Flue gas treatment device and method
A technology for flue gas treatment and flue gas, which is applied in the integrated device of nitrogen oxides, mercury and dust, and the field of sulfur dioxide. It can solve the problems that the dust removal effect cannot meet the requirements of the new standard, the denitrification and mercury removal efficiency is low, and the oxidation performance is poor. , to achieve the effects of saving ozone consumption, reducing water in flue gas, and low production cost
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[0106] The flue gas oxidation step of the present invention is to use ozone and hydrogen peroxide to synergistically oxidize low-valent nitrogen oxides and elemental mercury in the flue gas in the ozone spray oxidation reaction layer and hydrogen peroxide spray oxidation reaction layer, and form high-valent nitrogen oxides substances and mercury oxide. Preferably, the flue gas oxidation step of the present invention includes: in the ozone spray oxidation reaction layer, spray ozone downward through the ozone atomization spray part; in the hydrogen peroxide spray oxidation reaction layer, spray The shower unit sprays hydrogen peroxide downwards. The atomization and spraying process used in the flue gas oxidation step is not particularly limited, and those well known in the art can be used. According to one embodiment of the present invention, the flue gas oxidation step preferably uses stainless steel nozzles to spray ozone and hydrogen peroxide. The synergistic oxidation pri...
Embodiment 1
[0123] figure 1 A schematic diagram of the device of Example 1 of the present invention is shown. It can be seen from the figure that the flue gas treatment device of the present invention includes flue gas treatment equipment 1 , ozone supply equipment 5 , and hydrogen peroxide supply equipment 8 . The flue gas treatment equipment 1 includes an ozone spray oxidation reaction layer 4, a hydrogen peroxide spray oxidation reaction layer 7, an absorption spray area 2 and a slurry storage area 10, wherein the ozone spray oxidation reaction layer 4 and the hydrogen peroxide spray oxidation reaction layer 7 They are all located in the absorption spray area 2. The absorption spray zone 2 comprises a first absorption spray layer 13 , a second absorption spray layer 14 and a third absorption spray layer 15 . The hydrogen peroxide spray oxidation reaction layer 7 is located between the first absorption spray layer 13 and the second absorption spray layer 14 . The ozone spray oxidatio...
Embodiment 2
[0138] figure 2 A schematic diagram of the device of Example 2 of the present invention is shown. It can be seen from the figure that the flue gas treatment device of the present invention includes flue gas treatment equipment 1 , ozone supply equipment 5 , and hydrogen peroxide supply equipment 8 . The flue gas treatment equipment 1 includes an ozone spray oxidation reaction layer 4, a hydrogen peroxide spray oxidation reaction layer 7, an absorption spray area 2 and a slurry storage area 10, wherein the ozone spray oxidation reaction layer 4 and the hydrogen peroxide spray oxidation reaction layer 7 They are all located in the absorption spray area 2. The absorption spray zone 2 comprises a first absorption spray layer 13 , a second absorption spray layer 14 and a third absorption spray layer 15 . The ozone spray oxidation reaction layer 4 is located between the first absorption spray layer 13 and the second absorption spray layer 14 . The hydrogen peroxide spray oxidati...
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