Laying method of seed crystals, preparation method of quasi-monocrystalline silicon piece and quasi-monocrystalline silicon piece

A laying method and quasi-single crystal technology, which are applied in the directions of single crystal growth, single crystal growth, chemical instruments and methods, etc. Dislocation source and other problems, to achieve the effect of simple and easy operation of the laying method, reducing lattice mismatch stress, and reducing the probability of dislocation

Active Publication Date: 2015-09-16
JIANGXI SAI WEI LDK SOLAR HI TECH CO LTD
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0002] At present, the casting methods of quasi-single crystal mainly include seedless seeding and seeded seeding method. The seeded seeding method is to lay the single crystal seed crystal on the bottom of the quartz crucible first, and keep the seed crystal incompletely melted during the melting stage. , the seeding growth is carried out on the single crystal seed crystal to obtain the quasi-single crystal silicon ingot. When laying the seed crystal, the growth crystal direction of the nucleation surface of the seed crystal is generally guaranteed to be consistent, but the crystal orientation of the side contact surface of the adjacent seed crystal It is usually random, and it is easy to form small-angle grain boundaries during the seeding growth process. The small-angle grain boundaries not only become a dislocation source during the growth process, resulting in the continuous pro

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  • Laying method of seed crystals, preparation method of quasi-monocrystalline silicon piece and quasi-monocrystalline silicon piece
  • Laying method of seed crystals, preparation method of quasi-monocrystalline silicon piece and quasi-monocrystalline silicon piece
  • Laying method of seed crystals, preparation method of quasi-monocrystalline silicon piece and quasi-monocrystalline silicon piece

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Effect test

Embodiment 1

[0075] A method for laying a seed crystal, which is used for the casting of a quasi-single crystal, comprises the following steps:

[0076] Select a square seed crystal with a crystal orientation of on the growth surface and on the side surface as the target growth seed crystal, and the numbering method is as follows figure 1 As shown, wherein, the seed crystals are derived from the same single crystal rod, the thickness of the seed crystals is 20mm, and 25 pieces of the seed crystals with a cross-sectional size of 156mm*156mm are spread on the bottom of the crucible in a 5×5 manner, and the seed crystals are The crystal growth face of the crystal is [001] with the same positive direction, and then one of the adjacent seed crystals is turned 180° around the normal direction of the contact side of the seed crystal, or one of the adjacent seed crystals is Flip 180° around the direction perpendicular to the normal direction of the contact side of the seed crystal. At this time,...

Embodiment 2

[0081] A method for laying a seed crystal, which is used for the casting of a quasi-single crystal, comprises the following steps:

[0082] Select a square seed crystal with a crystal orientation of on the growth surface and on the side surface as the target growth seed crystal, and the numbering method is as follows figure 1As shown, wherein, the seed crystals are derived from the same single crystal rod, the thickness of the seed crystals is 20mm, and 25 pieces of the seed crystals with a cross-sectional size of 156mm*156mm are spread on the bottom of the crucible in a 5×5 manner, and the seed crystals are The crystal orientation of the growth surface of the crystal is the same as [001], and then one of the adjacent seed crystals is rotated by 90°. At this time, the crystal orientation of the contact side of the two adjacent seed crystals belongs to the other crystal orientation group of the same crystal orientation group. crystal orientation, and the contact side surfaces...

Embodiment 3

[0088] A method for laying a seed crystal, which is used for the casting of a quasi-single crystal, comprises the following steps:

[0089] Select the crystallographic orientation of the growth plane as The square seed crystal with side crystal direction is used as the target growth seed crystal, and the numbering method is as follows figure 1 As shown, wherein, the seed crystals are derived from the same single crystal rod, the thickness of the seed crystals is 20mm, and 25 pieces of the seed crystals with a cross-sectional size of 156mm*156mm are spread on the bottom of the crucible in a 5×5 manner, and the seed crystals are The growth planes of the crystals are all opposite Then rotate one of the adjacent seed crystals by 90° (at this time, the adjacent seed crystals are laid on the opposite side), and at this time, the crystal orientations of the contact sides of the two adjacent seed crystals belong to different crystal orientations of the same crystal plane family i...

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Abstract

The invention provides a laying method of seed crystals and is used for the casting of quasi-monocrystalline silicon piece. The method comprises the steps of: seed crystals are laid on the crucible bottom, the seed crystals have a same growth surface crystal orientation of [001] or [001<->]; the seed crystals in close contact and fully cover the crucible bottom to form a seed crystal layer; the side crystal orientation of two adjacent contact the seed crystals belongs to the same crystal to the same crystal orientation family and constitute a coincidence position lattice type of grain boundary; when the side crystal orientation of the seed crystal is <110>, the crystal orientation of growth face of the adjacent seed crystals alternately splices front and back according to [001] [001<->], or one of the adjacent seed crystals rotates 90 DEG; when the side crystal orientation of the seed crystals is not <110> crystal orientation family, the crystal orientation of growth face of the adjacent seed crystals alternately splices front and back, or after the front and back alternate splicing, one of the adjacent seed crystals rotates 90 DEG. The laying of seed crystals reduces the occurrence of dislocation sources in the crystal introduction process. The invention also provides a preparation method of a quasi-monocrystalline silicon piece and the quasi-monocrystalline silicon piece.

Description

technical field [0001] The invention relates to the field of semiconductor manufacturing, in particular to a method for laying a seed crystal, a method for preparing a quasi-single crystal silicon chip and a quasi-single crystal silicon chip. Background technique [0002] At present, the casting methods of quasi-single crystal mainly include seedless seeding and seeded seeding method. The seeded seeding method is to lay the single crystal seed crystal on the bottom of the quartz crucible first, and keep the seed crystal incompletely melted during the melting stage. , the seeding growth is carried out on the single crystal seed crystal to obtain the quasi-single crystal silicon ingot. When laying the seed crystal, the growth crystal direction of the nucleation surface of the seed crystal is generally guaranteed to be consistent, but the crystal orientation of the side contact surface of the adjacent seed crystal It is usually random, and it is easy to form small-angle grain b...

Claims

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Application Information

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IPC IPC(8): C30B11/14C30B29/06
Inventor 陈红荣胡动力徐云飞雷琦何亮
Owner JIANGXI SAI WEI LDK SOLAR HI TECH CO LTD
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