Polarizing plate and liquid crystal display including same
A polarizer and polarizer technology, applied in the field of liquid crystal display devices, can solve the problems of insufficient adhesive strength, no alternatives, poor appearance of polarizers, etc., and achieve the effects of excellent durability and excellent adhesion
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Examples
Embodiment 1
[0157] (1) Preparation of photocurable adhesive composition
[0158] As a cationic polymerizable compound, 65 parts by weight of Daicel's CEL-2021P and 32 parts by weight of KUKDO Chemical's YDF-8170, 2.0 parts by weight of CPI-110A as a photopolymerization initiator, and 1.0 parts by weight as a photosensitizer The UVS-1331 of Kawasaki Chemical Industry Co., Ltd. was mixed in parts by weight to prepare a photocurable adhesive composition.
[0159] (2) Manufacture of polarizer
[0160] A triacetyl cellulose film was bonded to the upper surface of the polyvinyl alcohol-based polarizer.
[0161] Thereafter, a laminate (zeonor film: eZB12, manufactured by ZEON Corporation) in which a primer layer was formed on a cycloolefin film was bonded to a polarizer using the photocurable adhesive composition described above.
Embodiment 2
[0163] In addition to using 98% by weight of trimethylolpropane triacrylate (Aronix M-309, Toagosei) as a cationic polymerizable compound, and 1.0% by weight of UVACURE1590 (DAICEL-CYTEC Company) as a photopolymerization initiator, A polarizing plate was produced in the same manner as in Example 1, except that an adhesive composition of 1.0% by weight of IRGACURE 184 (CIBA Corporation) was used as a photosensitizer instead of the photocurable adhesive.
experiment example
[0173] (1) Adhesion evaluation
[0174] The results of evaluating the adhesiveness between the polarizer and the protective film in the polarizing plates produced in Examples and Comparative Examples are shown in Table 1 below according to the following criteria.
[0175] ◯: The film did not spread due to cracks, and the film could be broken without interfacial peeling.
[0176] Δ: The film was not broken by cracks, but peeled off at the interface.
[0177] X: When separation occurs with cracks, separation can be easily performed, and protrusions appear between the protective film and the polarizer.
[0178] (2) Evaluation of heat and humidity resistance, heat resistance, and thermal shock resistance
[0179] The polarizing plates produced in Examples and Comparative Examples were placed in a heat-resistant oven at a temperature of 60° C. and a relative humidity of 90% and a heat-resistant oven at a temperature of 80° C., respectively. After leaving for 3 days, the appearanc...
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Abstract
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