Temperature control, aeration and stirring integrated environmental pollutant photochemical transformation studying device

A technology of environmental pollutants, aeration and agitation, applied in the direction of measuring devices, scientific instruments, instruments, etc., can solve the problems of complex overall design, temperature rise of the reaction system, cost increase, etc., to improve accuracy and precision, simplify Photochemical device, effect of reducing complexity

Active Publication Date: 2015-09-23
HENAN POLYTECHNIC UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] (1) The relatively simple device cannot be tested in parallel, and only a single influencing factor can be considered, resulting in poor accuracy and precision of the experimental results (such as patent 201320130115.3)
[0004] (2) Although the more complex design can comprehensively consider the conditions of stirring, filtering and aeration, the temperature conditions are not considered (such as patents 200720196142.5, 201010293017.2, 201410361142.0)
Long-term irradiation of the sample by a high-power light source will cause the temperature of the reaction system to rise, which will affect the accuracy of the experimental results
[0005] (3) The realization of stirring mostly adopts electromagnetic stirring or motor stirring, which increases the complexity of the device and increases the cost;
[0006] (4) The modularity of the overall design is poor, which causes the overall design to be too complicated when multiple factors are considered comprehensively, which increases the cost and affects the expansion of the photochemical reaction device function;

Method used

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  • Temperature control, aeration and stirring integrated environmental pollutant photochemical transformation studying device
  • Temperature control, aeration and stirring integrated environmental pollutant photochemical transformation studying device
  • Temperature control, aeration and stirring integrated environmental pollutant photochemical transformation studying device

Examples

Experimental program
Comparison scheme
Effect test

specific Embodiment 1

[0038] Add 200ml of water into the three beakers respectively, beaker 1 is aerated through the aeration tube, beaker 2 is stirred by a magnetic stirrer, and beaker 3 is left untreated. Add 2 drops of methyl orange to each of the three beakers, and observe the mixing of methyl orange and water. Under the condition of aeration rate of 25ml / min, it takes 1-2 seconds for the water in beaker 1 to completely mix with methyl orange. ; Under the condition of a stirring rate of 500r / min, the time required for complete mixing of water and methyl orange in beaker 2 is about 40s, while that of beaker 3 takes 1h. It can be seen that aeration can achieve rapid mixing of solutions.

specific Embodiment 2

[0039] see Figure 1 to Figure 6 , the connection module, that is, the heat exchange connector, in which the cylindrical aluminum block is 310mm high, the bottom surface diameter is 100mm, the outer diameter and inner diameter of the copper air pipe and the copper temperature control pipeline are 3mm and 1mm respectively, and the number of turns of the copper air pipe is 49 turns, copper temperature control pipeline 50 turns. The water outlet of the constant temperature circulating water bath of the temperature control module is connected with the temperature control pipeline water inlet 94 of the heat exchange connector, and the temperature control pipeline water outlet 95 of the heat exchange connector is connected with the water inlet of the constant temperature circulation water bath of the temperature control module. At the same time, the air storage bottle of the aeration module is connected to the air inlet 96 of the heat exchange connector by plastic connecting pipelin...

specific Embodiment 3

[0040] Experimental condition and embodiment two are basically the same, and difference is: in three sample cups, add 200mL respectively, the trichlorophenol solution of 1mmol / L, use 2 sets of heat exchange connectors, its copper ventilation tube is respectively connected with nitrogen, nitrogen, The oxygen storage cylinders are connected, and nitrogen and oxygen are fed into the three sample cups respectively, and the last one is a blank control without any gas. The xenon lamp power of the photochemical reaction module device is 1000W, and samples are taken from the sampling port 24 at five time points of 0h, 4h, 8h, 12h, and 16h during the illumination process. Finally, the degradation rate constant of trichlorophenol was measured: the nitrogen gas was 0.05h -1 , oxygen is 0.09h -1 , the blank is 0.06h -1 .

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Abstract

The invention discloses a temperature control, aeration and stirring integrated environmental pollutant photochemical transformation studying device. The device comprises a photochemical reaction module, a temperature-controlling module, an aeration module and a connecting module, and is characterized in that the photochemical reaction module is a cylindrical container and comprises a light source (1), a sample cup (2), an illuminating room (3), an illuminating room top turning door (4), a light-filtering film clamping groove top turning door (5), a light-filtering film (6), an annular vertical clapboard (7) and an aeration pipe (8). Aeration, stirring and temperature control are integrated by aerating in solution and adjusting the temperature of gas used by aeration, so that precise and quick temperature control is realized, a stirring effect is achieved, the overall uniformity of the solution is realized, the photochemical reaction module is simplified, and the cost is reduced; meanwhile, the illumination wavelength can also be controlled, a plurality of experiments can be simultaneously performed at one time, and the experiment efficiency and the comparability of an experiment result are improved.

Description

technical field [0001] The invention relates to an experimental device, in particular to a research device for photochemical conversion of environmental pollutants integrated with temperature control, aeration and stirring. Background technique [0002] Photochemical degradation is an important transformation process of pollutants in the water environment, and the study of the mechanism of pollutant photochemical degradation is the basis for clarifying the environmental fate of pollutants and evaluating the environmental risk of pollutants. However, there are many factors affecting the degradation of pollutants in water bodies, such as temperature, oxygen content, light wavelength and other parameters will directly affect the pathways, products and mechanisms of the photochemical degradation of pollutants. It is difficult to strictly control the above influencing factors by using the existing photochemical photochemical reaction module, which directly affects the accuracy an...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N33/00
Inventor 邰超
Owner HENAN POLYTECHNIC UNIV
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