and can generate CO which is the reducing agent; NO and CO carry out reduction reaction and flue gas denitration is implemented; the boiler burner comprises a low-nitrogen burner (LNB) and over fire air (OFA); by the low-nitrogen burner, deep air classification is implemented so as to reduce the original production of the NO; the molar ratio of the CO which is the reducing agent to the NO is adjusted by the over fire air (OFA); and catalyst layers are respectively adhered to the boiler internal water-cooled wall heating surface, the screen type heating surface and the convection heating surface along a smoke flowing direction, or independent catalyst layers are arranged on a tail-end flue. The pulverized coal fired boiler with ultralow nitric oxide emission is simple in structure and runs stably; denitration reaction can be finished without the aid of amino reducing agents, the denitration efficiency is high, and the denitration cost is reduced obviously; and the pulverized coal fired boiler with ultralow nitric oxide emission can be in different scale grades.

Description

technical field [0001] The invention belongs to the technical field of coal-fired power generation and environmental protection, and in particular relates to a pulverized coal boiler with ultra-low emission of nitrogen oxides. Background technique [0002] With the country's increasing emphasis on environmental protection, the control of pollutant emissions from thermal power plants is becoming more and more stringent. According to the "Coal Power Energy Conservation and Emission Reduction Upgrading and Transformation Action Plan (2014-2020)", the newly built coal-fired generating units in the central and eastern regions NO x Emissions must meet the emission limits of gas-fired units (50mg / m 3 ), ultra-low emissions will be the development trend of coal-fired power plants in the future. [0003] At present, the denitrification method of pulverized coal boiler mainly adopts low nitrogen combustion technology combined with selective catalytic reduction denitrification techno...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): F23C7/00B01D53/56
Inventor 蒋敏华肖平黄中高洪培唐巍徐正泉刘冠杰
Owner HUANENG CLEAN ENERGY RES INST
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